Temporal voltage adaptive lithium battery charger

Description

RELATED APPLICATION

This application claims the benefit of U.S. Patent Application No. 61/788,473, filed Mar. 15, 2013.

TECHNICAL FIELD

Embodiments described herein relate generally to systems and methods for charging lithium batteries.

BACKGROUND

Typically Lithium battery chargers can be a single, fixed piece of silicon (chip) or a microprocessor based hardware that has digital to analog converters (DAC) and analog to digital converters (ADC) to set and/or determine charge voltage and charge current.

Li-ion cannot absorb overcharge, and, when fully charged, the charge current must be cut off. A continuous trickle charge would cause plating of metallic lithium, and this could compromise safety. To minimize stress, the lithium-ion battery is kept at the 4.20V/cell peak voltage as short a time as possible.

Another issue is that lithium capacity and open cell voltage change as the battery ages, due to phase changes in the anode/cathode, metal dissolution, and electrolyte and electrode oxidation. Any of these effects cause a decrease in the cell voltage as well as the capacity of the battery.

Lithium Chargers typically use a 3 or 4 stage charge cycle, comprising of constant current, constant voltage and/or equalization and charge termination.

The constant-current charge ends when the cell voltage reaches 4.2 V, at which the constant voltage stage begins. Charging is typically terminated by one of two methods, a minimum charge current or a timer. The minimum current approach monitors the charge current during the constant-voltage stage and terminates the charge when the charge current diminishes in the range of 0.02 C to 0.07 C.

The second method determines when the constant-voltage stage is invoked. Charging continues for an additional 2 hr, and then the charge is terminated. Charging in this manner replenishes a deeply depleted battery in roughly 2.5 hr to 3 h.

Another method to determine capacity and cutoff instead of current, is reading the Open Cell Voltage of the battery. This requires periodically disconnecting the battery from the charge circuit, and reading the voltage of the cell(s). This requires high accuracy A/D converters, precision tolerance components, as well as exemplary layout of the printed circuit board.

In order to safely charge a battery using an open cell or even cutoff current assumes a fresh battery. As a battery ages, the cutoff current or end of charge open cell voltage decreases. As a result, a fixed timer to guarantee the charger stops operating may eventually induce failure in a lithium battery due to the application of voltage across the battery, even though, in its present condition, it is actually at maximum capacity for a cell of that age.

For example, a fixed timer may allow 20 hours total charge time for a totally depleted 15 Amp-hour battery charged at 1 Amp. There is no distinction in partially charged, fully charged or empty batteries with fixed timers. For example, one has a 5-year old 15 Amp-hour battery, currently at 75% of charge. However, due to cell aging, it cannot charge to 100% capacity, but rather only 90%. If attempted to charge beyond 90%, the cell starts to heat due to the increased series resistance of the battery (from aging). Current chargers will attempt to charge this battery to full capacity for the entire 15 hours.

Due to the nature of processor driven battery chargers, the charger voltage may be derived from a bandgap or other voltage reference, as well as a fixed amplifier or digital to analog converter. In the DAC approach, the processor sets a digital value to the desired charger voltage output. However, due to silicon variations, component tolerances and PCB layout, the actual voltage supplied by the charger may have offsets from the expected value.

Another safety feature is monitoring the temperature of the Lithium battery. Some circuits stop charging when over heated (and reset the timer), or merely decrease the voltage applied to the battery. Either method may allow continual charging of a failing battery.

INCORPORATION BY REFERENCE

Each patent, patent application, and/or publication mentioned in this specification is herein incorporated by reference in its entirety to the same extent as if each individual patent, patent application, and/or publication was specifically and individually indicated to be incorporated by reference.

BRIEF DESCRIPTION OF THE FIGURES

FIG. 1 is a flow diagram for a method of adaptively adjusting charger voltage to prevent over potential to a battery 100, under and embodiment.

DETAILED DESCRIPTION

Although the detailed description herein contains many specifics for the purposes of illustration, anyone of ordinary skill in the art will appreciate that many variations and alterations to the following details are within the scope of the embodiments described herein. Thus, the following illustrative embodiments are set forth without any loss of generality to, and without imposing limitations upon, the claimed invention.

An embodiment described herein adjusts the charger voltage adaptively to prevent an over potential to the battery. First, the processor sets the DAC to the maximum voltage allowable (4.2 for single cell battery). It attempts to calibrate the unit by reading the charger voltage and comparing it to the set voltage. This results in an offset, which is then used to calculate the cutoff voltage of the battery (using the OCV method). This prevents the case of overcharging when the battery cutoff may never actually reach the desired/ideal 4.2V. This method also addresses battery aging, since its OCV voltage will slowly decrease with time, and having a decreased charge voltage will minimize the risk of plating metallic lithium inside the battery.

FIG. 1 is a flow diagram for a method of adaptively adjusting charger voltage to prevent over potential to a battery 100, under and embodiment. The method comprises setting a digital-to-analog converter of a charger to a set voltage 102. The set voltage is a maximum voltage allowable for a battery type. An output voltage of the charger is determined when the charger is operating at the set voltage 104. An offset voltage is determined by comparing the output voltage to the set voltage 106. A cutoff voltage of a battery is determined using the offset voltage and the open circuit voltage 108. The charger voltage adaptively adjusted in response to the cutoff voltage, and the adjusting prevents an over potential to the battery.

The second embodiment is the adaptive timer. If a battery is at 85% capacity, it is undesirable to keeping charging the battery as if the battery is fully discharged, since if the algorithm is a cutoff voltage based, and the cell is aged or has minor internal damage, cell stress to structural, phase change, or plating may occur.

A variable timer is set, based on the remaining capacity of the cell. The constant current phase timer of the charge algorithm is then set by the difference between full capacity and actual capacity of the cell, divided by the charge current. This yields in the time that the cell needs to complete constant current phase. This greatly reduce the time that a potentially damaged cell can be exposed to charge current and voltage. In addition, if the temperature of the cell exceeds a pre-defined upper limit (typically 40 degrees C.) or a lower limit (typically 0 deg C), the then charger circuit is opened, however, the timer is still allowed to run. This is designed to eventually flag a battery as failing if it continually faults hot or cold.

Under an embodiment a 5-year old 15 Amp-hour battery at 75% charge is charged at 1 Amp. Under an embodiment, it is attempted to charge this battery. The estimated time to charge a fully depleted battery would be 1.3*15=19.5 hours at a 1-amp charge rate. The adaptive timer would adjust this to 4.875 hours ([19.5−(19.5*0.75)]).

With a web interface, it is possible for offsite servers to examine cell voltages of batteries over millions of installed batteries. It is feasible for the server to analyze and determine cell open voltage cutoff values as the lithium battery ages.

The device can then request cutoff voltage from the server at large, allowing for longer battery lifetimes.

The same web technique could also be used to calculate the adaptive timer, to allow for tends to decrease or increase allowable charge from statistical battery data.

Unless the context clearly requires otherwise, throughout the description and the claims, the words “comprise,” “comprising,” and the like are to be construed in an inclusive sense as opposed to an exclusive or exhaustive sense; that is to say, in a sense of “including, but not limited to.” Words using the singular or plural number also include the plural or singular number respectively. Additionally, the words “herein,” “hereunder,” “above,” “below,” and words of similar import, when used in this application, refer to this application as a whole and not to any particular portions of this application. When the word “or” is used in reference to a list of two or more items, that word covers all of the following interpretations of the word: any of the items in the list, all of the items in the list and any combination of the items in the list.

The above description of embodiments and corresponding systems and methods is not intended to be exhaustive or to limit the systems and methods to the precise forms disclosed. While specific embodiments of, and examples for, the systems and methods are described herein for illustrative purposes, various equivalent modifications are possible within the scope of the systems and methods, as those skilled in the relevant art will recognize. The teachings of the systems and methods provided herein can be applied to other systems and methods, not only for the systems and methods described above.

The elements and acts of the various embodiments described above can be combined to provide further embodiments. These and other changes can be made to the embodiments and corresponding systems and methods in light of the above detailed description.

In general, in the following claims, the terms used should not be construed to limit the invention and corresponding systems and methods to the specific embodiments disclosed in the specification and the claims, but should be construed to include all systems that operate under the claims. Accordingly, the invention and corresponding systems and methods is not limited by the disclosure, but instead the scope is to be determined entirely by the claims.

While certain aspects of the systems and methods are presented below in certain claim forms, the inventors contemplate the various aspects of the systems and methods in any number of claim forms. Accordingly, the inventors reserve the right to add additional claims after filing the application to pursue such additional claim forms for other aspects of the systems and methods described herein.