US20100240558A1
2010-09-23
12/408,122
2009-03-20
The present invention pertains to a lubricating arrangement of a chain assemblage serving to coat chain components. Particularly, the lubricating arrangement includes a first non-electrolytic nickel layer and a second PTFE alloy layer that possess 3 to 35 vol % PTFE, whereby the present invention conduces to attain an automatically lubricating capability, increase the surface hardness of the chain assemblage, and prolong the utilization thereof without affecting the tensile strength.
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C10M169/041 » CPC main
Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential; Mixtures of base-materials and additives the additives being macromolecular compounds only
C10M2201/053 » CPC further
Inorganic compounds or elements as ingredients in lubricant compositions; Elements; Metals; Alloys used as base material
C10M2201/0613 » CPC further
Inorganic compounds or elements as ingredients in lubricant compositions; Metal compounds; Carbides; Hydrides; Nitrides used as base material
C10M2213/0623 » CPC further
Organic compounds containing halogen as ingredients in lubricant compositions; Perfluoro polymers; Polytetrafluoroethylene [PTFE] used as base material
C10N2020/06 » CPC further
Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions; Physico-chemical properties; Particles related characteristics Particles of special shape or size
C10N2030/06 » CPC further
Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
C10N2050/025 » CPC further
Form in which the lubricant is applied to the material being lubricated; Multi-layer lubricant coatings in the form of films or sheets
C10N2050/14 » CPC further
Form in which the lubricant is applied to the material being lubricated Composite materials or sliding materials in which lubricants are integrally molded
C10N2080/00 » CPC further
Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal
C10M125/00 IPC
Additives
C10M125/00 IPC
Lubricating compositions characterised by the additive being an inorganic material
1. Field of the Invention
The present invention relates to a lubricating arrangement of a chain assemblage, in particular to one applied to coat the chain components of the chain assemblage with layers of non-electrolytic nickel and Polytetrafluoroethylene alloy to attain effects of automatically lubricating and increasing the surface hardness and durability of the chain without burdening the tensile strength.
2. Description of the Related Art
Generally, the assemblage of the chain is required to be immersed in a heat and liquefied lubricating liquid. When the liquefied lubricating liquid gradually becomes thick lubricant oil at room temperature, the chain assemblage is homogenized to be coated with the lubricant oil. In the long term, the critical occurrence attendant on the lubricant-coated chain is the large consumption of the lubricant oil caused by the wrapping of soil, mud, or sand on the chain components and the combination thereof with the redundant oil. Such difficulty not only decreases the efficiency of the chain operation but obstructs the further addition of the liquid lubricant into the chain shaft. Therefore, the conventional chain configuration is still in a rugged operation. The conventional chain also facilely incurs the problems of the rusty chain shaft and the oil stains on user's clothes while operating the chain.
A closed prior is cited by Taiwanese Patent No. M275160, shown in FIG. 8, also exists the aforementioned deficiencies, in which mainly discloses to embed inner protrusions A1 of chain plates A into respective chain hubs B. Such configuration also renders the lubricating oil unable to drip into chain axles C, and the chain axles C would facilely become rusty and result in the premature abrasion and exhaustion of the chain plates A.
The object of the present invention is to provide a lubricating arrangement that coats every chain component with layers of non-electrolytic nickel and Polytetrafluoroethylene alloy to obtain an automatic lubrication and to increase the surface hardness and durability of the chain without burdening the tensile strength.
The present invention in conformity with the lubricating arrangement of chain assemblage applied to components thereof mainly comprises a first lubricating layer coating the surface of the chain assemblage and a second lubricating layer covering the surface of the first lubricating layer; wherein, the first lubricating layer is preferably fabricated of a non-electrolytic nickel layer in a thickness of 2 to 5 micrometers (i), and the second lubricating layer is preferably made of a Polytetrafluoroethylene alloy (PTFE alloy) layer in a thickness of 2 to 8 micrometers (i) and provided with the volume of Polytetrafluoroethylene (PTFE, namely Teflon) ranging from 3 to 35 vol %.
Further, the chain assemblage comprises one of a chain hub, a chain axle, an interior chain plate, an exterior chain plate and a bushing or the combination of the above.
The chain assemblage is preferably constituted of the eighth group of periodic element.
The non-electrolytic nickel layer preferably has components in weight (wt %) ranging from 6 to 13 wt % phosphorus (P) and 87 to 94 wt % nickel (Ni).
The PTFE alloy layer preferably contains ranging from 20 to 35 vol % PTFE and provides the density ranging from 5.9 to 6.8 g/cm3, equating with 6 to 12.5 wt %. The PTFE alloy layer further comprises components in weight (wt %) ranging from 7.5 to 10 wt % phosphorus (P) and 77 to 86 wt % nickel (Ni).
The second lubricating layer is further overlaid with either a reinforcing layer or a painting, wherein the reinforcing layer is a layer of titanium nitride (TiN).
Accordingly, the advantages of present invention set forth below:
The advantages of the present invention over the known prior arts will become more apparent to those of ordinary skilled in the art by reading the following descriptions with the relating drawings.
FIG. 1 is a cross-sectional view showing chain components according to a first preferred embodiment of the present invention;
FIG. 2 is a cross-sectional view showing a structure of an interior chain plate according to the first preferred embodiment of the present invention;
FIG. 2A is a local cross-sectional view showing the interior chain plate according to the first preferred embodiment of the present invention;
FIG. 3 is a cross-sectional view showing a structure of an exterior chain plate according to the first preferred embodiment of the present invention;
FIG. 3A is a local cross-sectional view showing the exterior chain plate according to the first preferred embodiment of the present invention;
FIG. 4 is a cross-sectional view showing a structure of a chain hub according to the first preferred embodiment of the present invention;
FIG. 4A is a local cross-sectional view showing the chain hub according to the first preferred embodiment of the present invention;
FIG. 5 is a cross-sectional view showing a structure of a chain axle according to the first preferred embodiment of the present invention;
FIG. 5A is a local cross-sectional view showing the chain axle according to the first preferred embodiment of the present invention;
FIG. 6 is a cross-sectional view showing chain components according to a second preferred embodiment of the present invention;
FIG. 7 is a cross-sectional view showing a structure of a bushing according to the second preferred embodiment of the present invention;
FIG. 7A is a local cross-sectional view the bushing according to the second preferred embodiment of the present invention; and
FIG. 8 is a cross-sectional view showing a conventional chain assemblage.
Before describing in greater detail, it should note that the like elements are denoted by the similar reference numerals throughout the disclosure.
FIG. 1 shows a first preferred embodiment of the present invention, a chain assemblage of the present invention is primarily constituted of the eighth group of periodic element, namely elements of ferrum (F), cobalt (Co), nickel (Ni), ruthenium (Ru), rhodium (Rn), palladium (Pd), osmium (Os), iridium (Ir), platinum (Pt) and the alloy thereof. Further, the chain assemblage includes a pair of interior chain plates 1, a pair of exterior chain plates 2, a chain hub 3, and a chain axle 4.
The pair of interior chain plates 1 are disposed in relative positions. Each interior chain plate 1 includes a first pivot bore 11 arranged thereon, a first lubricating layer 12, and a second lubricating layer 13 as illustrated in FIGS. 2 and 2A. The first lubricating layer 12 coats the surface of the interior chain plate 1 and has a thickness of 2 to 5 micrometers (i). Particularly, the first lubricating layer 12 is preferably fabricated of a non-electrolytic nickel layer containing in weight (wt %) of 6 to 13 wt % phosphorus (P) and 87 to 94 wt % nickel (Ni). It is adopted in the first embodiment that the non-electrolytic nickel layer having components in weight of 11 wt % phosphorus and 89 wt % nickel. The physical properties of the non-electrolytic nickel layer in different proportions of phosphorus and nickel are depicted in Table 1:
| TABLE 1 |
| Physical characteristics of the non-electrolytic nickel layer in different |
| proportions of P and Ni. |
| Specification | 9151 | 115 | 754 |
| Configuration | piece particle | particle | particle |
| Lustrous | brilliant | half- | half- |
| brilliant | brilliant | ||
| Proportion of P | 6-9 wt % | 11-13 wt % | 7-9 wt % |
| Melting point | 960° C. | 860° C. | 890° C. |
| Specific gravity | 8.2 | 7.9 | 8.0 |
| Electrical Resistance (μΩ/cm) | 60 | 60 | 60 |
| Coefficient of Thermal | 13-15 | 13 | 15 |
| Expansion | |||
| (μm/m * ° C.) | |||
| Hardness (HV) | 619 | 556 | 594 |
| Hardness after heat at 350° C. | 1009 | 1002 | 1130 |
| for one hour (HV) | |||
| Stress | half- | compress | compress |
| compress | |||
| Magnetism | micro- | non- | non- |
| magnetic | magnetic | magnetic | |
| Density (psi) | 50000-70000 | 50000-70000 | 50000-70000 |
| Corrosion Resistance | good | excellent | excellent |
| Chemical Resistance | good | excellent | excellent |
| Consistency | below ± 5% | below ± 5% | below ± 5% |
| Precipitation Velocity (μm/hr) | 22 | 15 | 15 |
| Plumbum (Pb) Inclusion | non | 100 ppm | 650 ppm |
In addition, the chain assemblage, which is alternatively made of the eighth group of periodic element as well as the alloy thereof, stainless steel, copper (Cu) as well as the alloy thereof, titanium (Ti) as well as the alloy thereof, and magnesium (Mg) as well as the alloy thereof, can be coated with the non-electrolytic nickel layer, hence attaining a wide application.
Furthermore, the second lubricating layer 13 coats the surface of the first lubricating layer 12 and has a thickness of 2 to 8 micrometers (μ). The second lubricating layer 13 is preferably made of a Polytetrafluoroethylene alloy (PTFE alloy) layer that contains particles of Polytetrafluoroethylene (PTFE) ranging from 3 to 35 vol % for being dispersed eutectoidly among the non-electrolytic nickel layer. It is adopted in the first preferred embodiment that the PTFE alloy layer, which includes the proportion in weight (wt %) ranging from 7.5 to 10 wt % phosphorus (P) and 77 to 86 wt % nickel (Ni), possesses 20 to 35 vol % PTFE and a density ranging from 5.9 to 6.8 g/cm3, equating with 6 to 12.5 wt %. A subsequent layer of titanium nitride (TiN) can serve as a reinforcing layer or process through the painting treatment for coating the surface of the second lubricating layer 13. The physical characteristics of the PTFE alloy layer with different proportions addition to PTFE particles and the non-electrolytic nickel layer are herein shown in Table 2:
| TABLE 2 |
| Comparisons between physical characteristics of the PTFE alloy layer in |
| proportions and the non-electrolytic nickel layer. |
| non- | |||
| Type | Low | High | electrolytic |
| Item | PTFE alloy | PTFE alloy | nickel |
| Ni (wt %) | 83-86 | 77-83 | 88-92 |
| P (wt %) | 7.5-9   |  8-10 |  8-12 |
| PTFE (wt %) |   6-8.5 |  9.5-12.5 | 0   |
| (20-25 vol %) | (29-35 vol %) | ||
| PTFE | 0.2-0.4 | 0.2-0.4 | non |
| aggregates (μm) | |||
| Density (g/cm3) | 6.4-6.8 | 5.9-6.3 | 7.9 |
| Hard-ness | before heat | 250-350 | 200-300 | 500-550 |
| (HV) | treatment | |||
| after heat | 400-500 | 350-450 | 550-900 | |
| treatment | ||||
Table 3 further performs the comparisons between the friction coefficients of PTFE alloy layer and that of the conventional material with lower friction coefficients as set forth below:
| TABLE 3 |
| Comparisons between lubricating layers and typical materials |
| Item | Dynamic friction | |
| Type | Static friction coefficient | coefficient |
| PTFE alloy | 0.134 | 0.097 |
| Non-electrolytic nickel | 0.191 | 0.144 |
| Steel-Plate-Coldrolled-Coil | 0.507 | 0.427 |
| (SPCC) | ||
| Copper (Cu) | 0.232 | 0.146 |
| Aluminum (Al) | 0.171 | 0.106 |
Referring to FIGS. 3 and 3A, the pair of exterior chain plates 2 relatively overlaps the pair of interior chain plates 1. Each exterior chain plate 2 also has a second pivot bore 21 relative to the first pivot bore 11. Each exterior chain plate 2 is also coated with a first lubricating layer 22 and a second lubricating layer 23. The characters of the lubricating layers have been described as above and herein are omitted.
Referring to FIGS. 4 and 4A, the chain hub 3 is disposed between the pair of the interior chain plates 1 and has a circular contour, on which a hub orifice 31 is defined. The chain hub 3 is also coated with a first lubricating layer 32 and a second lubricating layer 33. The characters of the lubricating layers have been described as above and herein are omitted.
Referring to FIGS. 5 and 5A, the chain axle 4 penetrates through the hub orifice 31 of the chain hub 3 and pivots to the second pivot bores 21 of adjacent exterior chain plates 2 and the first pivot bores 11 of adjacent interior chain plates 1. The chain axle 4 is also coated with a first lubricating layer 41 and a second lubricating layer 42. The characters of the lubricating layers have been described as above and herein are omitted.
FIG. 6 shows a second preferred embodiment of the present invention, which is substantially similar to the first preferred embodiment with the exception described hereinafter. The chain assemblage further comprises a bushing 5, in which a bushing orifice 51 is defined. The bushing 5 densely embeds among the pair of the interior chain plates 1 and disposed within the chain hub 3 for permitting turning. As illustrated in FIGS. 7 and 7A, the bushing 5 is also coated with a first lubricating layer 52 and a second lubricating layer 53. The characters of the lubricating layers have been described as above and herein are omitted.
To sum up, the present invention mainly coat every component of the chain assemblage with dual lubricating layers, that is, the first non-electrolytic nickel layers 12, 22, 32, 41, 52 possessing the characteristics of a homogeneous coating, a great adhesion, a high hardness, a favorable wear resistance, a preferable anti-corrosion, and available welding and coating hardness higher than 500 HV (HRC50). The coating hardness would preferably obtain 1000 HV (HRC70) via processing a specific treatment, so as to efficiently enhance the hardness of the chain assemblage. Further, in view of the second lubricating layers 13, 23, 33, 42, 53 is the PTFE alloy layer having a friction coefficient lower than the conventional materials (see Table 3). The second lubricating layer substantially provides the merits of a favorable lubrication and a non-adhesive surface, thereby avoiding the wrapping of the dirt on the components and the rugged operation of the chain assemblage. Further, the second lubricating layer also possesses the properties of a strong temperature endurance, a favorable electric insulation, a great ageing retardation, a precious incombustibility, a great corrosion resistance to enhance the chemical stability, and a diminutive absorption capability. Consequently, the present invention facilitates to attain a durable utilization without frequent renewals, an automatic lubricating effect, and an increment of the surface hardness of the chain assemblage without burdening the tensile strength.
While we have shown and described the embodiment in accordance with the present invention, it should be clear to those skilled in the art that further embodiments may be made without departing from the scope of the present invention.
1. A lubricating arrangement of a chain assemblage applied to components thereof including:
a first lubricating layer coating surfaces of said chain components; wherein, said first lubricating layer being fabricated of a non-electrolytic nickel layer in a thickness of 2-5 micrometers (μ); and
a second lubricating layer covering a surface of said first lubricating layer; wherein, said second lubricating layer being made of a Polytetrafluoroethylene alloy (PTFE alloy) layer that contains a thickness ranging between 2-8μ and a volume of PTFE ranging between 3-35 vol %.
2. The lubricating arrangement of a chain assemblage as claimed in claim 1, wherein, said chain assemblage comprises one of a chain hub, a chain axle, an interior chain plate, an exterior chain plate and a bushing or the combination of the above.
3. The lubricating arrangement of a chain assemblage as claimed in claim 1, wherein, said chain assemblage is constituted of the eighth group of periodic element.
4. The lubricating arrangement of a chain assemblage as claimed in claim 1, wherein, said non-electrolytic nickel layer has components in weight ranging among 6-13 wt % phosphorus (P) and 87-94 wt % nickel (Ni).
5. The lubricating arrangement of a chain assemblage as claimed in claim 1, wherein, said PTFE alloy layer includes the 20-35 vol % PTFE and a density ranging between 5.9-6.8 g/cm3, equating with 6-12.5 wt %; said PTFE alloy layer further comprises components 7.5-10 wt % phosphorus (P) and 77-86 wt % nickel (Ni)
6. The lubricating arrangement of a chain assemblage as claimed in claim 1, wherein, said second lubricating layer is further overlaid with either a reinforcing layer or painting, and said reinforcing layer is preferably a layer of nitrogen titanium (TiN).