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Patent application title:

AIR CONDITIONER

Publication number:

US20210164701A1

Publication date:

2021-06-03

Application number:

16/772,961

Filed date:

2018-12-18

Abstract:

In an air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, high efficiency is achieved. In the air conditioner (1), a compressor (100, 200) can be driven without interposing a power conversion device between an AC power source (90, 190) and a motor (70, 170). Thus, it is possible to provide the air conditioner (1) that is environmentally friendly and has a relatively inexpensive configuration.

Inventors:

Yuzo Komatsu 73 🇯🇵 Osaka, Japan
Daisuke Karube 116 🇯🇵 Osaka, Japan
Kazuhiro TAKAHASHI 140 🇯🇵 Osaka, Japan
Tatsuya TAKAKUWA 81 🇯🇵 Osaka, Japan

Shun OHKUBO 104 🇯🇵 Osaka, Japan
Mitsushi ITANO 128 🇯🇵 Osaka, Japan
Yuuki YOTSUMOTO 87 🇯🇵 Osaka, Japan
Tetsushi TSUDA 35 🇯🇵 Osaka, Japan

Keisuke OHTSUKA 11 🇯🇵 Osaka, Japan

Assignee:

DAIKIN INDUSTRIES, LTD. 3,398 🇯🇵 Osaka, Japan

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Classification:

C09K5/045 » CPC further

Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion; Materials undergoing a change of physical state when used the change of state being from liquid to vapour or for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen

F25B2700/1931 » CPC further

Sensing or detecting of parameters; Sensors therefor; Pressures of the compressor Discharge pressures

F25B2313/0233 » CPC further

Compression machines, plants or systems with reversible cycle not otherwise provided for using multiple indoor units in parallel arrangements

F25B2600/2513 » CPC further

Control issues; Control of valves Expansion valves

F25B2313/02741 » CPC further

Compression machines, plants or systems with reversible cycle not otherwise provided for characterised by the reversing means using one four-way valve

F25B13/00 » CPC main

Compression machines, plants or systems, with reversible cycle

F25B49/02 » CPC further

Arrangement or mounting of control or safety devices for compression type machines, plants or systems

C09K5/04 IPC

Description

TECHNICAL FIELD

The present invention relates to an air conditioner that uses refrigerant with a low global warming potential (GWP).

BACKGROUND ART

In recent years, use of refrigerant with a low GWP (hereinafter referred to as low-GWP refrigerant) in air conditioners has been considered from the viewpoint of environmental protection. A dominant example of low-GWP refrigerant is a refrigerant mixture containing 1,2-difluoroethylene.

SUMMARY OF THE INVENTION

Technical Problem

However, the related art giving consideration from the aspect of increasing the efficiency of air conditioners using the foregoing refrigerant is rarely found. For example, in the case of applying the foregoing refrigerant to the air conditioner disclosed in PTL 1 (Japanese Unexamined Patent Application Publication No. 2013-124848), there is an issue of how to achieve high efficiency.

Solution to Problem

An air conditioner according to a first aspect includes a compressor that compresses a refrigerant mixture containing at least 1,2-difluoroethylene, a motor that drives the compressor, and a connection unit that causes power to be supplied from an alternating-current (AC) power source to the motor without frequency conversion.

An air conditioner according to a second aspect is the air conditioner according to the first aspect, in which the connection unit directly applies an AC voltage of the AC power source between at least two terminals of the motor.

An air conditioner according to a third aspect is the air conditioner according to the first aspect or the second aspect, in which the AC power source is a single-phase power source.

An air conditioner according to a fourth aspect is the air conditioner according to any one of the first aspect to the third aspect, in which one terminal of the motor is connected in series to an activation circuit.

An air conditioner according to a fifth aspect is the air conditioner according to the fourth aspect, in which the activation circuit is a circuit in which a positive temperature coefficient thermistor and an operation capacitor are connected in parallel to each other.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, after the compressor has been activated, the PTC thermistor self-heats and the resistance value thereof increases, and switching to an operation circuit substantially by the operation capacitor occurs. Thus, the compressor enters a state of being capable of outputting a rated torque at appropriate timing.

An air conditioner according to a sixth aspect is the air conditioner according to the first aspect or the second aspect, in which the AC power source is a three-phase power source.

This air conditioner does not require an activation circuit and thus the cost is relatively low.

An air conditioner according to a seventh aspect is the air conditioner according to any one of the first aspect to the sixth aspect, in which the motor is an induction motor.

In this air conditioner, the motor is capable of high output with relatively low cost, and thus the efficiency of the air conditioner can be increased.

An air conditioner according to a eighth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A is used.

An air conditioner according to a ninth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments BD, CO, and OA are straight lines.

An air conditioner according to a tenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:

point G (72.0, 28.0, 0.0),
point I (72.0, 0.0, 28.0),
point A (68.6, 0.0, 31.4),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0), and
point C (32.9, 67.1, 0.0),
or on the above line segments (excluding the points on the line segments IA, BD, and CG);

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments GI, IA, BD, and CG are straight lines.

An air conditioner according to a eleventh aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

point J (47.1, 52.9, 0.0),
point P (55.8, 42.0, 2.2),
point N (68.6, 16.3, 15.1),
point K (61.3, 5.4, 33.3),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0), and
point C (32.9, 67.1, 0.0),
or on the above line segments (excluding the points on the line segments BD and CJ);

the line segment PN is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment NK is represented by coordinates (x, 0.2421x²−29.955x+931.91, −0.2421x²+28.955x−831.91),

the line segment KA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, BD, and CG are straight lines.

An air conditioner according to a twelfth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

point J (47.1, 52.9, 0.0),
point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0),
point M (60.3, 6.2, 33.5),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0), and
point C (32.9, 67.1, 0.0),
or on the above line segments (excluding the points on the line segments BD and CJ);

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43)

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, LM, BD, and CG are straight lines.

An air conditioner according to a thirteenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:

point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0),
point M (60.3, 6.2, 33.5),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point F (0.0, 61.8, 38.2), and
point T (35.8, 44.9, 19.3),
or on the above line segments (excluding the points on the line segment BF);

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LM and BF are straight lines.

An air conditioner according to a fourteenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:

point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0),
point Q (62.8, 29.6, 7.6), and
point R (49.8, 42.3, 7.9),
or on the above line segments;

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment RP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LQ and QR are straight lines.

An air conditioner according to a fifth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:

point S (62.6, 28.3, 9.1),
point M (60.3, 6.2, 33.5),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point F (0.0, 61.8, 38.2), and
point T (35.8, 44.9, 19.3),
or on the above line segments,

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TS is represented by coordinates (x, −0.0017x²−0.7869x+70.888, −0.0017x²−0.2131x+29.112), and

the line segments SM and BF are straight lines.

An air conditioner according to a sixth aspect is the air conditioner according to any of the 1 through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprises 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire refrigerant.

An air conditioner according to a seventeenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises HFO-1132(E) and HFO-1123 in a total amount of 99.5 mass % or more based on the entire refrigerant, and

the refrigerant comprises 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.

An air conditioner according to a eighteenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32), wherein

when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,

if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines GI, IA, AB, BD′, D′C, and CG that connect the following 6 points:

point G (0.026a²−1.7478a+72.0, −0.026a²+0.7478a+28.0, 0.0),
point I (0.026a²−1.7478a+72.0, 0.0, −0.026a²+0.7478a+28.0),
point A (0.0134a²−1.9681a+68.6, 0.0, −0.0134a²+0.9681a+31.4),
point B (0.0, 0.0144a²−1.6377a+58.7, −0.0144a²+0.6377a+41.3),
point D′ (0.0, 0.0224a²+0.968a+75.4, −0.0224a²−1.968a+24.6), and
point C (−0.2304a²−0.4062a+32.9, 0.2304a²−0.5938a+67.1, 0.0),
or on the straight lines GI, AB, and D′C (excluding point G, point I, point A, point B, point D′, and point C);

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.02a²−1.6013a+71.105, −0.02a²+0.6013a+28.895, 0.0),
point I (0.02a²−1.6013a+71.105, 0.0, −0.02a²+0.6013a+28.895),
point A (0.0112a²−1.9337a+68.484, 0.0, −0.0112a²+0.9337a+31.516),
point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0135a²−1.4068a+69.727, −0.0135a²+0.4068a+30.273, 0.0),
point I (0.0135a²−1.4068a+69.727, 0.0, −0.0135a²+0.4068a+30.273),
point A (0.0107a²−1.9142a+68.305, 0.0, −0.0107a²+0.9142a+31.695),
point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0111a²−1.3152a+68.986, −0.0111a²+0.3152a+31.014, 0.0),
point I (0.0111a²−1.3152a+68.986, 0.0, −0.0111a²+0.3152a+31.014),
point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),
point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W); and

if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

An air conditioner according to a nineteenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32), wherein

when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,

if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines JK′, K′B, BD′, D′C, and CJ that connect the following 5 points:

point J (0.0049a²−0.9645a+47.1, −0.0049a²−0.0355a+52.9, 0.0),
point K′ (0.0514a²−2.4353a+61.7, −0.0323a²+0.4122a+5.9, −0.0191a²+1.0231a+32.4),
point B (0.0, 0.0144a²−1.6377a+58.7, −0.0144a²+0.6377a+41.3),
point D′ (0.0, 0.0224a²+0.968a+75.4, −0.0224a²−1.968a+24.6), and
point C (−0.2304a²−0.4062a+32.9, 0.2304a²−0.5938a+67.1, 0.0),
or on the straight lines JK′, K′B, and D′C (excluding point J, point B, point D′, and point C);

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0243a²−1.4161a+49.725, −0.0243a²+0.4161a+50.275, 0.0),
point K′ (0.0341a²−2.1977a+61.187, −0.0236a²+0.34a+5.636, −0.0105a²+0.8577a+33.177),
point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0246a²−1.4476a+50.184, −0.0246a²+0.4476a+49.816, 0.0),
point K′ (0.0196a²−1.7863a+58.515, −0.0079a²−0.1136a+8.702, −0.0117a²+0.8999a+32.783),
point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:

point J (0.0183a²−1.1399a+46.493, −0.0183a²+0.1399a+53.507, 0.0),
point K′ (−0.0051a²+0.0929a+25.95, 0.0, 0.0051a²−1.0929a+74.05),
point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),
point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714), and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W); and

if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:

An air conditioner according to a twentieth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:

point I (72.0, 0.0, 28.0),
point J (48.5, 18.3, 33.2),
point N (27.7, 18.2, 54.1), and
point E (58.3, 0.0, 41.7),
or on these line segments (excluding the points on the line segment EI;

the line segment IJ is represented by coordinates (0.0236y²−1.7616y+72.0, y, −0.0236y²+0.7616y+28.0);

the line segment NE is represented by coordinates (0.012y²−1.9003y+58.3, y, −0.012y²+0.9003y+41.7); and

the line segments JN and EI are straight lines.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.

An air conditioner according to a twenty-first aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:

point M (52.6, 0.0, 47.4),
point M′ (39.2, 5.0, 55.8),
point N (27.7, 18.2, 54.1),
point V (11.0, 18.1, 70.9), and
point G (39.6, 0.0, 60.4),
or on these line segments (excluding the points on the line segment GM);

the line segment MM′ is represented by coordinates (0.132y²−3.34y+52.6, y, −−0.132y²+2.34y+47.4);

the line segment M′N is represented by coordinates (0.0596y²−2.2541y+48.98, y, −0.0596y²+1.2541y+51.02);

the line segment VG is represented by coordinates (0.0123y²−1.8033y+39.6, y, −0.0123y²+0.8033y+60.4); and

the line segments NV and GM are straight lines.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.

An air conditioner according to a twenty-second aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:

point O (22.6, 36.8, 40.6),
point N (27.7, 18.2, 54.1), and
point U (3.9, 36.7, 59.4),
or on these line segments;

the line segment ON is represented by coordinates (0.0072y²−0.6701y+37.512, y, −0.0072y²−0.3299y+62.488);

the line segment NU is represented by coordinates (0.0083y²−1.7403y+56.635, y, −0.0083y²+0.7403y+43.365); and

the line segment UO is a straight line.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.

An air conditioner according to a twenty-third aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:

point Q (44.6, 23.0, 32.4),
point R (25.5, 36.8, 37.7),
point T (8.6, 51.6, 39.8),
point L (28.9, 51.7, 19.4), and
point K (35.6, 36.8, 27.6),
or on these line segments;

the line segment QR is represented by coordinates (0.0099y²−1.975y+84.765, y, −0.0099y²+0.975y+15.235);

the line segment RT is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874);

the line segment LK is represented by coordinates (0.0049y²−0.8842y+61.488, y, −0.0049y²−0.1158y+38.512);

the line segment KQ is represented by coordinates (0.0095y²−1.2222y+67.676, y, −0.0095y²+0.2222y+32.324); and

the line segment TL is a straight line.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.

An air conditioner according to a twenty-fourth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (20.5, 51.7, 27.8),
point S (21.9, 39.7, 38.4), and
point T (8.6, 51.6, 39.8),
or on these line segments;

the line segment PS is represented by coordinates (0.0064y²−0.7103y+40.1, y, −0.0064y²−0.2897y+59.9);

the line segment ST is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874); and

the line segment TP is a straight line.

In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.

An air conditioner according to a fifth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IK, KB′, B′H, HR, RG, and GI that connect the following 6 points:

point I (72.0, 28.0, 0.0),
point K (48.4, 33.2, 18.4),
point B′ (0.0, 81.6, 18.4),
point H (0.0, 84.2, 15.8),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segments B′H and GI);

the line segment IK is represented by coordinates (0.025z²−1.7429z+72.00, −0.025z²+0.7429z+28.0, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments KB′ and GI are straight lines.

An air conditioner according to a twenty-sixth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IJ, JR, RG, and GI that connect the following 4 points:

point I (72.0, 28.0, 0.0),
point J (57.7, 32.8, 9.5),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segment GI);

the line segment IJ is represented by coordinates (0.025z²−1.7429z+72.0, −0.025z²+0.7429z+28.0, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and the line segments JR and GI are straight lines.

An air conditioner according to a twenty-seventh aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MP, PB′, B′H, HR, RG, and GM that connect the following 6 points:

point M (47.1, 52.9, 0.0),
point P (31.8, 49.8, 18.4),
point B′ (0.0, 81.6, 18.4),
point H (0.0, 84.2, 15.8),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segments B′H and GM);

the line segment MP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments PB′ and GM are straight lines.

An air conditioner according to a twenty-eighth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MN, NR, RG, and GM that connect the following 4 points:

point M (47.1, 52.9, 0.0),
point N (38.5, 52.1, 9.5),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segment GM);

the line segment MN is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments JR and GI are straight lines.

An air conditioner according to a twenty-ninth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (31.8, 49.8, 18.4),
point S (25.4, 56.2, 18.4), and
point T (34.8, 51.0, 14.2),
or on these line segments;

the line segment ST is represented by coordinates (−0.0982z²+0.9622z+40.931, 0.0982z²−1.9622z+59.069, z),

the line segment TP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z), and

the line segment PS is a straight line.

An air conditioner according to a thirtieth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments QB″, B″D, DU, and UQ that connect the following 4 points:

point Q (28.6, 34.4, 37.0),
point B″ (0.0, 63.0, 37.0),
point D (0.0, 67.0, 33.0), and
point U (28.7, 41.2, 30.1),
or on these line segments (excluding the points on the line segment B″D);

the line segment DU is represented by coordinates (−3.4962z²+210.71z−3146.1, 3.4962z²−211.71z+3246.1, z),

the line segment UQ is represented by coordinates (0.0135z²−0.9181z+44.133, −0.0135z²−0.0819z+55.867, z), and

the line segments QB″ and B″D are straight lines.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of an instrument used for a flammability test.

FIG. 2 is a diagram showing points A to T and line segments that connect these points in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass %.

FIG. 3 is a diagram showing points A to C, D′, G, I, J, and K′, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass %.

FIG. 4 is a diagram showing points A to C, D′, G, I, J, and K′, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 92.9 mass % (the content of R32 is 7.1 mass %).

FIG. 5 is a diagram showing points A to C, D′, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 88.9 mass % (the content of R32 is 11.1 mass %).

FIG. 6 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 85.5 mass % (the content of R32 is 14.5 mass %).

FIG. 7 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 81.8 mass % (the content of R32 is 18.2 mass %).

FIG. 8 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 78.1 mass % (the content of R32 is 21.9 mass %).

FIG. 9 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 73.3 mass % (the content of R32 is 26.7 mass %).

FIG. 10 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 70.7 mass % (the content of R32 is 29.3 mass %).

FIG. 11 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 63.3 mass % (the content of R32 is 36.7 mass %).

FIG. 12 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 55.9 mass % (the content of R32 is 44.1 mass %).

FIG. 13 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 52.2 mass % (the content of R32 is 47.8 mass %).

FIG. 14 is a view showing points A to C, E, G, and I to W; and line segments that connect points A to C, E, G, and I to W in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass %.

FIG. 15 is a view showing points A to U; and line segments that connect the points in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass %.

FIG. 16 is a configuration diagram of an air conditioner according to one embodiment of the present disclosure.

FIG. 17 is an operation circuit diagram of a motor of a compressor.

FIG. 18 is an operation circuit diagram of a motor of a compressor in an air conditioner according to a modification example.

DESCRIPTION OF EMBODIMENTS

(1) Definition of Terms

In the present specification, the term “refrigerant” includes at least compounds that are specified in ISO 817 (International Organization for Standardization), and that are given a refrigerant number (ASHRAE number) representing the type of refrigerant with “R” at the beginning; and further includes refrigerants that have properties equivalent to those of such refrigerants, even though a refrigerant number is not yet given. Refrigerants are broadly divided into fluorocarbon compounds and non-fluorocarbon compounds in terms of the structure of the compounds. Fluorocarbon compounds include chlorofluorocarbons (CFC), hydrochlorofluorocarbons (HCFC), and hydrofluorocarbons (HFC). Non-fluorocarbon compounds include propane (R290), propylene (R1270), butane (R600), isobutane (R600a), carbon dioxide (R744), ammonia (R717), and the like.

In the present specification, the phrase “composition comprising a refrigerant” at least includes (1) a refrigerant itself (including a mixture of refrigerants), (2) a composition that further comprises other components and that can be mixed with at least a refrigeration oil to obtain a working fluid for a refrigerating machine, and (3) a working fluid for a refrigerating machine containing a refrigeration oil. In the present specification, of these three embodiments, the composition (2) is referred to as a “refrigerant composition” so as to distinguish it from a refrigerant itself (including a mixture of refrigerants). Further, the working fluid for a refrigerating machine (3) is referred to as a “refrigeration oil-containing working fluid” so as to distinguish it from the “refrigerant composition.”

In the present specification, when the term “alternative” is used in a context in which the first refrigerant is replaced with the second refrigerant, the first type of “alternative” means that equipment designed for operation using the first refrigerant can be operated using the second refrigerant under optimum conditions, optionally with changes of only a few parts (at least one of the following: refrigeration oil, gasket, packing, expansion valve, dryer, and other parts) and equipment adjustment. In other words, this type of alternative means that the same equipment is operated with an alternative refrigerant. Embodiments of this type of “alternative” include “drop-in alternative,” “nearly drop-in alternative,” and “retrofit,” in the order in which the extent of changes and adjustment necessary for replacing the first refrigerant with the second refrigerant is smaller.

The term “alternative” also includes a second type of “alternative,” which means that equipment designed for operation using the second refrigerant is operated for the same use as the existing use with the first refrigerant by using the second refrigerant. This type of alternative means that the same use is achieved with an alternative refrigerant.

In the present specification, the term “refrigerating machine” refers to machines in general that draw heat from an object or space to make its temperature lower than the temperature of ambient air, and maintain a low temperature. In other words, refrigerating machines refer to conversion machines that gain energy from the outside to do work, and that perform energy conversion, in order to transfer heat from where the temperature is lower to where the temperature is higher.

In the present specification, a refrigerant having a “WCF lower flammability” means that the most flammable composition (worst case of formulation for flammability: WCF) has a burning velocity of 10 cm/s or less according to the US ANSI/ASHRAE Standard 34-2013. Further, in the present specification, a refrigerant having “ASHRAE lower flammability” means that the burning velocity of WCF is 10 cm/s or less, that the most flammable fraction composition (worst case of fractionation for flammability: WCFF), which is specified by performing a leakage test during storage, shipping, or use based on ANSI/ASHRAE 34-2013 using WCF, has a burning velocity of 10 cm/s or less, and that flammability classification according to the US ANSI/ASHRAE Standard 34-2013 is determined to classified as be “Class 2L.”

In the present specification, a refrigerant having an “RCL of x % or more” means that the refrigerant has a refrigerant concentration limit (RCL), calculated in accordance with the US ANSI/ASHRAE Standard 34-2013, of x % or more. RCL refers to a concentration limit in the air in consideration of safety factors. RCL is an index for reducing the risk of acute toxicity, suffocation, and flammability in a closed space where humans are present. RCL is determined in accordance with the ASHRAE Standard. More specifically, RCL is the lowest concentration among the acute toxicity exposure limit (ATEL), the oxygen deprivation limit (ODL), and the flammable concentration limit (FCL), which are respectively calculated in accordance with sections 7.1.1, 7.1.2, and 7.1.3 of the ASHRAE Standard.

In the present specification, temperature glide refers to an absolute value of the difference between the initial temperature and the end temperature in the phase change process of a composition containing the refrigerant of the present disclosure in the heat exchanger of a refrigerant system.

(2) Refrigerant

(2-1) Refrigerant Component

Any one of various refrigerants such as refrigerant A, refrigerant B, refrigerant C, refrigerant D, and refrigerant E, details of these refrigerant are to be mentioned later, can be used as the refrigerant.

(2-2) Use of Refrigerant

The refrigerant according to the present disclosure can be preferably used as a working fluid in a refrigerating machine.

The composition according to the present disclosure is suitable for use as an alternative refrigerant for HFC refrigerant such as R410A, R407C and R404 etc, or HCFC refrigerant such as R22 etc.

(3) Refrigerant Composition

The refrigerant composition according to the present disclosure comprises at least the refrigerant according to the present disclosure, and can be used for the same use as the refrigerant according to the present disclosure. Moreover, the refrigerant composition according to the present disclosure can be further mixed with at least a refrigeration oil to thereby obtain a working fluid for a refrigerating machine.

The refrigerant composition according to the present disclosure further comprises at least one other component in addition to the refrigerant according to the present disclosure. The refrigerant composition according to the present disclosure may comprise at least one of the following other components, if necessary. As described above, when the refrigerant composition according to the present disclosure is used as a working fluid in a refrigerating machine, it is generally used as a mixture with at least a refrigeration oil. Therefore, it is preferable that the refrigerant composition according to the present disclosure does not substantially comprise a refrigeration oil. Specifically, in the refrigerant composition according to the present disclosure, the content of the refrigeration oil based on the entire refrigerant composition is preferably 0 to 1 mass %, and more preferably 0 to 0.1 mass %.

(3-1) Water

The refrigerant composition according to the present disclosure may contain a small amount of water. The water content of the refrigerant composition is preferably 0.1 mass % or less based on the entire refrigerant. A small amount of water contained in the refrigerant composition stabilizes double bonds in the molecules of unsaturated fluorocarbon compounds that can be present in the refrigerant, and makes it less likely that the unsaturated fluorocarbon compounds will be oxidized, thus increasing the stability of the refrigerant composition.

(3-2) Tracer

A tracer is added to the refrigerant composition according to the present disclosure at a detectable concentration such that when the refrigerant composition has been diluted, contaminated, or undergone other changes, the tracer can trace the changes.

The refrigerant composition according to the present disclosure may comprise a single tracer, or two or more tracers.

The tracer is not limited, and can be suitably selected from commonly used tracers. Preferably, a compound that cannot be an impurity inevitably mixed in the refrigerant of the present disclosure is selected as the tracer.

Examples of tracers include hydrofluorocarbons, hydrochlorofluorocarbons, chlorofluorocarbons, hydrochlorocarbons, fluorocarbons, deuterated hydrocarbons, deuterated hydrofluorocarbons, perfluorocarbons, fluoroethers, brominated compounds, iodinated compounds, alcohols, aldehydes, ketones, and nitrous oxide (N₂O). The tracer is particularly preferably a hydrofluorocarbon, a hydrochlorofluorocarbon, a chlorofluorocarbon, a fluorocarbon, a hydrochlorocarbon, a fluorocarbon, or a fluoroether.

The following compounds are preferable as the tracer.

FC-14 (tetrafluoromethane, CF₄)
HCC-40 (chloromethane, CH₃Cl)
HFC-23 (trifluoromethane, CHF₃)
HFC-41 (fluoromethane, CH₃Cl)
HFC-125 (pentafluoroethane, CF₃CHF₂)
HFC-134a (1,1,1,2-tetrafluoroethane, CF₃CH₂F)
HFC-134 (1,1,2,2-tetrafluoroethane, CHF₂CHF₂)
HFC-143a (1,1,1-trifluoroethane, CF₃CH₃)
HFC-143 (1,1,2-trifluoroethane, CHF₂CH₂F)
HFC-152a (1,1-difluoroethane, CHF₂CH₃)
HFC-152 (1,2-difluoroethane, CH₂FCH₂F)
HFC-161 (fluoroethane, CH₃CH₂F)
HFC-245fa (1,1,1,3,3-pentafluoropropane, CF₃CH₂CHF₂)
HFC-236fa (1,1,1,3,3,3-hexafluoropropane, CF₃CH₂CF₃)
HFC-236ea (1,1,1,2,3,3-hexafluoropropane, CF₃CHFCHF₂)
HFC-227ea (1,1,1,2,3,3,3-heptafluoropropane, CF₃CHFCF₃)
HCFC-22 (chlorodifluoromethane, CHClF₂)
HCFC-31 (chlorofluoromethane, CH₂ClF)
CFC-1113 (chlorotrifluoroethylene, CF₂═CClF)
HFE-125 (trifluoromethyl-difluoromethyl ether, CF₃OCHF₂)
HFE-134a (trifluoromethyl-fluoromethyl ether, CF₃OCH₂F)
HFE-143a (trifluoromethyl-methyl ether, CF₃OCH₃)
HFE-227ea (trifluoromethyl-tetrafluoroethyl ether, CF₃OCHFCF₃)
HFE-236fa (trifluoromethyl-trifluoroethyl ether, CF₃OCH₂CF₃)

The tracer compound may be present in the refrigerant composition at a total concentration of about 10 parts per million (ppm) to about 1000 ppm. Preferably, the tracer compound is present in the refrigerant composition at a total concentration of about 30 ppm to about 500 ppm, and most preferably, the tracer compound is present at a total concentration of about 50 ppm to about 300 ppm.

(3-3) Ultraviolet Fluorescent Dye

The refrigerant composition according to the present disclosure may comprise a single ultraviolet fluorescent dye, or two or more ultraviolet fluorescent dyes.

The ultraviolet fluorescent dye is not limited, and can be suitably selected from commonly used ultraviolet fluorescent dyes.

Examples of ultraviolet fluorescent dyes include naphthalimide, coumarin, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, and derivatives thereof. The ultraviolet fluorescent dye is particularly preferably either naphthalimide or coumarin, or both.

(3-4) Stabilizer

The refrigerant composition according to the present disclosure may comprise a single stabilizer, or two or more stabilizers.

The stabilizer is not limited, and can be suitably selected from commonly used stabilizers.

Examples of stabilizers include nitro compounds, ethers, and amines.

Examples of nitro compounds include aliphatic nitro compounds, such as nitromethane and nitroethane; and aromatic nitro compounds, such as nitro benzene and nitro styrene.

Examples of ethers include 1,4-dioxane.

Examples of amines include 2,2,3,3,3-pentafluoropropylamine and diphenylamine.

Examples of stabilizers also include butylhydroxyxylene and benzotriazole.

The content of the stabilizer is not limited. Generally, the content of the stabilizer is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant.

(3-5) Polymerization Inhibitor

The refrigerant composition according to the present disclosure may comprise a single polymerization inhibitor, or two or more polymerization inhibitors.

The polymerization inhibitor is not limited, and can be suitably selected from commonly used polymerization inhibitors.

Examples of polymerization inhibitors include 4-methoxy-1-naphthol, hydroquinone, hydroquinone methyl ether, dimethyl-t-butylphenol, 2,6-di-tert-butyl-p-cresol, and benzotriazole.

The content of the polymerization inhibitor is not limited. Generally, the content of the polymerization inhibitor is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant.

(4) Refrigeration Oil-Containing Working Fluid

The refrigeration oil-containing working fluid according to the present disclosure comprises at least the refrigerant or refrigerant composition according to the present disclosure and a refrigeration oil, for use as a working fluid in a refrigerating machine. Specifically, the refrigeration oil-containing working fluid according to the present disclosure is obtained by mixing a refrigeration oil used in a compressor of a refrigerating machine with the refrigerant or the refrigerant composition. The refrigeration oil-containing working fluid generally comprises 10 to 50 mass % of refrigeration oil.

(4-1) Refrigeration Oil

The refrigeration oil is not limited, and can be suitably selected from commonly used refrigeration oils. In this case, refrigeration oils that are superior in the action of increasing the miscibility with the mixture and the stability of the mixture, for example, are suitably selected as necessary.

The base oil of the refrigeration oil is preferably, for example, at least one member selected from the group consisting of polyalkylene glycols (PAG), polyol esters (POE), and polyvinyl ethers (PVE).

The refrigeration oil may further contain additives in addition to the base oil. The additive may be at least one member selected from the group consisting of antioxidants, extreme-pressure agents, acid scavengers, oxygen scavengers, copper deactivators, rust inhibitors, oil agents, and antifoaming agents.

A refrigeration oil with a kinematic viscosity of 5 to 400 cSt at 40° C. is preferable from the standpoint of lubrication.

The refrigeration oil-containing working fluid according to the present disclosure may further optionally contain at least one additive. Examples of additives include compatibilizing agents described below.

(4-2) Compatibilizing Agent

The refrigeration oil-containing working fluid according to the present disclosure may comprise a single compatibilizing agent, or two or more compatibilizing agents.

The compatibilizing agent is not limited, and can be suitably selected from commonly used compatibilizing agents.

Examples of compatibilizing agents include polyoxyalkylene glycol ethers, amides, nitriles, ketones, chlorocarbons, esters, lactones, aryl ethers, fluoroethers, and 1,1,1-trifluoroalkanes. The compatibilizing agent is particularly preferably a polyoxyalkylene glycol ether.

(5) Various Refrigerants

Hereinafter, the refrigerants A to E, which are the refrigerants used in the present embodiment, will be described in detail.

In addition, each description of the following refrigerant A, refrigerant B, refrigerant C, refrigerant D, and refrigerant E is each independent. The alphabet which shows a point or a line segment, the number of an Examples, and the number of a comparative examples are all independent of each other among the refrigerant A, the refrigerant B, the refrigerant C, the refrigerant D, and the refrigerant E. For example, the first embodiment of the refrigerant A and the first embodiment of the refrigerant B are different embodiment from each other.

(5-1) Refrigerant A

The refrigerant A according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

The refrigerant A according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., a refrigerating capacity and a coefficient of performance that are equivalent to those of R410A, and a sufficiently low GWP.

The refrigerant A according to the present disclosure is a composition comprising HFO-1132(E) and R1234yf, and optionally further comprising HFO-1123, and may further satisfy the following requirements. This refrigerant also has various properties desirable as an alternative refrigerant for R410A; i.e., it has a refrigerating capacity and a coefficient of performance that are equivalent to those of R410A, and a sufficiently low GWP.

Requirements

Preferable refrigerant A is as follows:

When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3,

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments BD, CO, and OA are straight lines.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A.

When the mass % of HFO-1132(E), HFO-1123, and R1234yf, based on their sum in the refrigerant A according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:

point G (72.0, 28.0, 0.0),

point I (72.0, 0.0, 28.0),
point A (68.6, 0.0, 31.4),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0), and
point C (32.9, 67.1, 0.0),
or on the above line segments (excluding the points on the line segment CG);

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments GI, IA, BD, and CG are straight lines.

When the requirements above are satisfied, the refrigerant A according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A; furthermore, the refrigerant A has a WCF lower flammability according to the ASHRAE Standard (the WCF composition has a burning velocity of 10 cm/s or less).

When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

the line segment PN is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment NK is represented by coordinates (x, 0.2421x²−29.955x+931.91, −0.2421x²+28.955x−831.91),

the line segment KA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, BD, and CG are straight lines.

When the requirements above are satisfied, the refrigerant A according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A; furthermore, the refrigerant exhibits a lower flammability (Class 2L) according to the ASHRAE Standard (the WCF composition and the WCFF composition have a burning velocity of 10 cm/s or less).

When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

point J (47.1, 52.9, 0.0),
point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0),
point M (60.3, 6.2, 33.5),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0), and
point (32.9, 67.1, 0.0),
or on the above line segments (excluding the points on the line segment CJ);

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, LM, BD, and CG are straight lines.

When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant A according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LM and BF are straight lines.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:

point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0),
point Q (62.8, 29.6, 7.6), and
point R (49.8, 42.3, 7.9),
or on the above line segments;

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment RP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LQ and QR are straight lines.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP of 95% or more relative to that of R410A, and an RCL of 40 g/m³or more, furthermore, the refrigerant has a condensation temperature glide of 1° C. or less.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:

point S (62.6, 28.3, 9.1),
point M (60.3, 6.2, 33.5),
point A′(30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point F (0.0, 61.8, 38.2), and
point T (35.8, 44.9, 19.3),
or on the above line segments,

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TS is represented by coordinates (x, −0.0017x²−0.7869x+70.888, −0.0017x²−0.2131x+29.112), and

the line segments SM and BF are straight lines.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, a COP of 95% or more relative to that of R410A, and an RCL of 40 g/m³or more furthermore, the refrigerant has a discharge pressure of 105% or more relative to that of R410A.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Od, dg, gh, and hO that connect the following 4 points:

point d (87.6, 0.0, 12.4),
point g (18.2, 55.1, 26.7),
point h (56.7, 43.3, 0.0), and
point o (100.0, 0.0, 0.0),
or on the line segments Od, dg, gh, and hO (excluding the points O and h);

the line segment dg is represented by coordinates (0.0047y²−1.5177y+87.598, y, −0.0047y²+0.5177y+12.402),

the line segment gh is represented by coordinates (−0.0134z²−1.0825z+56.692, 0.0134z²+0.0825z+43.308, z), and

the line segments hO and Od are straight lines.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf, based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments lg, gh, hi, and il that connect the following 4 points:

point l (72.5, 10.2, 17.3),
point g (18.2, 55.1, 26.7),
point h (56.7, 43.3, 0.0), and
point i (72.5, 27.5, 0.0) or
on the line segments lg, gh, and il (excluding the points h and i);

the line segment lg is represented by coordinates (0.0047y²−1.5177y+87.598, y, −0.0047y²+0.5177y+12.402),

the line gh is represented by coordinates (−0.0134z²−1.0825z+56.692, 0.0134z²+0.0825z+43.308, z), and

the line segments hi and il are straight lines.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Od, de, ef, and fO that connect the following 4 points:

point d (87.6, 0.0, 12.4),
point e (31.1, 42.9, 26.0),
point f (65.5, 34.5, 0.0), and
point O (100.0, 0.0, 0.0),
or on the line segments Od, de, and ef (excluding the points O and f);

the line segment de is represented by coordinates (0.0047y²−1.5177y+87.598, y, −0.0047y²+0.5177y+12.402),

the line segment ef is represented by coordinates (−0.0064z²−1.1565z+65.501, 0.0064z²+0.1565z+34.499, z), and

the line segments fO and Od are straight lines.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 93.5% or more relative to that of R410A, and a COP ratio of 93.5% or more relative to that of R410A.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,

coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments le, ef, fi, and il that connect the following 4 points:

point l (72.5, 10.2, 17.3),
point e (31.1, 42.9, 26.0),
point f (65.5, 34.5, 0.0), and
point i (72.5, 27.5, 0.0),
or on the line segments le, ef, and il (excluding the points f and i);

the line segment le is represented by coordinates (0.0047y²−1.5177y+87.598, y, −0.0047y²+0.5177y+12.402),

the line segment ef is represented by coordinates (−0.0134z²−1.0825z+56.692, 0.0134z²+0.0825z+43.308, z), and

the line segments fi and il are straight lines.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,

coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Oa, ab, bc, and cO that connect the following 4 points:

point a (93.4, 0.0, 6.6),
point b (55.6, 26.6, 17.8),
point c (77.6, 22.4, 0.0), and
point O (100.0, 0.0, 0.0),
or on the line segments Oa, ab, and bc (excluding the points O and c);

the line segment ab is represented by coordinates (0.0052y²−1.5588y+93.385, y, −0.0052y²+0.5588y+6.615),

the line segment bc is represented by coordinates (−0.0032z²−1.1791z+77.593, 0.0032z²+0.1791z+22.407, z), and

the line segments cO and Oa are straight lines.

The refrigerant A according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,

coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments kb, bj, and jk that connect the following 3 points:

point k (72.5, 14.1, 13.4),
point b (55.6, 26.6, 17.8), and
point j (72.5, 23.2, 4.3),
or on the line segments kb, bj, and jk;

the line segment kb is represented by coordinates (0.0052y²−1.5588y+93.385, y, and −0.0052y²+0.5588y+6.615),

the line segment bj is represented by coordinates (−0.0032z²−1.1791z+77.593, 0.0032z²+0.1791z+22.407, z), and

the line segment jk is a straight line.

When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to that of R410A, and a COP ratio of 95% or more relative to that of R410A; furthermore, the refrigerant has a lower flammability (Class 2L) according to the ASHRAE Standard.

The refrigerant according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, and R1234yf, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, and R1234yf in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more, based on the entire refrigerant.

The refrigerant according to the present disclosure may comprise HFO-1132(E), HFO-1123, and R1234yf in a total amount of 99.5 mass % or more, 99.75 mass % or more, or 99.9 mass % or more, based on the entire refrigerant.

Additional refrigerants are not particularly limited and can be widely selected. The mixed refrigerant may contain one additional refrigerant, or two or more additional refrigerants.

(Examples of Refrigerant A)

The present disclosure is described in more detail below with reference to Examples of refrigerant A. However, refrigerant A is not limited to the Examples.

The GWP of R1234yf and a composition consisting of a mixed refrigerant R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of R410A and compositions each comprising a mixture of HFO-1132(E), HFO-1123, and R1234yf was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.

Further, the RCL of the mixture was calculated with the LFL of HFO-1132(E) being 4.7 vol. %, the LFL of HFO-1123 being 10 vol. %, and the LFL of R1234yf being 6.2 vol. %, in accordance with the ASHRAE Standard 34-2013.

Evaporating temperature: 5° C.
Condensation temperature: 45° C.
Degree of superheating: 5 K
Degree of subcooling: 5 K
Compressor efficiency: 70%

Tables 1 to 34 show these values together with the GWP of each mixed refrigerant.

TABLE 1

			Comp.	Comp.		Exam-		Comp.
		Comp.	Ex. 2	Ex. 3	Exam-	ple 2	Exam-	Ex. 4
Item	Unit	Ex. 1	O	A	ple 1	A′	ple 3	B

HFO-1132(E)	mass %	R410A	100.0	68.6	49.0	30.6	14.1	0.0
HFO-1123	mass %		0.0	0.0	14.9	30.0	44.8	58.7
R1234yf	mass %		0.0	31.4	36.1	39.4	41.1	41.3
GWP	—	2088	1	2	2	2	2	2
COP ratio	% (relative	100	99.7	100.0	98.6	97.3	96.3	95.5
	to 410A)
Refrigerating	% (relative	100	98.3	85.0	85.0	85.0	85.0	85.0
capacity ratio	to 410A)
Condensation	° C.	0.1	0.00	1.98	3.36	4.46	5.15	5.35
glide
Discharge	% (relative	100.0	99.3	87.1	88.9	90.6	92.1	93.2
pressure	to 410A)
RCL	g/m³	—	30.7	37.5	44.0	52.7	64.0	78.6

TABLE 2

		Comp.		Exam-		Comp.	Comp.	Exam-	Comp.
		Ex. 5	Exam-	ple 5	Exam-	Ex. 6	Ex. 7	ple 7	Ex. 8
Item	Unit	C	ple 4	C′	ple 6	D	E	E′	F

HFO-1132(E)	mass %	32.9	26.6	19.5	10.9	0.0	58.0	23.4	0.0
HFO-1123	mass %	67.1	68.4	70.5	74.1	80.4	42.0	48.5	61.8
R1234yf	mass %	0.0	5.0	10.0	15.0	19.6	0.0	28.1	38.2
GWP	—	1	1	1	1	2	1	2	2
COP ratio	% (relative	92.5	92.5	92.5	92.5	92.5	95.0	95.0	95.0
	to 410A)
Refrigerating	% (relative	107.4	105.2	102.9	100.5	97.9	105.0	92.5	86.9
capacity ratio	to 410A)
Condensation	° C.	0.16	0.52	0.94	1.42	1.90	0.42	3.16	4.80
glide
Discharge	% (relative	119.5	117.4	115.3	113.0	115.9	112.7	101.0	95.8
pressure	to 410A)
RCL	g/m³	53.5	57.1	62.0	69.1	81.3	41.9	46.3	79.0

TABLE 3

		Comp.	Exam-	Exam-	Exam-	Exam-	Exam-
		Ex. 9	ple 8	ple 9	ple 10	ple 11	ple 12
Item	Unit	J	P	L	N	N′	K

HFO-1132(E)	mass %	47.1	55.8	63.1	68.6	65.0	61.3
HFO-1123	mass %	52.9	42.0	31.9	16.3	7.7	5.4
R1234yf	mass %	0.0	2.2	5.0	15.1	27.3	33.3
GWP	—	1	1	1	1	2	2
COP ratio	% (relative	93.8	95.0	96.1	97.9	99.1	99.5
	to 410A)
Refrigerating	% (relative	106.2	104.1	101.6	95.0	88.2	85.0
capacity ratio	to 410A)
Condensation	° C.	0.31	0.57	0.81	1.41	2.11	2.51
glide
Discharge	% (relative	115.8	111.9	107.8	99.0	91.2	87.7
pressure	to 410A)
RCL	g/m³	46.2	42.6	40.0	38.0	38.7	39.7

TABLE 4

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
		ple 13	ple 14	ple 15	ple 16	ple 17	ple 18	ple 19
Item	Unit	L	M	Q	R	S	S′	T

HFO-1132(E)	mass %	63.1	60.3	62.8	49.8	62.6	50.0	35.8
HFO-1123	mass %	31.9	6.2	29.6	42.3	28.3	35.8	44.9
R1234yf	mass %	5.0	33.5	7.6	7.9	9.1	14.2	19.3
GWP	—	1	2	1	1	1	1	2
COP ratio	% (relative	96.1	99.4	96.4	95.0	96.6	95.8	95.0
	to 410A)
Refrigerating	% (relative	101.6	85.0	100.2	101.7	99.4	98.1	96.7
capacity ratio	to 410A)
Condensation	° C.	0.81	2.58	1.00	1.00	1.10	1.55	2.07
glide
Discharge	% (relative	107.8	87.9	106.0	109.6	105.0	105.0	105.0
pressure	to 410A)
RCL	g/m³	40.0	40.0	40.0	44.8	40.0	44.4	50.8

TABLE 5

		Comp.	Example	Example
		Ex. 10	20	21
Item	Unit	G	H	I

HFO-1132(E)	mass %	72.0	72.0	72.0
HFO-1123	mass %	28.0	14.0	0.0
R1234yf	mass %	0.0	14.0	28.0
GWP	—	1	1	2
COP ratio	% (relative	96.6	98.2	99.9
	to 410A)
Refrigerating	% (relative	103.1	95.1	86.6
capacity ratio	to 410A)
Condensation glide	° C.	0.46	1.27	1.71
Discharge pressure	% (relative	108.4	98.7	88.6
	to 410A)
RCL	g/m³	37.4	37.0	36.6

TABLE 6

		Comp.	Comp.	Exam-	Exam-	Exam-	Exam-	Exam-	Comp.
Item	Unit	Ex. 11	Ex. 12	ple 22	ple 23	ple 24	ple 25	ple 26	Ex. 13

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
HFO-1123	mass %	85.0	75.0	65.0	55.0	45.0	35.0	25.0	15.0
R1234yf	mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	91.4	92.0	92.8	93.7	94.7	95.8	96.9	98.0
	to 410A)
Refrigerating	% (relative	105.7	105.5	105.0	104.3	103.3	102.0	100.6	99.1
capacity ratio	to 410A)
Condensation	° C.	0.40	0.46	0.55	0.66	0.75	0.80	0.79	0.67
glide
Discharge	% (relative	120.1	118.7	116.7	114.3	111.6	108.7	105.6	102.5
pressure	to 410A)
RCL	g/m³	71.0	61.9	54.9	49.3	44.8	41.0	37.8	35.1

TABLE 7

		Comp.	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Comp.
Item	Unit	Ex. 14	ple 27	ple 28	ple 29	ple 30	ple 31	ple 32	Ex. 15

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
HFO-1123	mass %	80.0	70.0	60.0	50.0	40.0	30.0	20.0	10.0
R1234yf	mass %	10.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	91.9	92.5	93.3	94.3	95.3	96.4	97.5	98.6
	to 410A)
Refrigerating	% (relative	103.2	102.9	102.4	101.5	100.5	99.2	97.8	96.2
capacity ratio	to 410A)
Condensation	° C.	0.87	0.94	1.03	1.12	1.18	1.18	1.09	0.88
glide
Discharge	% (relative	116.7	115.2	113.2	110.8	108.1	105.2	102.1	99.0
pressure	to 410A)
RCL	g/m³	70.5	61.6	54.6	49.1	44.6	40.8	37.7	35.0

TABLE 8

		Comp.	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Comp.
Item	Unit	Ex. 16	ple 33	ple 34	ple 35	ple 36	ple 37	ple 38	Ex. 17

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
HFO-1123	mass %	75.0	65.0	55.0	45.0	35.0	25.0	15.0	5.0
R1234yf	mass %	15.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	92.4	93.1	93.9	94.8	95.9	97.0	98.1	99.2
	to 410A)
Refrigerating	% (relative	100.5	100.2	99.6	98.7	97.7	96.4	94.9	93.2
capacity ratio	to 410A)
Condensation	° C.	1.41	1.49	1.56	1.62	1.63	1.55	1.37	1.05
glide
Discharge	% (relative	113.1	111.6	109.6	107.2	104.5	101.6	98.6	95.5
pressure	to 410A)
RCL	g/m³	70.0	61.2	54.4	48.9	44.4	40.7	37.5	34.8

TABLE 9

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 39	ple 40	ple 41	ple 42	ple 43	ple 44	ple 45

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0
HFO-1123	mass %	70.0	60.0	50.0	40.0	30.0	20.0	10.0
R1234yf	mass %	20.0	20.0	20.0	20.0	20.0	20.0	20.0
GWP	—	2	2	2	2	2	2	2
COP ratio	% (relative	93.0	93.7	94.5	95.5	96.5	97.6	98.7
	to 410A)
Refrigerating	% (relative	97.7	97.4	96.8	95.9	94.7	93.4	91.9
capacity ratio	to 410A)
Condensation	° C.	2.03	2.09	2.13	2.14	2.07	1.91	1.61
glide
Discharge	% (relative	109.4	107.9	105.9	103.5	100.8	98.0	95.0
pressure	to 410A)
RCL	g/m³	69.6	60.9	54.1	48.7	44.2	40.5	37.4

TABLE 10

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 46	ple 47	ple 48	ple 49	ple 50	ple 51	ple 52

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0
HFO-1123	mass %	65.0	55.0	45.0	35.0	25.0	15.0	5.0
R1234yf	mass %	25.0	25.0	25.0	25.0	25.0	25.0	25.0
GWP	—	2	2	2	2	2	2	2
COP ratio	% (relative	93.6	94.3	95.2	96.1	97.2	98.2	99.3
	to 410A)
Refrigerating	% (relative	94.8	94.5	93.8	92.9	91.8	90.4	88.8
capacity ratio	to 410A)
Condensation	° C.	2.71	2.74	2.73	2.66	2.50	2.22	1.78
glide
Discharge	% (relative	105.5	104.0	102.1	99.7	97.1	94.3	91.4
pressure	to 410A)
RCL	g/m³	69.1	60.5	53.8	48.4	44.0	40.4	37.3

TABLE 11

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 53	ple 54	ple 55	ple 56	ple 57	ple 58

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0
HFO-1123	mass %	60.0	50.0	40.0	30.0	20.0	10.0
R1234yf	mass %	30.0	30.0	30.0	30.0	30.0	30.0
GWP	—	2	2	2	2	2	2
COP ratio	% (relative	94.3	95.0	95.9	96.8	97.8	98.9
	to 410A)
Refrigerating	% (relative	91.9	91.5	90.8	89.9	88.7	87.3
capacity ratio	to 410A)
Condensation	° C.	3.46	3.43	3.35	3.18	2.90	2.47
glide
Discharge	% (relative	101.6	100.1	98.2	95.9	93.3	90.6
pressure	to 410A)
RCL	g/m³	68.7	60.2	53.5	48.2	43.9	40.2

TABLE 12

		Exam-	Exam-	Exam-	Exam-	Exam-	Comp.
Item	Unit	ple 59	ple 60	ple 61	ple 62	ple 63	Ex. 18

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0
HFO-1123	mass %	55.0	45.0	35.0	25.0	15.0	5.0
R1234yf	mass %	35.0	35.0	35.0	35.0	35.0	35.0
GWP	—	2	2	2	2	2	2
COP ratio	% (relative	95.0	95.8	96.6	97.5	98.5	99.6
	to 410A)
Refrigerating	% (relative	88.9	88.5	87.8	86.8	85.6	84.1
capacity ratio	to 410A)
Condensation	° C.	4.24	4.15	3.96	3.67	3.24	2.64
glide
Discharge	% (relative	97.6	96.1	94.2	92.0	89.5	86.8
pressure	to 410A)
RCL	g/m³	68.2	59.8	53.2	48.0	43.7	40.1

TABLE 13

		Exam-	Exam-	Comp.	Comp.	Comp.
Item	Unit	ple 64	ple 65	Ex. 19	Ex. 20	Ex. 21

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0
HFO-1123	mass %	50.0	40.0	30.0	20.0	10.0
R1234yf	mass %	40.0	40.0	40.0	40.0	40.0
GWP	—	2	2	2	2	2
COP ratio	% (relative	95.9	96.6	97.4	98.3	99.2
	to 410A)
Refrigerating	% (relative	85.8	85.4	84.7	83.6	82.4
capacity ratio	to 410A)
Condensation	° C.	5.05	4.85	4.55	4.10	3.50
glide
Discharge	% (relative	93.5	92.1	90.3	88.1	85.6
pressure	to 410A)
RCL	g/m³	67.8	59.5	53.0	47.8	43.5

TABLE 14

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 66	ple 67	ple 68	ple 69	ple 70	ple 71	ple 72	ple 73

HFO-1132(E)	mass %	54.0	56.0	58.0	62.0	52.0	54.0	56.0	58.0
HFO-1123	mass %	41.0	39.0	37.0	33.0	41.0	39.0	37.0	35.0
R1234yf	mass %	5.0	5.0	5.0	5.0	7.0	7.0	7.0	7.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	95.1	95.3	95.6	96.0	95.1	95.4	95.6	95.8
	to 410A)
Refrigerating	% (relative	102.8	102.6	102.3	101.8	101.9	101.7	101.5	101.2
capacity ratio	to 410A)
Condensation	° C.	0.78	0.79	0.80	0.81	0.93	0.94	0.95	0.95
glide
Discharge	% (relative	110.5	109.9	109.3	108.1	109.7	109.1	108.5	107.9
pressure	to 410A)
RCL	g/m³	43.2	42.4	41.7	40.3	43.9	43.1	42.4	41.6

TABLE 15

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 74	ple 75	ple 76	ple 77	ple 78	ple 79	ple 80	ple 81

HFO-1132(E)	mass %	60.0	62.0	61.0	58.0	60.0	62.0	52.0	54.0
HFO-1123	mass %	33.0	31.0	29.0	30.0	28.0	26.0	34.0	32.0
R1234yf	mass %	7.0	7.0	10.0	12.0	12.0	12.0	14.0	14.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	96.0	96.2	96.5	96.4	96.6	96.8	96.0	96.2
	to 410A)
Refrigerating	% (relative	100.9	100.7	99.1	98.4	98.1	97.8	98.0	97.7
capacity ratio	to 410A)
Condensation	° C.	0.95	0.95	1.18	1.34	1.33	1.32	1.53	1.53
glide
Discharge	% (relative	107.3	106.7	104.9	104.4	103.8	103.2	104.7	104.1
pressure	to 410A)
RCL	g/m³	40.9	40.3	40.5	41.5	40.8	40.1	43.6	42.9

TABLE 16

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 82	ple 83	ple 84	ple 85	ple 86	ple 87	ple 88	ple 89

HFO-1132(E)	mass %	56.0	58.0	60.0	48.0	50.0	52.0	54.0	56.0
HFO-1123	mass %	30.0	28.0	26.0	36.0	34.0	32.0	30.0	28.0
R1234yf	mass %	14.0	14.0	14.0	16.0	16.0	16.0	16.0	16.0
GWP	—	1	1	1	1	1	1	1	1
COP ratio	% (relative	96.4	96.6	96.9	95.8	96.0	96.2	96.4	96.7
	to 410A)
Refrigerating	% (relative	97.5	97.2	96.9	97.3	97.1	96.8	96.6	96.3
capacity ratio	to 410A)
Condensation	° C.	1.51	1.50	1.48	1.72	1.72	1.71	1.69	1.67
glide
Discharge	% (relative	103.5	102.9	102.3	104.3	103.8	103.2	102.7	102.1
pressure	to 410A)
RCL	g/m³	42.1	41.4	40.7	45.2	44.4	43.6	42.8	42.1

TABLE 17

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 90	ple 91	ple 92	ple 93	ple 94	ple 95	ple 96	ple 97

HFO-1132(E)	mass %	58.0	60.0	42.0	44.0	46.0	48.0	50.0	52.0
HFO-1123	mass %	26.0	24.0	40.0	38.0	36.0	34.0	32.0	30.0
R1234yf	mass %	16.0	16.0	18.0	18.0	18.0	18.0	18.0	18.0
GWP	—	1	1	2	2	2	2	2	2
COP ratio	% (relative	96.9	97.1	95.4	95.6	95.8	96.0	96.3	96.5
	to 410A)
Refrigerating	% (relative	96.1	95.8	96.8	96.6	96.4	96.2	95.9	95.7
capacity ratio	to 410A)
Condensation	° C.	1.65	1.63	1.93	1.92	1.92	1.91	1.89	1.88
glide
Discharge	% (relative	101.5	100.9	104.5	103.9	103.4	102.9	102.3	101.8
pressure	to 410A)
RCL	g/m³	41.4	40.7	47.8	46.9	46.0	45.1	44.3	43.5

TABLE 18

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 98	ple 99	ple 100	ple 101	ple 102	ple 103	ple 104	ple 105

HFO-1132(E)	mass %	54.0	56.0	58.0	60.0	36.0	38.0	42.0	44.0
HFO-1123	mass %	28.0	26.0	24.0	22.0	44.0	42.0	38.0	36.0
R1234yf	mass %	18.0	18.0	18.0	18.0	20.0	20.0	20.0	20.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.7	96.9	97.1	97.3	95.1	95.3	95.7	95.9
	to 410A)
Refrigerating	% (relative	95.4	95.2	94.9	94.6	96.3	96.1	95.7	95.4
capacity ratio	to 410A)
Condensation	° C.	1.86	1.83	1.80	1.77	2.14	2.14	2.13	2.12
glide
Discharge	% (relative	101.2	100.6	100.0	99.5	104.5	104.0	103.0	102.5
pressure	to 410A)
RCL	g/m³	42.7	42.0	41.3	40.6	50.7	49.7	47.7	46.8

TABLE 19

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 106	ple 107	ple 108	ple 109	ple 110	ple 111	ple 112	ple 113

HFO-1132(E)	mass %	46.0	48.0	52.0	54.0	56.0	58.0	34.0	36.0
HFO-1123	mass %	34.0	32.0	28.0	26.0	24.0	22.0	44.0	42.0
R1234yf	mass %	20.0	20.0	20.0	20.0	20.0	20.0	22.0	22.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.1	96.3	96.7	96.9	97.2	97.4	95.1	95.3
	to 410A)
Refrigerating	% (relative	95.2	95.0	94.5	94.2	94.0	93.7	95.3	95.1
capacity ratio	to 410A)
Condensation	° C.	2.11	2.09	2.05	2.02	1.99	1.95	2.37	2.36
glide
Discharge	% (relative	101.9	101.4	100.3	99.7	99.2	98.6	103.4	103.0
pressure	to 410A)
RCL	g/m³	45.9	45.0	43.4	42.7	41.9	41.2	51.7	50.6

TABLE 20

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 114	ple 115	ple 116	ple 117	ple 118	ple 119	ple 120	ple 121

HFO-1132(E)	mass %	38.0	40.0	42.0	44.0	46.0	48.0	50.0	52.0
HFO-1123	mass %	40.0	38.0	36.0	34.0	32.0	30.0	28.0	26.0
R1234yf	mass %	22.0	22.0	22.0	22.0	22.0	22.0	22.0	22.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	95.5	95.7	95.9	96.1	96.4	96.6	96.8	97.0
	to 410A)
Refrigerating	% (relative	94.9	94.7	94.5	94.3	94.0	93.8	93.6	93.3
capacity ratio	to 410A)
Condensation	° C.	2.36	2.35	2.33	2.32	2.30	2.27	2.25	2.21
glide
Discharge	% (relative	102.5	102.0	101.5	101.0	100.4	99.9	99.4	98.8
pressure	to 410A)
RCL	g/m³	49.6	48.6	47.6	46.7	45.8	45.0	44.1	43.4

TABLE 21

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 122	ple 123	ple 124	ple 125	ple 126	ple 127	ple 128	ple 129

HFO-1132(E)	mass %	54.0	56.0	58.0	60.0	32.0	34.0	36.0	38.0
HFO-1123	mass %	24.0	22.0	20.0	18.0	44.0	42.0	40.0	38.0
R1234yf	mass %	22.0	22.0	22.0	22.0	24.0	24.0	24.0	24.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.2	97.4	97.6	97.9	95.2	95.4	95.6	95.8
	to 410A)
Refrigerating	% (relative	93.0	92.8	92.5	92.2	94.3	94.1	93.9	93.7
capacity ratio	to 410A)
Condensation	° C.	2.18	2.14	2.09	2.04	2.61	2.60	2.59	2.58
glide
Discharge	% (relative	98.2	97.7	97.1	96.5	102.4	101.9	101.5	101.0
pressure	to 410A)
RCL	g/m³	42.6	41.9	41.2	40.5	52.7	51.6	50.5	49.5

TABLE 22

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 130	ple 131	ple 132	ple 133	ple 134	ple 135	ple 136	ple 137

HFO-1132(E)	mass %	40.0	42.0	44.0	46.0	48.0	50.0	52.0	54.0
HFO-1123	mass %	36.0	34.0	32.0	30.0	28.0	26.0	24.0	22.0
R1234yf	mass %	24.0	24.0	24.0	24.0	24.0	24.0	24.0	24.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.0	96.2	96.4	96.6	96.8	97.0	97.2	97.5
	to 410A)
Refrigerating	% (relative	93.5	93.3	93.1	92.8	92.6	92.4	92.1	91.8
capacity ratio	to 410A)
Condensation	° C.	2.56	2.54	2.51	2.49	2.45	2.42	2.38	2.33
glide
Discharge	% (relative	100.5	100.0	99.5	98.9	98.4	97.9	97.3	96.8
pressure	to 410A)
RCL	g/m³	48.5	47.5	46.6	45.7	44.9	44.1	43.3	42.5

TABLE 23

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 138	ple 139	ple 140	ple 141	ple 142	ple 143	ple 144	ple 145

HFO-1132(E)	mass %	56.0	58.0	60.0	30.0	32.0	34.0	36.0	38.0
HFO-1123	mass %	20.0	18.0	16.0	44.0	42.0	40.0	38.0	36.0
R1234yf	mass %	24.0	24.0	24.0	26.0	26.0	26.0	26.0	26.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.7	97.9	98.1	95.3	95.5	95.7	95.9	96.1
	to 410A)
Refrigerating	% (relative	91.6	91.3	91.0	93.2	93.1	92.9	92.7	92.5
capacity ratio	to 410A)
Condensation	° C.	2.28	2.22	2.16	2.86	2.85	2.83	2.81	2.79
glide
Discharge	% (relative	96.2	95.6	95.1	101.3	100.8	100.4	99.9	99.4
pressure	to 410A)
RCL	g/m³	41.8	41.1	40.4	53.7	52.6	51.5	50.4	49.4

TABLE 24

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 146	ple 147	ple 148	ple 149	ple 150	ple 151	ple 152	ple 153

HFO-1132(E)	mass %	40.0	42.0	44.0	46.0	48.0	50.0	52.0	54.0
HFO-1123	mass %	34.0	32.0	30.0	28.0	26.0	24.0	22.0	20.0
R1234yf	mass %	26.0	26.0	26.0	26.0	26.0	26.0	26.0	26.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.3	96.5	96.7	96.9	97.1	97.3	97.5	97.7
	to 410A)
Refrigerating	% (relative	92.3	92.1	91.9	91.6	91.4	91.2	90.9	90.6
capacity ratio	to 410A)
Condensation	° C.	2.77	2.74	2.71	2.67	2.63	2.59	2.53	2.48
glide
Discharge	% (relative	99.0	98.5	97.9	97.4	96.9	96.4	95.8	95.3
pressure	to 410A)
RCL	g/m³	48.4	47.4	46.5	45.7	44.8	44.0	43.2	42.5

TABLE 25

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 154	ple 155	ple 156	ple 157	ple 158	ple 159	ple 160	ple 161

HFO-1132(E)	mass %	56.0	58.0	60.0	30.0	32.0	34.0	36.0	38.0
HFO-1123	mass %	18.0	16.0	14.0	42.0	40.0	38.0	36.0	34.0
R1234yf	mass %	26.0	26.0	26.0	28.0	28.0	28.0	28.0	28.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.9	98.2	98.4	95.6	95.8	96.0	96.2	96.3
	to 410A)
Refrigerating	% (relative	90.3	90.1	89.8	92.1	91.9	91.7	91.5	91.3
capacity ratio	to 410A)
Condensation	° C.	2.42	2.35	2.27	3.10	3.09	3.06	3.04	3.01
glide
Discharge	% (relative	94.7	94.1	93.6	99.7	99.3	98.8	98.4	97.9
pressure	to 410A)
RCL	g/m³	41.7	41.0	40.3	53.6	52.5	51.4	50.3	49.3

TABLE 26

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 162	ple 163	ple 164	ple 165	ple 166	ple 167	ple 168	ple 169

HFO-1132(E)	mass %	40.0	42.0	44.0	46.0	48.0	50.0	52.0	54.0
HFO-1123	mass %	32.0	30.0	28.0	26.0	24.0	22.0	20.0	18.0
R1234yf	mass %	28.0	28.0	28.0	28.0	28.0	28.0	28.0	28.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.5	96.7	96.9	97.2	97.4	97.6	97.8	98.0
	to 410A)
Refrigerating	% (relative	91.1	90.9	90.7	90.4	90.2	89.9	89.7	89.4
capacity ratio	to 410A)
Condensation	° C.	2.98	2.94	2.90	2.85	2.80	2.75	2.68	2.62
glide
Discharge	% (relative	97.4	96.9	96.4	95.9	95.4	94.9	94.3	93.8
pressure	to 410A)
RCL	g/m³	48.3	47.4	46.4	45.6	44.7	43.9	43.1	42.4

TABLE 27

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 170	ple 171	ple 172	ple 173	ple 174	ple 175	ple 176	ple 177

HFO-1132(E)	mass %	56.0	58.0	60.0	32.0	34.0	36.0	38.0	42.0
HFO-1123	mass %	16.0	14.0	12.0	38.0	36.0	34.0	32.0	28.0
R1234yf	mass %	28.0	28.0	28.0	30.0	30.0	30.0	30.0	30.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	98.2	98.4	98.6	96.1	96.2	96.4	96.6	97.0
	to 410A)
Refrigerating	% (relative	89.1	88.8	88.5	90.7	90.5	90.3	90.1	89.7
capacity ratio	to 410A)
Condensation	° C.	2.54	2.46	2.38	3.32	3.30	3.26	3.22	3.14
glide
Discharge	% (relative	93.2	92.6	92.1	97.7	97.3	96.8	96.4	95.4
pressure	to 410A)
RCL	g/m³	41.7	41.0	40.3	52.4	51.3	50.2	49.2	47.3

TABLE 28

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 178	ple 179	ple 180	ple 181	ple 182	ple 183	ple 184	ple 185

HFO-1132(E)	mass %	44.0	46.0	48.0	50.0	52.0	54.0	56.0	58.0
HFO-1123	mass %	26.0	24.0	22.0	20.0	18.0	16.0	14.0	12.0
R1234yf	mass %	30.0	30.0	30.0	30.0	30.0	30.0	30.0	30.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.2	97.4	97.6	97.8	98.0	98.3	98.5	98.7
	to 410A)
Refrigerating	% (relative	89.4	89.2	89.0	88.7	88.4	88.2	87.9	87.6
capacity ratio	to 410A)
Condensation	° C.	3.08	3.03	2.97	2.90	2.83	2.75	2.66	2.57
glide
Discharge	% (relative	94.9	94.4	93.9	93.3	92.8	92.3	91.7	91.1
pressure	to 410A)
RCL	g/m³	46.4	45.5	44.7	43.9	43.1	42.3	41.6	40.9

TABLE 29

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 186	ple 187	ple 188	ple 189	ple 190	ple 191	ple 192	ple 193

HFO-1132(E)	mass %	30.0	32.0	34.0	36.0	38.0	40.0	42.0	44.0
HFO-1123	mass %	38.0	36.0	34.0	32.0	30.0	28.0	26.0	24.0
R1234yf	mass %	32.0	32.0	32.0	32.0	32.0	32.0	32.0	32.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.2	96.3	96.5	96.7	96.9	97.1	97.3	97.5
	to 410A)
Refrigerating	% (relative	89.6	89.5	89.3	89.1	88.9	88.7	88.4	88.2
capacity ratio	to 410A)
Condensation	° C.	3.60	3.56	3.52	3.48	3.43	3.38	3.33	3.26
glide
Discharge	% (relative	96.6	96.2	95.7	95.3	94.8	94.3	93.9	93.4
pressure	to 410A)
RCL	g/m³	53.4	52.3	51.2	50.1	49.1	48.1	47.2	46.3

TABLE 30

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 194	ple 195	ple 196	ple 197	ple 198	ple 199	ple 200	ple 201

HFO-1132(E)	mass %	46.0	48.0	50.0	52.0	54.0	56.0	58.0	60.0
HFO-1123	mass %	22.0	20.0	18.0	16.0	14.0	12.0	10.0	8.0
R1234yf	mass %	32.0	32.0	32.0	32.0	32.0	32.0	32.0	32.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.7	97.9	98.1	98.3	98.5	98.7	98.9	99.2
	to 410A)
Refrigerating	% (relative	88.0	87.7	87.5	87.2	86.9	86.6	86.3	86.0
capacity ratio	to 410A)
Condensation	° C.	3.20	3.12	3.04	2.96	2.87	2.77	2.66	2.55
glide
Discharge	% (relative	92.8	92.3	91.8	91.3	90.7	90.2	89.6	89.1
pressure	to 410A)
RCL	g/m³	45.4	44.6	43.8	43.0	42.3	41.5	40.8	40.2

TABLE 31

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 202	ple 203	ple 204	ple 205	ple 206	ple 207	ple 208	ple 209

HFO-1132(E)	mass %	30.0	32.0	34.0	36.0	38.0	40.0	42.0	44.0
HFO-1123	mass %	36.0	34.0	32.0	30.0	28.0	26.0	24.0	22.0
R1234yf	mass %	34.0	34.0	34.0	34.0	34.0	34.0	34.0	34.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	96.5	96.6	96.8	97.0	97.2	97.4	97.6	97.8
	to 410A)
Refrigerating	% (relative	88.4	88.2	88.0	87.8	87.6	87.4	87.2	87.0
capacity ratio	to 410A)
Condensation	° C.	3.84	3.80	3.75	3.70	3.64	3.58	3.51	3.43
glide
Discharge	% (relative	95.0	94.6	94.2	93.7	93.3	92.8	92.3	91.8
pressure	to 410A)
RCL	g/m³	53.3	52.2	51.1	50.0	49.0	48.0	47.1	46.2

TABLE 32

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 210	ple 211	ple 212	ple 213	ple 214	ple 215	ple 216	ple 217

HFO-1132(E)	mass %	46.0	48.0	50.0	52.0	54.0	30.0	32.0	34.0
HFO-1123	mass %	20.0	18.0	16.0	14.0	12.0	34.0	32.0	30.0
R1234yf	mass %	34.0	34.0	34.0	34.0	34.0	36.0	36.0	36.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	98.0	98.2	98.4	98.6	98.8	96.8	96.9	97.1
	to 410A)
Refrigerating	% (relative	86.7	86.5	86.2	85.9	85.6	87.2	87.0	86.8
capacity ratio	to 410A)
Condensation	° C.	3.36	3.27	3.18	3.08	2.97	4.08	4.03	3.97
glide
Discharge	% (relative	91.3	90.8	90.3	89.7	89.2	93.4	93.0	92.6
pressure	to 410A)
RCL	g/m³	45.3	44.5	43.7	42.9	42.2	53.2	52.1	51.0

TABLE 33

		Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-	Exam-
Item	Unit	ple 218	ple 219	ple 220	ple 221	ple 222	ple 223	ple 224	ple 225

HFO-1132(E)	mass %	36.0	38.0	40.0	42.0	44.0	46.0	30.0	32.0
HFO-1123	mass %	28.0	26.0	24.0	22.0	20.0	18.0	32.0	30.0
R1234yf	mass %	36.0	36.0	36.0	36.0	36.0	36.0	38.0	38.0
GWP	—	2	2	2	2	2	2	2	2
COP ratio	% (relative	97.3	97.5	97.7	97.9	98.1	98.3	97.1	97.2
	to 410A)
Refrigerating	% (relative	86.6	86.4	86.2	85.9	85.7	85.5	85.9	85.7
capacity ratio	to 410A)
Condensation	° C.	3.91	3.84	3.76	3.68	3.60	3.50	4.32	4.25
glide
Discharge	% (relative	92.1	91.7	91.2	90.7	90.3	89.8	91.9	91.4
pressure	to 410A)
RCL	g/m³	49.9	48.9	47.9	47.0	46.1	45.3	53.1	52.0

TABLE 34

		Example	Example
Item	Unit	226	227

HFO-1132(E)	mass %	34.0	36.0
HFO-1123	mass %	28.0	26.0
R1234yf	mass %	38.0	38.0
GWP	—	2	2
COP ratio	% (relative	97.4	97.6
	to 410A)
Refrigerating	% (relative	85.6	85.3
capacity ratio	to 410A)
Condensation glide	° C.	4.18	4.11
Discharge pressure	% (relative	91.0	90.6
	to 410A)
RCL	g/m³	50.9	49.8

These results indicate that under the condition that the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:

point A (68.6, 0.0, 31.4),
point A′(30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point D (0.0, 80.4, 19.6),
point C′ (19.5, 70.5, 10.0),
point C (32.9, 67.1, 0.0), and
point O (100.0, 0.0, 0.0),
or on the above line segments (excluding the points on the line segment CO);
the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),
the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3,
the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),
the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and
the line segments BD, CO, and OA are straight lines,
the refrigerant has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A.

The point on the line segment AA′ was determined by obtaining an approximate curve connecting point A, Example 1, and point A′ by the least square method.

The point on the line segment A′B was determined by obtaining an approximate curve connecting point A′, Example 3, and point B by the least square method.

The point on the line segment DC′ was determined by obtaining an approximate curve connecting point D, Example 6, and point C′ by the least square method.

The point on the line segment C′C was determined by obtaining an approximate curve connecting point C′, Example 4, and point C by the least square method.

Likewise, the results indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments AA′, A′B, BF, FT, TE, EO, and OA that connect the following 7 points:

point A (68.6, 0.0, 31.4),
point A′ (30.6, 30.0, 39.4),
point B (0.0, 58.7, 41.3),
point F (0.0, 61.8, 38.2),
point T (35.8, 44.9, 19.3),
point E (58.0, 42.0, 0.0) and
point O (100.0, 0.0, 0.0),
or on the above line segments (excluding the points on the line EO);
the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),
the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),
the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2), and
the line segment TE is represented by coordinates (x, 0.0067x²−0.7607x+63.525, −0.0067x²−0.2393x+36.475), and
the line segments BF, FO, and OA are straight lines,
the refrigerant has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 95% or more relative to that of R410A.

The point on the line segment FT was determined by obtaining an approximate curve connecting three points, i.e., points T, E′, and F, by the least square method.

The point on the line segment TE was determined by obtaining an approximate curve connecting three points, i.e., points E, R, and T, by the least square method.

The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which the sum of these components is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below the line segment LM connecting point L (63.1, 31.9, 5.0) and point M (60.3, 6.2, 33.5), the refrigerant has an RCL of 40 g/m³or more.

The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123 and R1234yf in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on the line segment QR connecting point Q (62.8, 29.6, 7.6) and point R (49.8, 42.3, 7.9) or on the left side of the line segment, the refrigerant has a temperature glide of 1° C. or less.

The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on the line segment ST connecting point S (62.6, 28.3, 9.1) and point T (35.8, 44.9, 19.3) or on the right side of the line segment, the refrigerant has a discharge pressure of 105% or less relative to that of 410A.

In these compositions, R1234yf contributes to reducing flammability, and suppressing deterioration of polymerization etc. Therefore, the composition preferably contains R1234yf.

Further, the burning velocity of these mixed refrigerants whose mixed formulations were adjusted to WCF concentrations was measured according to the ANSI/ASHRAE Standard 34-2013. Compositions having a burning velocity of 10 cm/s or less were determined to be classified as “Class 2L (lower flammability).”

A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. In FIG. 1, reference numeral 901 refers to a sample cell, 902 refers to a high-speed camera, 903 refers to a xenon lamp, 904 refers to a collimating lens, 905 refers to a collimating lens, and 906 refers to a ring filter. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.

Each WCFF concentration was obtained by using the WCF concentration as the initial concentration and performing a leak simulation using NIST Standard Reference Database REFLEAK Version 4.0.

Tables 35 and 36 show the results.

TABLE 35

Item	Unit	G	H	I

WCF	HFO-1132(E)	mass %	72.0	72.0	72.0
	HFO-1123	mass %	28.0	9.6	0.0
	R1234yf	mass %	0.0	18.4	28.0

Burning velocity (WCF)	cm/s	10	10	10

TABLE 36

Item	Unit	J	P	L	N	N′	K

WCF	HFO-1132(E)	mass %	47.1	55.8	63.1	68.6	65.0	61.3
	HFO-1123	mass %	52.9	42.0	31.9	16.3	7.7	5.4
	R1234yf	mass %	0.0	2.2	5.0	15.1	27.3	33.3

Leak condition that	Storage/	Storage/	Storage/	Storage/	Storage/	Storage/
results in WCFF	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping, −40°
	C., 92%	C., 90%	C., 90%	C., 66%	C., 12%	C., 0%
	release,	release,	release,	release,	release,	release,
	liquid	liquid	gas phase	gas phase	gas phase	gas phase
	phase side	phase side	side	side	side	side

WCFF	HFO-1132(E)	mass %	72.0	72.0	72.0	72.0	72.0	72.0
	HFO-1123	mass %	28.0	17.8	17.4	13.6	12.3	9.8
	R1234yf	mass %	0.0	10.2	10.6	14.4	15.7	18.2

Burning	cm/s	8 or less	8 or less	8 or less	9	9	8 or less
velocity (WCF)
Burning	cm/s	10	10	10	10	10	10
velocity (WCFF)

The results in Table 35 clearly indicate that when a mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf contains HFO-1132(E) in a proportion of 72.0 mass % or less based on their sum, the refrigerant can be determined to have a WCF lower flammability.

The results in Tables 36 clearly indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which their sum is 100 mass %, and a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base,

when coordinates (x,y,z) are on or below the line segments JP, PN, and NK connecting the following 6 points:
point J (47.1, 52.9, 0.0),
point P (55.8, 42.0, 2.2),
point L (63.1, 31.9, 5.0)
point N (68.6, 16.3, 15.1)
point N′ (65.0, 7.7, 27.3) and
point K (61.3, 5.4, 33.3),
the refrigerant can be determined to have a WCF lower flammability, and a WCFF lower flammability.
In the diagram, the line segment PN is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),
and the line segment NK is represented by coordinates (x, 0.2421x²−29.955x+931.91, −0.2421x²+28.955x−831.91).

The point on the line segment PN was determined by obtaining an approximate curve connecting three points, i.e., points P, L, and N, by the least square method.

The point on the line segment NK was determined by obtaining an approximate curve connecting three points, i.e., points N, N′, and K, by the least square method.

(5-2) Refrigerant B

The refrigerant B according to the present disclosure is

a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprising 62.0 mass % to 72.0 mass % or 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant, or

a mixed refrigerant comprising HFO-1132(E) and HFO-1123 in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprising 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.

The refrigerant B according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., (1) a coefficient of performance equivalent to that of R410A, (2) a refrigerating capacity equivalent to that of R410A, (3) a sufficiently low GWP, and (4) a lower flammability (Class 2L) according to the ASHRAE standard.

When the refrigerant B according to the present disclosure is a mixed refrigerant comprising 72.0 mass % or less of HFO-1132(E), it has WCF lower flammability. When the refrigerant B according to the present disclosure is a composition comprising 47.1% or less of HFO-1132(E), it has WCF lower flammability and WCFF lower flammability, and is determined to be “Class 2L,” which is a lower flammable refrigerant according to the ASHRAE standard, and which is further easier to handle.

When the refrigerant B according to the present disclosure comprises 62.0 mass % or more of HFO-1132(E), it becomes superior with a coefficient of performance of 95% or more relative to that of R410A, the polymerization reaction of HFO-1132(E) and/or HFO-1123 is further suppressed, and the stability is further improved. When the refrigerant B according to the present disclosure comprises 45.1 mass % or more of HFO-1132(E), it becomes superior with a coefficient of performance of 93% or more relative to that of R410A, the polymerization reaction of HFO-1132(E) and/or HFO-1123 is further suppressed, and the stability is further improved.

The refrigerant B according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E) and HFO-1123, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E) and HFO-1123 in a total amount of 99.75 mass % or more, and more preferably 99.9 mass % or more, based on the entire refrigerant.

Such additional refrigerants are not limited, and can be selected from a wide range of refrigerants. The mixed refrigerant may comprise a single additional refrigerant, or two or more additional refrigerants.

(Examples of Refrigerant B)

The present disclosure is described in more detail below with reference to Examples of refrigerant B. However, the refrigerant B is not limited to the Examples.

Mixed refrigerants were prepared by mixing HFO-1132(E) and HFO-1123 at mass % based on their sum shown in Tables 37 and 38.

The GWP of compositions each comprising a mixture of R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of compositions each comprising R410A and a mixture of HFO-1132(E) and HFO-1123 was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.

Evaporating temperature: 5° C.
Condensation temperature: 45° C.
Superheating temperature: 5 K
Subcooling temperature: 5 K
Compressor efficiency: 70%

The composition of each mixture was defined as WCF. A leak simulation was performed using NIST Standard Reference Data Base Refleak Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

Tables 1 and 2 show GWP, COP, and refrigerating capacity, which were calculated based on these results. The COP and refrigerating capacity are ratios relative to R410A.

The coefficient of performance (COP) was determined by the following formula.

COP=(refrigerating capacity or heating capacity)/power consumption

For the flammability, the burning velocity was measured according to the ANSI/ASHRAE Standard 34-2013. Both WCF and WCFF having a burning velocity of 10 cm/s or less were determined to be “Class 2L (lower flammability).”

A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.

TABLE 37

		Comparative	Comparative
		Example 1	Example 2	Comparative	Exam-	Exam-	Exam-	Exam-	Exam-	Comparative
Item	Unit	R410A	HFO-1132E	Example 3	ple 1	ple 2	ple 3	ple 4	ple 5	Example 4

HFO-1132E	mass %	—	100	80	72	70	68	65	62	60
(WCF)
HFO-1123	mass %		0	20	28	30	32	35	38	40
(WCF)
GWP	—	2088	1	1	1	1	1	1	1	1
COP ratio	% (relative	100	99.7	97.5	96.6	96.3	96.1	95.8	95.4	95.2
	to R410A)
Refrigerating	% (relative	100	98.3	101.9	103.1	103.4	103.8	104.1	104.5	104.8
capacity ratio	to R410A)
Discharge	Mpa	2.73	2.71	2.89	2.96	2.98	3.00	3.02	3.04	3.06
pressure
Burning	cm/sec	Non-	20	13	10	9	9	8	8 or	8 or
velocity		flammable							less	less
(WCF)

TABLE 38

		Comparative	Comparative
Item	Unit	Example 5	Example 6	Example 7	Example 8	Example 9

HFO-1132E	mass %	50	48	47.1	46.1	45.1
(WCF)
HFO-1123	mass %	50	52	52.9	53.9	54.9
(WCF)
GWP	—	1	1	1	1	1
COP ratio	% (relative	94.1	93.9	93.8	93.7	93.6
	to R410A)
Refrigerating	% (relative	105.9	106.1	106.2	106.3	106.4
capacity ratio	to R410A)
Discharge	Mpa	3.14	3.16	3.16	3.17	3.18
pressure

Leakage test	Storage/	Storage/	Storage/	Storage/	Storage/
conditions (WCFF)	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°
	C., 92%	C., 92%	C., 92%	C., 92%	C., 92%
	release,	release,	release,	release,	release,
	liquid	liquid	liquid	liquid	liquid
	phase side	phase side	phase side	phase side	phase side

HFO-1132E	mass %	74	73	72	71	70
(WCFF)
HFO-1123	mass %	26	27	28	29	30
(WCFF)
Burning	cm/sec	8 or less	8 or less	8 or less	8 or less	8 or less
velocity
(WCF)
Burning	cm/sec	11	10.5	10.0	9.5	9.5
velocity
(WCFF)

ASHRAE flammability	2	2	2L	2L	2L
classification

					Comparative
		Comparative	Comparative	Comparative	Example 10
Item	Unit	Example 7	Example 8	Example 9	HFO-1123

HFO-1132E	mass %	43	40	25	0
(WCF)
HFO-1123	mass %	57	60	75	100
(WCF)
GWP	—	1	1	1	1
COP ratio	% (relative	93.4	93.1	91.9	90.6
	to R410A)
Refrigerating	% (relative	106.6	106.9	107.9	108.0
capacity ratio	to R410A)
Discharge	Mpa	3.20	3.21	3.31	3.39
pressure

Leakage test	Storage/	Storage/	Storage/	—
conditions (WCFF)	Shipping −40°	Shipping −40°	Shipping −40°
	C., 92%	C., 92%	C., 90%
	release,	release,	release,
	liquid	liquid	liquid
	phase side	phase side	phase side

HFO-1132E	mass %	67	63	38	—
(WCFF)
HFO-1123	mass %	33	37	62
(WCFF)
Burning	cm/sec	8 or less	8 or less	8 or less	5
velocity
(WCF)
Burning	cm/sec	8.5	8 or less	8 or less
velocity
(WCFF)

ASHRAE flammability	2L	2L	2L	2L
classification

The compositions each comprising 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire composition are stable while having a low GWP (GWP=1), and they ensure WCF lower flammability. Further, surprisingly, they can ensure performance equivalent to that of R410A. Moreover, compositions each comprising 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire composition are stable while having a low GWP (GWP=1), and they ensure WCFF lower flammability. Further, surprisingly, they can ensure performance equivalent to that of R410A.

(5-3) Refrigerant C

The refrigerant C according to the present disclosure is a composition comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32), and satisfies the following requirements. The refrigerant C according to the present disclosure has various properties that are desirable as an alternative refrigerant for R410A; i.e. it has a coefficient of performance and a refrigerating capacity that are equivalent to those of R410A, and a sufficiently low GWP.

Requirements

Preferable refrigerant C is as follows:

When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a,

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.02a²−1.6013a+71.105, −0.02a²+0.6013a+28.895, 0.0),
point I (0.02a²−1.6013a+71.105, 0.0, −0.02a²+0.6013a+28.895),
point A (0.0112a²−1.9337a+68.484, 0.0, −0.0112a²+0.9337a+31.516),
point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0135a²−1.4068a+69.727, −0.0135a²+0.4068a+30.273, 0.0),
point I (0.0135a²−1.4068a+69.727, 0.0, −0.0135a²+0.4068a+30.273),
point A (0.0107a²−1.9142a+68.305, 0.0, −0.0107a²+0.9142a+31.695),
point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0111a²−1.3152a+68.986, −0.0111a²+0.3152a+31.014, 0.0),
point I (0.0111a²−1.3152a+68.986, 0.0, −0.0111a²+0.3152a+31.014),
point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),
point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W); and

if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0061a²−0.9918a+63.902, −0.0061a²−0.0082a+36.098, 0.0),
point I (0.0061a²−0.9918a+63.902, 0.0, −0.0061a²−0.0082a+36.098),
point A (0.0085a²−1.8102a+67.1, 0.0, −0.0085a²+0.8102a+32.9),
point B (0.0, 0.0012a²−1.1659a+52.95, −0.0012a²+0.1659a+47.05) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W). When the refrigerant according to the present disclosure satisfies the above requirements, it has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A, and further ensures a WCF lower flammability.

The refrigerant C according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,

if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines JK′, K′B, BD′, D′C, and CJ that connect the following 5 points:

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0243a²−1.4161a+49.725, −0.0243a²+0.4161a+50.275, 0.0),
point K′ (0.0341a²−2.1977a+61.187, −0.0236a²+0.34a+5.636, −0.0105a²+0.8577a+33.177),
point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0246a²−1.4476a+50.184, −0.0246a²+0.4476a+49.816, 0.0),
point K′ (0.0196a²−1.7863a+58.515, −0.0079a²−0.1136a+8.702, −0.0117a²+0.8999a+32.783),
point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

point J (0.0183a²−1.1399a+46.493, −0.0183a²+0.1399a+53.507, 0.0),
point K′ (−0.0051a²+0.0929a+25.95, 0.0, 0.0051a²−1.0929a+74.05),
point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),
point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W); and

point J (−0.0134a²+1.0956a+7.13, 0.0134a²−2.0956a+92.87, 0.0),
point K′ (−1.892a+29.443, 0.0, 0.892a+70.557),
point A (0.0085a²−1.8102a+67.1, 0.0, −0.0085a²+0.8102a+32.9),
point B (0.0, 0.0012a²−1.1659a+52.95, −0.0012a²+0.1659a+47.05) and
point W (0.0, 100.0−a, 0.0),
or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W). When the refrigerant according to the present disclosure satisfies the above requirements, it has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A. Additionally, the refrigerant has a WCF lower flammability and a WCFF lower flammability, and is classified as “Class 2L,” which is a lower flammable refrigerant according to the ASHRAE standard.

When the refrigerant C according to the present disclosure further contains R32 in addition to HFO-1132 (E), HFO-1123, and R1234yf, the refrigerant may be a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a,

if 0<a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines that connect the following 4 points:

point a (0.02a²−2.46a+93.4, 0, −0.02a²+2.46a+6.6),
point b′ (−0.008a²−1.38a+56, 0.018a²−0.53a+26.3, −0.01a²+1.91a+17.7),
point c (−0.016a²+1.02a+77.6, 0.016a²−1.02a+22.4, 0), and
point o (100.0−a, 0.0, 0.0)
or on the straight lines oa, ab′, and b′c (excluding point o and point c);

if 10.0<a≤16.5, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines that connect the following 4 points:

point a (0.0244a²−2.5695a+94.056, 0, −0.0244a²+2.5695a+5.944),
point b′ (0.1161a²−1.9959a+59.749, 0.014a²−0.3399a+24.8, −0.1301a²+2.3358a+15.451),
point c (−0.0161a²+1.02a+77.6, 0.0161a²−1.02a+22.4, 0), and
point o (100.0−a, 0.0, 0.0),
or on the straight lines oa, ab′, and b′c (excluding point o and point c); or

if 16.5<a≤21.8, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines that connect the following 4 points:

point a (0.0161a²−2.3535a+92.742, 0, −0.0161a²+2.3535a+7.258),
point b′ (−0.0435a²−0.0435a+50.406, 0.0304a²+1.8991a−0.0661, 0.0739a²−1.8556a+49.6601),
point c (−0.0161a²+0.9959a+77.851, 0.0161a²−0.9959a+22.149, 0), and
point o (100.0−a, 0.0, 0.0),
or on the straight lines oa, ab′, and b′c (excluding point o and point c). Note that when point b in the ternary composition diagram is defined as a point where a refrigerating capacity ratio of 95% relative to that of R410A and a COP ratio of 95% relative to that of R410A are both achieved, point b′ is the intersection of straight line ab and an approximate line formed by connecting the points where the COP ratio relative to that of R410A is 95%. When the refrigerant according to the present disclosure meets the above requirements, the refrigerant has a refrigerating capacity ratio of 95% or more relative to that of R410A, and a COP ratio of 95% or more relative to that of R410A.

The refrigerant C according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, R1234yf, and R32 as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, R1234yf, and R32 in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more, based on the entire refrigerant.

The refrigerant C according to the present disclosure may comprise HFO-1132(E), HFO-1123, R1234yf, and R32 in a total amount of 99.5 mass % or more, 99.75 mass % or more, or 99.9 mass % or more, based on the entire refrigerant.

Additional refrigerants are not particularly limited and can be widely selected. The mixed refrigerant may contain one additional refrigerant, or two or more additional refrigerants.

(Examples of Refrigerant C)

The present disclosure is described in more detail below with reference to Examples of refrigerant C. However, the refrigerant C is not limited to the Examples.

Mixed refrigerants were prepared by mixing HFO-1132(E), HFO-1123, R1234yf, and R32 at mass % based on their sum shown in Tables 39 to 96.

For each of these mixed refrigerants, the COP ratio and the refrigerating capacity ratio relative to those of R410 were obtained. Calculation was conducted under the following conditions.

Evaporating temperature: 5° C.

Condensation temperature: 45° C.

Superheating temperature: 5 K

Subcooling temperature: 5 K

Compressor efficiency: 70%

Tables 39 to 96 show the resulting values together with the GWP of each mixed refrigerant. The COP and refrigerating capacity are ratios relative to R410A.

The coefficient of performance (COP) was determined by the following formula.

COP=(refrigerating capacity or heating capacity)/power consumption

TABLE 39

			Comp.	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Comp.	Ex. 2	Ex. 3	Ex. 4	Ex. 5	Ex. 6	Ex. 7	Ex. 8	Ex. 1
Item	Unit	Ex. 1	A	B	C	D′	G	I	J	K′

HFO-1132(E)	Mass %	R410A	68.6	0.0	32.9	0.0	72.0	72.0	47.1	61.7
HFO-1123	Mass %		0.0	58.7	67.1	75.4	28.0	0.0	52.9	5.9
R1234yf	Mass %		31.4	41.3	0.0	24.6	0.0	28.0	0.0	32.4
R32	Mass %		0.0	0.0	0.0	0.0	0.0	0.0	0.0	0.0
GWP	—	2088	2	2	1	2	1	2	1	2
COP ratio	% (relative	100	100.0	95.5	92.5	93.1	96.6	99.9	93.8	99.4
	to R410A)
Refrigerating	% (relative	100	85.0	85.0	107.4	95.0	103.1	86.6	106.2	85.5
capacity ratio	to R410A)

TABLE 40

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 9	Ex. 10	Ex. 11	Ex. 12	Ex. 13	Ex. 14	Ex. 15	Ex. 2
Item	Unit	A	B	C	D′	G	I	J	K′

HFO-1132(E)	Mass %	55.3	0.0	18.4	0.0	60.9	60.9	40.5	47.0
HFO-1123	Mass %	0.0	47.8	74.5	83.4	32.0	0.0	52.4	7.2
R1234yf	Mass %	37.6	45.1	0.0	9.5	0.0	32.0	0.0	38.7
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	49	49	49	50	49	50
COP ratio	% (relative	99.8	96.9	92.5	92.5	95.9	99.6	94.0	99.2
	to R410A)
Refrigerating	% (relative	85.0	85.0	110.5	106.0	106.5	87.7	108.9	85.5
capacity ratio	to R410A)

TABLE 41

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 16	Ex. 17	Ex. 18	Ex. 19	Ex. 20	Ex. 21	Ex. 3
Item	Unit	A	B	C = D′	G	I	J	K′

HFO-1132(E)	Mass %	48.4	0.0	0.0	55.8	55.8	37.0	41.0
HFO-1123	Mass %	0.0	42.3	88.9	33.1	0.0	51.9	6.5
R1234yf	Mass %	40.5	46.6	0.0	0.0	33.1	0.0	41.4
R32	Mass %	11.1	11.1	11.1	11.1	11.1	11.1	11.1
GWP	—	77	77	76	76	77	76	77
COP ratio	% (relative	99.8	97.6	92.5	95.8	99.5	94.2	99.3
	to R410A)
Refrigerating	% (relative	85.0	85.0	112.0	108.0	88.6	110.2	85.4
capacity ratio	to R410A)

TABLE 42

		Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 22	Ex. 23	Ex. 24	Ex. 25	Ex. 26	Ex. 4
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	42.8	0.0	52.1	52.1	34.3	36.5
HFO-1123	Mass %	0.0	37.8	33.4	0.0	51.2	5.6
R1234yf	Mass %	42.7	47.7	0.0	33.4	0.0	43.4
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	100	100	99	100	99	100
COP ratio	% (relative	99.9	98.1	95.8	99.5	94.4	99.5
	to R410A)
Refrigerating	% (relative	85.0	85.0	109.1	89.6	111.1	85.3
capacity ratio	to R410A)

TABLE 43

		Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 27	Ex. 28	Ex. 29	Ex. 30	Ex. 31	Ex. 5
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	37.0	0.0	48.6	48.6	32.0	32.5
HFO-1123	Mass %	0.0	33.1	33.2	0.0	49.8	4.0
R1234yf	Mass %	44.8	48.7	0.0	33.2	0.0	45.3
R32	Mass %	18.2	18.2	18.2	18.2	18.2	18.2
GWP	—	125	125	124	125	124	125
COP ratio	% (relative	100.0	98.6	95.9	99.4	94.7	99.8
	to R410A)
Refrigerating	% (relative	85.0	85.0	110.1	90.8	111.9	85.2
capacity ratio	to R410A)

TABLE 44

		Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 32	Ex. 33	Ex. 34	Ex. 35	Ex. 36	Ex. 6
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	31.5	0.0	45.4	45.4	30.3	28.8
HFO-1123	Mass %	0.0	28.5	32.7	0.0	47.8	2.4
R1234yf	Mass %	46.6	49.6	0.0	32.7	0.0	46.9
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	150	150	149	150	149	150
COP ratio	% (relative	100.2	99.1	96.0	99.4	95.1	100.0
	to R410A)
Refrigerating	% (relative	85.0	85.0	111.0	92.1	112.6	85.1
capacity ratio	to R410A)

TABLE 45

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 37	Ex. 38	Ex. 39	Ex. 40	Ex. 41	Ex. 42
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	24.8	0.0	41.8	41.8	29.1	24.8
HFO-1123	Mass %	0.0	22.9	31.5	0.0	44.2	0.0
R1234yf	Mass %	48.5	50.4	0.0	31.5	0.0	48.5
R32	Mass %	26.7	26.7	26.7	26.7	26.7	26.7
GWP	—	182	182	181	182	181	182
COP ratio	% (relative	100.4	99.8	96.3	99.4	95.6	100.4
	to R410A)
Refrigerating	% (relative	85.0	85.0	111.9	93.8	113.2	85.0
capacity ratio	to R410A)

TABLE 46

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 43	Ex. 44	Ex. 45	Ex. 46	Ex. 47	Ex. 48
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	21.3	0.0	40.0	40.0	28.8	24.3
HFO-1123	Mass %	0.0	19.9	30.7	0.0	41.9	0.0
R1234yf	Mass %	49.4	50.8	0.0	30.7	0.0	46.4
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	200	200	198	199	198	200
COP ratio	% (relative	100.6	100.1	96.6	99.5	96.1	100.4
	to R410A)
Refrigerating	% (relative	85.0	85.0	112.4	94.8	113.6	86.7
capacity ratio	to R410A)

TABLE 47

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 49	Ex. 50	Ex. 51	Ex. 52	Ex. 53	Ex. 54
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	12.1	0.0	35.7	35.7	29.3	22.5
HFO-1123	Mass %	0.0	11.7	27.6	0.0	34.0	0.0
R1234yf	Mass %	51.2	51.6	0.0	27.6	0.0	40.8
R32	Mass %	36.7	36.7	36.7	36.7	36.7	36.7
GWP	—	250	250	248	249	248	250
COP ratio	% (relative	101.2	101.0	96.4	99.6	97.0	100.4
	to R410A)
Refrigerating	% (relative	85.0	85.0	113.2	97.6	113.9	90.9
capacity ratio	to R410A)

TABLE 48

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 55	Ex. 56	Ex. 57	Ex. 58	Ex. 59	Ex. 60
Item	Unit	A	B	G	I	J	K′

HFO-1132(E)	Mass %	3.8	0.0	32.0	32.0	29.4	21.1
HFO-1123	Mass %	0.0	3.9	23.9	0.0	26.5	0.0
R1234yf	Mass %	52.1	52.0	0.0	23.9	0.0	34.8
R32	Mass %	44.1	44.1	44.1	44.1	44.1	44.1
GWP	—	300	300	298	299	298	299
COP ratio	% (relative	101.8	101.8	97.9	99.8	97.8	100.5
	to R410A)
Refrigerating	% (relative	85.0	85.0	113.7	100.4	113.9	94.9
capacity ratio	to R410A)

TABLE 49

		Comp.	Comp.	Comp.	Comp.	Comp.
		Ex. 61	Ex. 62	Ex. 63	Ex. 64	Ex. 65
Item	Unit	A = B	G	I	J	K′

HFO-1132(E)	Mass %	0.0	30.4	30.4	28.9	20.4
HFO-1123	Mass %	0.0	21.8	0.0	23.3	0.0
R1234yf	Mass %	52.2	0.0	21.8	0.0	31.8
R32	Mass %	47.8	47.8	47.8	47.8	47.8
GWP	—	325	323	324	323	324
COP ratio	% (relative	102.1	98.2	100.0	98.2	100.6
	to R410A)
Refrigerating	% (relative	85.0	113.8	101.8	113.9	96.8
capacity ratio	to R410A)

TABLE 50

		Comp.
Item	Unit	Ex. 66	Ex. 7	Ex. 8	Ex. 9	Ex. 10	Ex. 11	Ex. 12	Ex. 13

HFO-1132(E)	Mass %	5.0	10.0	15.0	20.0	25.0	30.0	35.0	40.0
HFO-1123	Mass %	82.9	77.9	72.9	67.9	62.9	57.9	52.9	47.9
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	92.4	92.6	92.8	93.1	93.4	93.7	94.1	94.5
	to R410A)
Refrigerating	% (relative	108.4	108.3	108.2	107.9	107.6	107.2	106.8	106.3
capacity ratio	to R410A)

TABLE 51

						Comp.
Item	Unit	Ex. 14	Ex. 15	Ex. 16	Ex. 17	Ex. 67	Ex. 18	Ex. 19	Ex. 20

HFO-1132(E)	Mass %	45.0	50.0	55.0	60.0	65.0	10.0	15.0	20.0
HFO-1123	Mass %	42.9	37.9	32.9	27.9	22.9	72.9	67.9	62.9
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	10.0	10.0	10.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	95.0	95.4	95.9	96.4	96.9	93.0	93.3	93.6
	to R410A)
Refrigerating	% (relative	105.8	105.2	104.5	103.9	103.1	105.7	105.5	105.2
capacity ratio	to R410A)

TABLE 52

Item	Unit	Ex. 21	Ex. 22	Ex. 23	Ex. 24	Ex. 25	Ex. 26	Ex. 27	Ex. 28

HFO-1132(E)	Mass %	25.0	30.0	35.0	40.0	45.0	50.0	55.0	60.0
HFO-1123	Mass %	57.9	52.9	47.9	42.9	37.9	32.9	27.9	22.9
R1234yf	Mass %	10.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	93.9	94.2	94.6	95.0	95.5	96.0	96.4	96.9
	to R410A)
Refrigerating	% (relative	104.9	104.5	104.1	103.6	103.0	102.4	101.7	101.0
capacity ratio	to R410A)

TABLE 53

		Comp.
Item	Unit	Ex. 68	Ex. 29	Ex. 30	Ex. 31	Ex. 32	Ex. 33	Ex. 34	Ex. 35

HFO-1132(E)	Mass %	65.0	10.0	15.0	20.0	25.0	30.0	35.0	40.0
HFO-1123	Mass %	17.9	67.9	62.9	57.9	52.9	47.9	42.9	37.9
R1234yf	Mass %	10.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	97.4	93.5	93.8	94.1	94.4	94.8	95.2	95.6
	to R410A)
Refrigerating	% (relative	100.3	102.9	102.7	102.5	102.1	101.7	101.2	100.7
capacity ratio	to R410A)

TABLE 54

						Comp.
Item	Unit	Ex. 36	Ex. 37	Ex. 38	Ex. 39	Ex. 69	Ex. 40	Ex. 41	Ex. 42

HFO-1132(E)	Mass %	45.0	50.0	55.0	60.0	65.0	10.0	15.0	20.0
HFO-1123	Mass %	32.9	27.9	22.9	17.9	12.9	62.9	57.9	52.9
R1234yf	Mass %	15.0	15.0	15.0	15.0	15.0	20.0	20.0	20.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	96.0	96.5	97.0	97.5	98.0	94.0	94.3	94.6
	to R410A)
Refrigerating	% (relative	100.1	99.5	98.9	98.1	97.4	100.1	99.9	99.6
capacity ratio	to R410A)

TABLE 55

Item	Unit	Ex. 43	Ex. 44	Ex. 45	Ex. 46	Ex. 47	Ex. 48	Ex. 49	Ex. 50

HFO-1132(E)	Mass %	25.0	30.0	35.0	40.0	45.0	50.0	55.0	60.0
HFO-1123	Mass %	47.9	42.9	37.9	32.9	27.9	22.9	17.9	12.9
R1234yf	Mass %	20.0	20.0	20.0	20.0	20.0	20.0	20.0	20.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	49	49	49	49	49	49	49
COP ratio	% (relative	95.0	95.3	95.7	96.2	96.6	97.1	97.6	98.1
	to R410A)
Refrigerating	% (relative	99.2	98.8	98.3	97.8	97.2	96.6	95.9	95.2
capacity ratio	to R410A)

TABLE 56

		Comp.
Item	Unit	Ex. 70	Ex. 51	Ex. 52	Ex. 53	Ex. 54	Ex. 55	Ex. 56	Ex. 57

HFO-1132(E)	Mass %	65.0	10.0	15.0	20.0	25.0	30.0	35.0	40.0
HFO-1123	Mass %	7.9	57.9	52.9	47.9	42.9	37.9	32.9	27.9
R1234yf	Mass %	20.0	25.0	25.0	25.0	25.0	25.0	25.0	25.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	49	50	50	50	50	50	50	50
COP ratio	% (relative	98.6	94.6	94.9	95.2	95.5	95.9	96.3	96.8
	to R410A)
Refrigerating	% (relative	94.4	97.1	96.9	96.7	96.3	95.9	95.4	94.8
capacity ratio	to R410A)

TABLE 57

						Comp.
Item	Unit	Ex. 58	Ex. 59	Ex. 60	Ex. 61	Ex. 71	Ex. 62	Ex. 63	Ex. 64

HFO-1132(E)	Mass %	45.0	50.0	55.0	60.0	65.0	10.0	15.0	20.0
HFO-1123	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
R1234yf	Mass %	25.0	25.0	25.0	25.0	25.0	30.0	30.0	30.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	50	50	50	50	50	50
COP ratio	% (relative	97.2	97.7	98.2	98.7	99.2	95.2	95.5	95.8
	to R410A)
Refrigerating	% (relative	94.2	93.6	92.9	92.2	91.4	94.2	93.9	93.7
capacity ratio	to R410A)

TABLE 58

Item	Unit	Ex. 65	Ex. 66	Ex. 67	Ex. 68	Ex. 69	Ex. 70	Ex. 71	Ex. 72

HFO-1132(E)	Mass %	25.0	30.0	35.0	40.0	45.0	50.0	55.0	60.0
HFO-1123	Mass %	37.9	32.9	27.9	22.9	17.9	12.9	7.9	2.9
R1234yf	Mass %	30.0	30.0	30.0	30.0	30.0	30.0	30.0	30.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	50	50	50	50	50	50
COP ratio	% (relative	96.2	96.6	97.0	97.4	97.9	98.3	98.8	99.3
	to R410A)
Refrigerating	% (relative	93.3	92.9	92.4	91.8	91.2	90.5	89.8	89.1
capacity ratio	to R410A)

TABLE 59

Item	Unit	Ex. 73	Ex. 74	Ex. 75	Ex. 76	Ex. 77	Ex. 78	Ex. 79	Ex. 80

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	47.9	42.9	37.9	32.9	27.9	22.9	17.9	12.9
R1234yf	Mass %	35.0	35.0	35.0	35.0	35.0	35.0	35.0	35.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	50	50	50	50	50	50
COP ratio	% (relative	95.9	96.2	96.5	96.9	97.2	97.7	98.1	98.5
	to R410A)
Refrigerating	% (relative	91.1	90.9	90.6	90.2	89.8	89.3	88.7	88.1
capacity ratio	to R410A)

TABLE 60

Item	Unit	Ex. 81	Ex. 82	Ex. 83	Ex. 84	Ex. 85	Ex. 86	Ex. 87	Ex. 88

HFO-1132(E)	Mass %	50.0	55.0	10.0	15.0	20.0	25.0	30.0	35.0
HFO-1123	Mass %	7.9	2.9	42.9	37.9	32.9	27.9	22.9	17.9
R1234yf	Mass %	35.0	35.0	40.0	40.0	40.0	40.0	40.0	40.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	50	50	50	50	50	50
COP ratio	% (relative	99.0	99.4	96.6	96.9	97.2	97.6	98.0	98.4
	to R410A)
Refrigerating	% (relative	87.4	86.7	88.0	87.8	87.5	87.1	86.6	86.1
capacity ratio	to R410A)

TABLE 61

		Comp.	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Unit	Ex. 72	Ex. 73	Ex. 74	Ex. 75	Ex. 76	Ex. 77	Ex. 78	Ex. 79

HFO-1132(E)	Mass %	40.0	45.0	50.0	10.0	15.0	20.0	25.0	30.0
HFO-1123	Mass %	12.9	7.9	2.9	37.9	32.9	27.9	22.9	17.9
R1234yf	Mass %	40.0	40.0	40.0	45.0	45.0	45.0	45.0	45.0
R32	Mass %	7.1	7.1	7.1	7.1	7.1	7.1	7.1	7.1
GWP	—	50	50	50	50	50	50	50	50
COP ratio	% (relative	98.8	99.2	99.6	97.4	97.7	98.0	98.3	98.7
	to R410A)
Refrigerating	% (relative	85.5	84.9	84.2	84.9	84.6	84.3	83.9	83.5
capacity ratio	to R410A)

TABLE 62

		Comp.	Comp.	Comp.
Item	Unit	Ex. 80	Ex. 81	Ex. 82

HFO-1132(E)	Mass %	35.0	40.0	45.0
HFO-1123	Mass %	12.9	7.9	2.9
R1234yf	Mass %	45.0	45.0	45.0
R32	Mass %	7.1	7.1	7.1
GWP	—	50	50	50
COP ratio	% (relative	99.1	99.5	99.9
	to R410A)
Refrigerating	% (relative	82.9	82.3	81.7
capacity ratio	to R410A)

TABLE 63

Item	Unit	Ex. 89	Ex. 90	Ex. 91	Ex. 92	Ex. 93	Ex. 94	Ex. 95	Ex. 96

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	70.5	65.5	60.5	55.5	50.5	45.5	40.5	35.5
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	93.7	93.9	94.1	94.4	94.7	95.0	95.4	95.8
	to R410A)
Refrigerating	% (relative	110.2	110.0	109.7	109.3	108.9	108.4	107.9	107.3
capacity ratio	to R410A)

TABLE 64

			Comp.
Item	Unit	Ex. 97	Ex. 83	Ex. 98	Ex. 99	Ex. 100	Ex. 101	Ex. 102	Ex. 103

HFO-1132(E)	Mass %	50.0	55.0	10.0	15.0	20.0	25.0	30.0	35.0
HFO-1123	Mass %	30.5	25.5	65.5	60.5	55.5	50.5	45.5	40.5
R1234yf	Mass %	5.0	5.0	10.0	10.0	10.0	10.0	10.0	10.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	96.2	96.6	94.2	94.4	94.6	94.9	95.2	95.5
	to R410A)
Refrigerating	% (relative	106.6	106.0	107.5	107.3	107.0	106.6	106.1	105.6
capacity ratio	to R410A)

TABLE 65

					Comp.
Item	Unit	Ex. 104	Ex. 105	Ex. 106	Ex. 84	Ex. 107	Ex. 108	Ex. 109	Ex. 110

HFO-1132(E)	Mass %	40.0	45.0	50.0	55.0	10.0	15.0	20.0	25.0
HFO-1123	Mass %	35.5	30.5	25.5	20.5	60.5	55.5	50.5	45.5
R1234yf	Mass %	10.0	10.0	10.0	10.0	15.0	15.0	15.0	15.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	95.9	96.3	96.7	97.1	94.6	94.8	95.1	95.4
	to R410A)
Refrigerating	% (relative	105.1	104.5	103.8	103.1	104.7	104.5	104.1	103.7
capacity ratio	to R410A)

TABLE 66

							Comp.
Item	Unit	Ex. 111	Ex. 112	Ex. 113	Ex. 114	Ex. 115	Ex. 85	Ex. 116	Ex. 117

HFO-1132(E)	Mass %	30.0	35.0	40.0	45.0	50.0	55.0	10.0	15.0
HFO-1123	Mass %	40.5	35.5	30.5	25.5	20.5	15.5	55.5	50.5
R1234yf	Mass %	15.0	15.0	15.0	15.0	15.0	15.0	20.0	20.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	95.7	96.0	96.4	96.8	97.2	97.6	95.1	95.3
	to R410A)
Refrigerating	% (relative	103.3	102.8	102.2	101.6	101.0	100.3	101.8	101.6
capacity ratio	to R410A)

TABLE 67

									Comp.
Item	Unit	Ex. 118	Ex. 119	Ex. 120	Ex. 121	Ex. 122	Ex. 123	Ex. 124	Ex. 86

HFO-1132(E)	Mass %	20.0	25.0	30.0	35.0	40.0	45.0	50.0	55.0
HFO-1123	Mass %	45.5	40.5	35.5	30.5	25.5	20.5	15.5	10.5
R1234yf	Mass %	20.0	20.0	20.0	20.0	20.0	20.0	20.0	20.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	95.6	95.9	96.2	96.5	96.9	97.3	97.7	98.2
	to R410A)
Refrigerating	% (relative	101.2	100.8	100.4	99.9	99.3	98.7	98.0	97.3
capacity ratio	to R410A)

TABLE 68

Item	Unit	Ex. 125	Ex. 126	Ex. 127	Ex. 128	Ex. 129	Ex. 130	Ex. 131	Ex. 132

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	50.5	45.5	40.5	35.5	30.5	25.5	20.5	15.5
R1234yf	Mass %	25.0	25.0	25.0	25.0	25.0	25.0	25.0	25.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	99	99	99	99	99	99
COP ratio	% (relative	95.6	95.9	96.1	96.4	96.7	97.1	97.5	97.9
	to R410A)
Refrigerating	% (relative	98.9	98.6	98.3	97.9	97.4	96.9	96.3	95.7
capacity ratio	to R410A)

TABLE 69

			Comp.
Item	Unit	Ex. 133	Ex. 87	Ex. 134	Ex. 135	Ex. 136	Ex. 137	Ex. 138	Ex. 139

HFO-1132(E)	Mass %	50.0	55.0	10.0	15.0	20.0	25.0	30.0	35.0
HFO-1123	Mass %	10.5	5.5	45.5	40.5	35.5	30.5	25.5	20.5
R1234yf	Mass %	25.0	25.0	30.0	30.0	30.0	30.0	30.0	30.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	99	99	100	100	100	100	100	100
COP ratio	% (relative	98.3	98.7	96.2	96.4	96.7	97.0	97.3	97.7
	to R410A)
Refrigerating	% (relative	95.0	94.3	95.8	95.6	95.2	94.8	94.4	93.8
capacity ratio	to R410A)

TABLE 70

Item	Unit	Ex. 140	Ex. 141	Ex. 142	Ex. 143	Ex. 144	Ex. 145	Ex. 146	Ex. 147

HFO-1132(E)	Mass %	40.0	45.0	50.0	10.0	15.0	20.0	25.0	30.0
HFO-1123	Mass %	15.5	10.5	5.5	40.5	35.5	30.5	25.5	20.5
R1234yf	Mass %	30.0	30.0	30.0	35.0	35.0	35.0	35.0	35.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	100	100	100	100	100	100	100	100
COP ratio	% (relative	98.1	98.5	98.9	96.8	97.0	97.3	97.6	97.9
	to R410A)
Refrigerating	% (relative	93.3	92.6	92.0	92.8	92.5	92.2	91.8	91.3
capacity ratio	to R410A)

TABLE 71

Item	Unit	Ex. 148	Ex. 149	Ex. 150	Ex. 151	Ex. 152	Ex. 153	Ex. 154	Ex. 155

HFO-1132(E)	Mass %	35.0	40.0	45.0	10.0	15.0	20.0	25.0	30.0
HFO-1123	Mass %	15.5	10.5	5.5	35.5	30.5	25.5	20.5	15.5
R1234yf	Mass %	35.0	35.0	35.0	40.0	40.0	40.0	40.0	40.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	100	100	100	100	100	100	100	100
COP ratio	% (relative	98.3	98.7	99.1	97.4	97.7	98.0	98.3	98.6
	to R410A)
Refrigerating	% (relative	90.8	90.2	89.6	89.6	89.4	89.0	88.6	88.2
capacity ratio	to R410A)

TABLE 72

							Comp.	Comp.	Comp.
Item	Unit	Ex. 156	Ex. 157	Ex. 158	Ex. 159	Ex. 160	Ex. 88	Ex. 89	Ex. 90

HFO-1132(E)	Mass %	35.0	40.0	10.0	15.0	20.0	25.0	30.0	35.0
HFO-1123	Mass %	10.5	5.5	30.5	25.5	20.5	15.5	10.5	5.5
R1234yf	Mass %	40.0	40.0	45.0	45.0	45.0	45.0	45.0	45.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5	14.5	14.5	14.5
GWP	—	100	100	100	100	100	100	100	100
COP ratio	% (relative	98.9	99.3	98.1	98.4	98.7	98.9	99.3	99.6
	to R410A)
Refrigerating	% (relative	87.6	87.1	86.5	86.2	85.9	85.5	85.0	84.5
capacity ratio	to R410A)

TABLE 73

		Comp.	Comp.	Comp.	Comp.	Comp.
Item	Unit	Ex. 91	Ex. 92	Ex. 93	Ex. 94	Ex. 95

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0
HFO-1123	Mass %	25.5	20.5	15.5	10.5	5.5
R1234yf	Mass %	50.0	50.0	50.0	50.0	50.0
R32	Mass %	14.5	14.5	14.5	14.5	14.5
GWP	—	100	100	100	100	100
COP ratio	% (relative	98.9	99.1	99.4	99.7	100.0
	to R410A)
Refrigerating	% (relative	83.3	83.0	82.7	82.2	81.8
capacity ratio	to R410A)

TABLE 74

Item	Unit	Ex. 161	Ex. 162	Ex. 163	Ex. 164	Ex. 165	Ex. 166	Ex. 167	Ex. 168

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	63.1	58.1	53.1	48.1	43.1	38.1	33.1	28.1
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	149	149	149
COP ratio	% (relative	94.8	95.0	95.2	95.4	95.7	95.9	96.2	96.6
	to R410A)
Refrigerating	% (relative	111.5	111.2	110.9	110.5	110.0	109.5	108.9	108.3
capacity ratio	to R410A)

TABLE 75

		Comp.
Item	Unit	Ex. 96	Ex. 169	Ex. 170	Ex. 171	Ex. 172	Ex. 173	Ex. 174	Ex. 175

HFO-1132(E)	Mass %	50.0	10.0	15.0	20.0	25.0	30.0	35.0	40.0
HFO-1123	Mass %	23.1	58.1	53.1	48.1	43.1	38.1	33.1	28.1
R1234yf	Mass %	5.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	149	149	149
COP ratio	% (relative	96.9	95.3	95.4	95.6	95.8	96.1	96.4	96.7
	to R410A)
Refrigerating	% (relative	107.7	108.7	108.5	108.1	107.7	107.2	106.7	106.1
capacity ratio	to R410A)

TABLE 76

			Comp.
Item	Unit	Ex. 176	Ex. 97	Ex. 177	Ex. 178	Ex. 179	Ex. 180	Ex. 181	Ex. 182

HFO-1132(E)	Mass %	45.0	50.0	10.0	15.0	20.0	25.0	30.0	35.0
HFO-1123	Mass %	23.1	18.1	53.1	48.1	43.1	38.1	33.1	28.1
R1234yf	Mass %	10.0	10.0	15.0	15.0	15.0	15.0	15.0	15.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	149	149	149
COP ratio	% (relative	97.0	97.4	95.7	95.9	96.1	96.3	96.6	96.9
	to R410A)
Refrigerating	% (relative	105.5	104.9	105.9	105.6	105.3	104.8	104.4	103.8
capacity ratio	to R410A)

TABLE 77

				Comp.
Item	Unit	Ex. 183	Ex. 184	Ex. 98	Ex. 185	Ex. 186	Ex. 187	Ex. 188	Ex. 189

HFO-1132(E)	Mass %	40.0	45.0	50.0	10.0	15.0	20.0	25.0	30.0
HFO-1123	Mass %	23.1	18.1	13.1	48.1	43.1	38.1	33.1	28.1
R1234yf	Mass %	15.0	15.0	15.0	20.0	20.0	20.0	20.0	20.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	149	149	149
COP ratio	% (relative	97.2	97.5	97.9	96.1	96.3	96.5	96.8	97.1
	to R410A)
Refrigerating	% (relative	103.3	102.6	102.0	103.0	102.7	102.3	101.9	101.4
capacity ratio	to R410A)

TABLE 78

					Comp.
Item	Unit	Ex. 190	Ex. 191	Ex. 192	Ex. 99	Ex. 193	Ex. 194	Ex. 195	Ex. 196

HFO-1132(E)	Mass %	35.0	40.0	45.0	50.0	10.0	15.0	20.0	25.0
HFO-1123	Mass %	23.1	18.1	13.1	8.1	43.1	38.1	33.1	28.1
R1234yf	Mass %	20.0	20.0	20.0	20.0	25.0	25.0	25.0	25.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	149	149	149
COP ratio	% (relative	97.4	97.7	98.0	98.4	96.6	96.8	97.0	97.3
	to R410A)
Refrigerating	% (relative	100.9	100.3	99.7	99.1	100.0	99.7	99.4	98.9
capacity ratio	to R410A)

TABLE 79

						Comp.
Item	Unit	Ex. 197	Ex. 198	Ex. 199	Ex. 200	Ex. 100	Ex. 201	Ex. 202	Ex. 203

HFO-1132(E)	Mass %	30.0	35.0	40.0	45.0	50.0	10.0	15.0	20.0
HFO-1123	Mass %	23.1	18.1	13.1	8.1	3.1	38.1	33.1	28.1
R1234yf	Mass %	25.0	25.0	25.0	25.0	25.0	30.0	30.0	30.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	149	149	149	149	149	150	150	150
COP ratio	% (relative	97.6	97.9	98.2	98.5	98.9	97.1	97.3	97.6
	to R410A)
Refrigerating	% (relative	98.5	97.9	97.4	96.8	96.1	97.0	96.7	96.3
capacity ratio	to R410A)

TABLE 80

Item	Unit	Ex. 204	Ex. 205	Ex. 206	Ex. 207	Ex. 208	Ex. 209	Ex. 210	Ex. 211

HFO-1132(E)	Mass %	25.0	30.0	35.0	40.0	45.0	10.0	15.0	20.0
HFO-1123	Mass %	23.1	18.1	13.1	8.1	3.1	33.1	28.1	23.1
R1234yf	Mass %	30.0	30.0	30.0	30.0	30.0	35.0	35.0	35.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	150	150	150	150	150	150	150	150
COP ratio	% (relative	97.8	98.1	98.4	98.7	99.1	97.7	97.9	98.1
	to R410A)
Refrigerating	% (relative	95.9	95.4	94.9	94.4	93.8	93.9	93.6	93.3
capacity ratio	to R410A)

TABLE 81

Item	Unit	Ex. 212	Ex. 213	Ex. 214	Ex. 215	Ex. 216	Ex. 217	Ex. 218	Ex. 219

HFO-1132(E)	Mass %	25.0	30.0	35.0	40.0	10.0	15.0	20.0	25.0
HFO-1123	Mass %	18.1	13.1	8.1	3.1	28.1	23.1	18.1	13.1
R1234yf	Mass %	35.0	35.0	35.0	35.0	40.0	40.0	40.0	40.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	150	150	150	150	150	150	150	150
COP ratio	% (relative	98.4	98.7	99.0	99.3	98.3	98.5	98.7	99.0
	to R410A)
Refrigerating	% (relative	92.9	92.4	91.9	91.3	90.8	90.5	90.2	89.7
capacity ratio	to R410A)

TABLE 82

									Comp.
Item	Unit	Ex. 220	Ex. 221	Ex. 222	Ex. 223	Ex. 224	Ex. 225	Ex. 226	Ex. 101

HFO-1132(E)	Mass %	30.0	35.0	10.0	15.0	20.0	25.0	30.0	10.0
HFO-1123	Mass %	8.1	3.1	23.1	18.1	13.1	8.1	3.1	18.1
R1234yf	Mass %	40.0	40.0	45.0	45.0	45.0	45.0	45.0	50.0
R32	Mass %	21.9	21.9	21.9	21.9	21.9	21.9	21.9	21.9
GWP	—	150	150	150	150	150	150	150	150
COP ratio	% (relative	99.3	99.6	98.9	99.1	99.3	99.6	99.9	99.6
	to R410A)
Refrigerating	% (relative	89.3	88.8	87.6	87.3	87.0	86.6	86.2	84.4
capacity ratio	to R410A)

TABLE 83

		Comp.	Comp.	Comp.
Item	Unit	Ex. 102	Ex. 103	Ex. 104

HFO-1132(E)	Mass %	15.0	20.0	25.0
HFO-1123	Mass %	13.1	8.1	3.1
R1234yf	Mass %	50.0	50.0	50.0
R32	Mass %	21.9	21.9	21.9
GWP	—	150	150	150
COP ratio	% (relative	99.8	100.0	100.2
	to R410A)
Refrigerating	% (relative	84.1	83.8	83.4
capacity ratio	to R410A)

TABLE 84

									Comp.
Item	Unit	Ex. 227	Ex. 228	Ex. 229	Ex. 230	Ex. 231	Ex. 232	Ex. 233	Ex. 105

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	55.7	50.7	45.7	40.7	35.7	30.7	25.7	20.7
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	199	199	199
COP ratio	% (relative	95.9	96.0	96.2	96.3	96.6	96.8	97.1	97.3
	to R410A)
Refrigerating	% (relative	112.2	111.9	111.6	111.2	110.7	110.2	109.6	109.0
capacity ratio	to R410A)

TABLE 85

									Comp.
Item	Unit	Ex. 234	Ex. 235	Ex. 236	Ex. 237	Ex. 238	Ex. 239	Ex. 240	Ex. 106

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	50.7	45.7	40.7	35.7	30.7	25.7	20.7	15.7
R1234yf	Mass %	10.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	199	199	199
COP ratio	% (relative	96.3	96.4	96.6	96.8	97.0	97.2	97.5	97.8
	to R410A)
Refrigerating	% (relative	109.4	109.2	108.8	108.4	107.9	107.4	106.8	106.2
capacity ratio	to R410A)

TABLE 86

									Comp.
Item	Unit	Ex. 241	Ex. 242	Ex. 243	Ex. 244	Ex. 245	Ex. 246	Ex. 247	Ex. 107

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	45.7	40.7	35.7	30.7	25.7	20.7	15.7	10.7
R1234yf	Mass %	15.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	199	199	199
COP ratio	% (relative	96.7	96.8	97.0	97.2	97.4	97.7	97.9	98.2
	to R410A)
Refrigerating	% (relative	106.6	106.3	106.0	105.5	105.1	104.5	104.0	103.4
capacity ratio	to R410A)

TABLE 87

									Comp.
Item	Unit	Ex. 248	Ex. 249	Ex. 250	Ex. 251	Ex. 252	Ex. 253	Ex. 254	Ex. 108

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	45.0
HFO-1123	Mass %	40.7	35.7	30.7	25.7	20.7	15.7	10.7	5.7
R1234yf	Mass %	20.0	20.0	20.0	20.0	20.0	20.0	20.0	20.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	199	199	199
COP ratio	% (relative	97.1	97.3	97.5	97.7	97.9	98.1	98.4	98.7
	to R410A)
Refrigerating	% (relative	103.7	103.4	103.0	102.6	102.2	101.6	101.1	100.5
capacity ratio	to R410A)

TABLE 88

Item	Unit	Ex. 255	Ex. 256	Ex. 257	Ex. 258	Ex. 259	Ex. 260	Ex. 261	Ex. 262

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	40.0	10.0
HFO-1123	Mass %	35.7	30.7	25.7	20.7	15.7	10.7	5.7	30.7
R1234yf	Mass %	25.0	25.0	25.0	25.0	25.0	25.0	25.0	30.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	199	199	199
COP ratio	% (relative	97.6	97.7	97.9	98.1	98.4	98.6	98.9	98.1
	to R410A)
Refrigerating	% (relative	100.7	100.4	100.1	99.7	99.2	98.7	98.2	97.7
capacity ratio	to R410A)

TABLE 89

Item	Unit	Ex. 263	Ex. 264	Ex. 265	Ex. 266	Ex. 267	Ex. 268	Ex. 269	Ex. 270

HFO-1132(E)	Mass %	15.0	20.0	25.0	30.0	35.0	10.0	15.0	20.0
HFO-1123	Mass %	25.7	20.7	15.7	10.7	5.7	25.7	20.7	15.7
R1234yf	Mass %	30.0	30.0	30.0	30.0	30.0	35.0	35.0	35.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	199	199	199	199	199	200	200	200
COP ratio	% (relative	98.2	98.4	98.6	98.9	99.1	98.6	98.7	98.9
	to R410A)
Refrigerating	% (relative	97.4	97.1	96.7	96.2	95.7	94.7	94.4	94.0
capacity ratio	to R410A)

TABLE 90

Item	Unit	Ex. 271	Ex. 272	Ex. 273	Ex. 274	Ex. 275	Ex. 276	Ex. 277	Ex. 278

HFO-1132(E)	Mass %	25.0	30.0	10.0	15.0	20.0	25.0	10.0	15.0
HFO-1123	Mass %	10.7	5.7	20.7	15.7	10.7	5.7	15.7	10.7
R1234yf	Mass %	35.0	35.0	40.0	40.0	40.0	40.0	45.0	45.0
R32	Mass %	29.3	29.3	29.3	29.3	29.3	29.3	29.3	29.3
GWP	—	200	200	200	200	200	200	200	200
COP ratio	% (relative	99.2	99.4	99.1	99.3	99.5	99.7	99.7	99.8
	to R410A)
Refrigerating	% (relative	93.6	93.2	91.5	91.3	90.9	90.6	88.4	88.1
capacity ratio	to R410A)

TABLE 91

				Comp.	Comp.
Item	Unit	Ex. 279	Ex. 280	Ex. 109	Ex. 110

HFO-1132(E)	Mass %	20.0	10.0	15.0	10.0
HFO-1123	Mass %	5.7	10.7	5.7	5.7
R1234yf	Mass %	45.0	50.0	50.0	55.0
R32	Mass %	29.3	29.3	29.3	29.3
GWP	—	200	200	200	200
COP ratio	% (relative	100.0	100.3	100.4	100.9
	to R410A)
Refrigerating	% (relative	87.8	85.2	85.0	82.0
capacity ratio	to R410A)

TABLE 92

							Comp.
Item	Unit	Ex. 281	Ex. 282	Ex. 283	Ex. 284	Ex. 285	Ex. 111	Ex. 286	Ex. 287

HFO-1132(E)	Mass %	10.0	15.0	20.0	25.0	30.0	35.0	10.0	15.0
HFO-1123	Mass %	40.9	35.9	30.9	25.9	20.9	15.9	35.9	30.9
R1234yf	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	10.0	10.0
R32	Mass %	44.1	44.1	44.1	44.1	44.1	44.1	44.1	44.1
GWP	—	298	298	298	298	298	298	299	299
COP ratio	% (relative	97.8	97.9	97.9	98.1	98.2	98.4	98.2	98.2
	to R410A)
Refrigerating	% (relative	112.5	112.3	111.9	111.6	111.2	110.7	109.8	109.5
capacity ratio	to R410A)

TABLE 93

					Comp.
Item	Unit	Ex. 288	Ex. 289	Ex. 290	Ex. 112	Ex. 291	Ex. 292	Ex. 293	Ex. 294

HFO-1132(E)	Mass %	20.0	25.0	30.0	35.0	10.0	15.0	20.0	25.0
HFO-1123	Mass %	25.9	20.9	15.9	10.9	30.9	25.9	20.9	15.9
R1234yf	Mass %	10.0	10.0	10.0	10.0	15.0	15.0	15.0	15.0
R32	Mass %	44.1	44.1	44.1	44.1	44.1	44.1	44.1	44.1
GWP	—	299	299	299	299	299	299	299	299
COP ratio	% (relative	98.3	98.5	98.6	98.8	98.6	98.6	98.7	98.9
	to R410A)
Refrigerating	% (relative	109.2	108.8	108.4	108.0	107.0	106.7	106.4	106.0
capacity ratio	to R410A)

TABLE 94

			Comp.
Item	Unit	Ex. 295	Ex. 113	Ex. 296	Ex. 297	Ex. 298	Ex. 299	Ex. 300	Ex. 301

HFO-1132(E)	Mass %	30.0	35.0	10.0	15.0	20.0	25.0	30.0	10.0
HFO-1123	Mass %	10.9	5.9	25.9	20.9	15.9	10.9	5.9	20.9
R1234yf	Mass %	15.0	15.0	20.0	20.0	20.0	20.0	20.0	25.0
R32	Mass %	44.1	44.1	44.1	44.1	44.1	44.1	44.1	44.1
GWP	—	299	299	299	299	299	299	299	299
COP ratio	% (relative	99.0	99.2	99.0	99.0	99.2	99.3	99.4	99.4
	to R410A)
Refrigerating	% (relative	105.6	105.2	104.1	103.9	103.6	103.2	102.8	101.2
capacity ratio	to R410A)

TABLE 95

Item	Unit	Ex. 302	Ex. 303	Ex. 304	Ex. 305	Ex. 306	Ex. 307	Ex. 308	Ex. 309

HFO-1132(E)	Mass %	15.0	20.0	25.0	10.0	15.0	20.0	10.0	15.0
HFO-1123	Mass %	15.9	10.9	5.9	15.9	10.9	5.9	10.9	5.9
R1234yf	Mass %	25.0	25.0	25.0	30.0	30.0	30.0	35.0	35.0
R32	Mass %	44.1	44.1	44.1	44.1	44.1	44.1	44.1	44.1
GWP	—	299	299	299	299	299	299	299	299
COP ratio	% (relative	99.5	99.6	99.7	99.8	99.9	100.0	100.3	100.4
	to R410A)
Refrigerating	% (relative	101.0	100.7	100.3	98.3	98.0	97.8	95.3	95.1
capacity ratio	to R410A)

TABLE 96

Item	Unit	Ex. 400

HFO-1132(E)	Mass %	10.0
HFO-1123	Mass %	5.9
R1234yf	Mass %	40.0
R32	Mass %	44.1
GWP	—	299
COP ratio	% (relative to R410A)	100.7
Refrigerating capacity ratio	% (relative to R410A)	92.3

The above results indicate that the refrigerating capacity ratio relative to R410A is 85% or more in the following cases:

When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a, in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass %, a straight line connecting a point (0.0, 100.0−a, 0.0) and a point (0.0, 0.0, 100.0−a) is the base, and the point (0.0, 100.0−a, 0.0) is on the left side, if 0<a≤11.1, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0134a²−1.9681a+68.6, 0.0, −0.0134a²+0.9681a+31.4) and point B (0.0, 0.0144a²−1.6377a+58.7, −0.0144a²+0.6377a+41.3);

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0112a²−1.9337a+68.484, 0.0, −0.0112a²+0.9337a+31.516) and point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801);

if 18.2a<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0107a²−1.9142a+68.305, 0.0, −0.0107a²+0.9142a+31.695) and point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682);

if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207) and point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714); and

if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0085a²−1.8102a+67.1, 0.0, −0.0085a²+0.8102a+32.9) and point B (0.0, 0.0012a²−1.1659a+52.95, −0.0012a²+0.1659a+47.05).

Actual points having a refrigerating capacity ratio of 85% or more form a curved line that connects point A and point B in FIG. 3, and that extends toward the 1234yf side. Accordingly, when coordinates are on, or on the left side of, the straight line AB, the refrigerating capacity ratio relative to R410A is 85% or more.

Similarly, it was also found that in the ternary composition diagram, if 0<a≤11.1, when coordinates (x,y,z) are on, or on the left side of, a straight line D′C that connects point D′ (0.0, 0.0224a²+0.968a+75.4, −0.0224a²−1.968a+24.6) and point C (−0.2304a²−0.4062a+32.9, 0.2304a²−0.5938a+67.1, 0.0); or if 11.1<a≤46.7, when coordinates are in the entire region, the COP ratio relative to that of R410A is 92.5% or more.

In FIG. 3, the COP ratio of 92.5% or more forms a curved line CD. In FIG. 3, an approximate line formed by connecting three points: point C (32.9, 67.1, 0.0) and points (26.6, 68.4, 5) (19.5, 70.5, 10) where the COP ratio is 92.5% when the concentration of R1234yf is 5 mass % and 10 mass was obtained, and a straight line that connects point C and point D′ (0, 75.4, 24.6), which is the intersection of the approximate line and a point where the concentration of HFO-1132(E) is 0.0 mass % was defined as a line segment D′C. In FIG. 4, point D′(0, 83.4, 9.5) was similarly obtained from an approximate curve formed by connecting point C (18.4, 74.5, 0) and points (13.9, 76.5, 2.5) (8.7, 79.2, 5) where the COP ratio is 92.5%, and a straight line that connects point C and point D′ was defined as the straight line D′C.

The composition of each mixture was defined as WCF. A leak simulation was performed using NIST Standard Reference Database REFLEAK Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

The results are shown in Tables 97 to 104.

TABLE 97

	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 6	Ex. 13	Ex. 19	Ex. 24	Ex. 29	Ex. 34

WCF	HFO-1132(E)	Mass %	72.0	60.9	55.8	52.1	48.6	45.4
	HFO-1123	Mass %	28.0	32.0	33.1	33.4	33.2	32.7
	R1234yf	Mass %	0.0	0.0	0.0	0	0	0
	R32	Mass %	0.0	7.1	11.1	14.5	18.2	21.9

Burning velocity (WCF)	cm/s	10	10	10	10	10	10

TABLE 98

	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 39	Ex. 45	Ex. 51	Ex. 57	Ex. 62

WCF	HFO-1132(E)	Mass %	41.8	40	35.7	32	30.4
	HFO-1123	Mass %	31.5	30.7	23.6	23.9	21.8
	R1234yf	Mass %	0	0	0	0	0
	R32	Mass %	26.7	29.3	36.7	44.1	47.8

Burning velocity (WCF)	cm/s	10	10	10	10	10

TABLE 99

	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 7	Ex. 14	Ex. 20	Ex. 25	Ex. 30	Ex. 35

WCF	HFO-1132(E)	Mass %	72.0	60.9	55.8	52.1	48.6	45.4
	HFO-1123	Mass %	0.0	0.0	0.0	0	0	0
	R1234yf	Mass %	28.0	32.0	33.1	33.4	33.2	32.7
	R32	Mass %	0.0	7.1	11.1	14.5	18.2	21.9

Burning velocity (WCF)	cm/s	10	10	10	10	10	10

TABLE 100

	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 40	Ex. 46	Ex. 52	Ex. 58	Ex. 63

WCF	HFO-1132(E)	Mass %	41.8	40	35.7	32	30.4
	HFO-1123	Mass %	0	0	0	0	0
	R1234yf	Mass %	31.5	30.7	23.6	23.9	21.8
	R32	Mass %	26.7	29.3	36.7	44.1	47.8

Burning velocity (WCF)	cm/s	10	10	10	10	10

TABLE 101

	Comp.	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 8	Ex. 15	Ex. 21	Ex. 26	Ex. 31	Ex. 36

WCF	HFO-1132(E)	Mass %	47.1	40.5	37.0	34.3	32.0	30.3
	HFO-1123	Mass %	52.9	52.4	51.9	51.2	49.8	47.8
	R1234yf	Mass %	0.0	0.0	0.0	0.0	0.0	0.0
	R32	Mass %	0.0	7.1	11.1	14.5	18.2	21.9

Leak condition that	Storage/	Storage/	Storage/	Storage/	Storage/	Storage/
results in WCFF	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°
	C., 92%	C., 92%	C., 92%	C., 92%	C., 92%	C., 92%
	release, liquid	release, liquid	release, liquid	release, liquid	release, liquid	release, liquid
	phase side	phase side	phase side	phase side	phase side	phase side

WCFF	HFO-1132(E)	Mass %	72.0	62.4	56.2	50.6	45.1	40.0
	HFO-1123	Mass %	28.0	31.6	33.0	33.4	32.5	30.5
	R1234yf	Mass %	0.0	0.0	0.0	20.4	0.0	0.0
	R32	Mass %	0.0	50.9	10.8	16.0	22.4	29.5

Burning velocity (WCF)	cm/s	8 or less	8 or less	8 or less	8 or less	8 or less	8 or less
Burning velocity (WCFF)	cm/s	10	10	10	10	10	10

TABLE 102

	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 41	Ex. 47	Ex. 53	Ex. 59	Ex. 64

WCF	HFO-1132(E)	Mass %	29.1	28.8	29.3	29.4	28.9
	HFO-1123	Mass %	44.2	41.9	34.0	26.5	23.3
	R1234yf	Mass %	0.0	0.0	0.0	0.0	0.0
	R32	Mass %	26.7	29.3	36.7	44.1	47.8

Leak condition that	Storage/	Storage/	Storage/	Storage/	Storage/
results in WCFF	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°
	C., 92%	C., 92%	C., 92%	C., 90%	C., 86%
	release, liquid	release, liquid	release, liquid	release, gas	release, gas
	phase side	phase side	phase side	phase side	phase side

WCFF	HFO-1132(E)	Mass %	34.6	32.2	27.7	28.3	27.5
	HFO-1123	Mass %	26.5	23.9	17.5	18.2	16.7
	R1234yf	Mass %	0.0	0.0	0.0	0.0	0.0
	R32	Mass %	38.9	43.9	54.8	53.5	55.8

Burning velocity (WCF)	cm/s	8 or less	8 or less	8.3	9.3	9.6
Burning velocity (WCFF)	cm/s	10	10	10	10	10

TABLE 103

	Comp.	Comp.	Comp.	Comp	Comp.	Comp.
Item	Ex. 9	Ex. 16	Ex. 22	Ex. 27	Ex. 32	Ex. 37

WCF	HFO-1132(E)	Mass %	61.7	47.0	41.0	36.5	32.5	28.8
	HFO-1123	Mass %	5.9	7.2	6.5	5.6	4.0	2.4
	R1234yf	Mass %	32.4	38.7	41.4	43.4	45.3	46.9
	R32	Mass %	0.0	7.1	11.1	14.5	18.2	21.9

Leak condition that	Storage/	Storage/	Storage/	Storage/	Storage/	Storage/
results in WCFF	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°
	C., 0%	C., 0%	C., 0%	C., 92%	C., 0%	C., 0%
	release, gas	release, gas	release, gas	release, liquid	release, gas	release, gas
	phase side	phase side	phase side	phase side	phase side	phase side

WCFF	HFO-1132(E)	Mass %	72.0	56.2	50.4	46.0	42.4	39.1
	HFO-1123	Mass %	10.5	12.6	11.4	10.1	7.4	4.4
	R1234yf	Mass %	17.5	20.4	21.8	22.9	24.3	25.7
	R32	Mass %	0.0	10.8	16.3	21.0	25.9	30.8

Burning velocity (WCF)	cm/s	8 or less	8 or less	8 or less	8 or less	8 or less	8 or less
Burning velocity (WCFF)	cm/s	10	10	10	10	10	10

TABLE 104

	Comp.	Comp.	Comp.	Comp.	Comp.
Item	Ex. 42	Ex. 48	Ex. 54	Ex. 60	Ex. 65

WCF	HFO-1132(E)	Mass %	24.8	24.3	22.5	21.1	20.4
	HFO-1123	Mass %	0.0	0.0	0.0	0.0	0.0
	R1234yf	Mass %	48.5	46.4	40.8	34.8	31.8
	R32	Mass %	26.7	29.3	36.7	44.1	47.8

Leak condition that	Storage/	Storage/	Storage/	Storage/	Storage/
results in WCFF	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°	Shipping −40°
	C., 0%	C., 0%	C., 0%	C., 0%	C., 0%
	release, gas	release, gas	release, gas	release, gas	release, gas
	phase side	phase side	phase side	phase side	phase side

WCFF	HFO-1132(E)	Mass %	35.3	34.3	31.3	29.1	28.1
	HFO-1123	Mass %	0.0	0.0	0.0	0.0	0.0
	R1234yf	Mass %	27.4	26.2	23.1	19.8	18.2
	R32	Mass %	37.3	39.6	45.6	51.1	53.7

Burning velocity (WCF)	cm/s	8 or less	8 or less	8 or less	8 or less	8 or less
Burning velocity (WCFF)	cm/s	10	10	10	10	10

The results in Tables 97 to 100 indicate that the refrigerant has a WCF lower flammability in the following cases:

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.02a²−1.6013a+71.105, −0.02a²+0.6013a+28.895, 0.0) and point I (0.02a²−1.6013a+71.105, 0.0, −0.02a²+0.6013a+28.895); if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0135a²−1.4068a+69.727, −0.0135a²+0.4068a+30.273, 0.0) and point I (0.0135a²−1.4068a+69.727, 0.0, −0.0135a²+0.4068a+30.273); if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0111a²−1.3152a+68.986, −0.0111a²+0.3152a+31.014, 0.0) and point I (0.0111a²−1.3152a+68.986, 0.0, −0.0111a²+0.3152a+31.014); and if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0061a²−0.9918a+63.902, −0.0061a²−0.0082a+36.098, 0.0) and point I (0.0061a²−0.9918a+63.902, 0.0, −0.0061a²−0.0082a+36.098).

Three points corresponding to point G (Table 105) and point I (Table 106) were individually obtained in each of the following five ranges by calculation, and their approximate expressions were obtained.

TABLE 105

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	72.0	60.9	55.8	55.8	52.1	48.6	48.6	45.4	41.8
HFO-1123	28.0	32.0	33.1	33.1	33.4	33.2	33.2	32.7	31.5
R1234yf	0	0	0	0	0	0	0	0	0

R32	a	a	a
HFO-1132(E)	0.026a²− 1.7478a + 72.0	0.02a²− 1.6013a + 71.105	0.0135a²− 1.4068a + 69.727
Approximate
expression
HFO-1123	−0.026a²+ 0..7478a + 28.0	−0.02a²+ 0..6013a + 28.895	−0.0135a²+ 0.4068a + 30.273
Approximate
expression
R1234yf	0	0	0
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	46.7 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	41.8	40.0	35.7	35.7	32.0	30.4
HFO-1123	31.5	30.7	27.6	27.6	23.9	21.8
R1234yf	0	0	0	0	0	0

R32	a	a
HFO-1132(E)	0.0111a2 − 1.3152a + 68.986	0.0061a²− 0.9918a + 63.902
Approximate
expression
HFO-1123	−0.0111a2 + 0.3152a + 31.014	−0.0061a²− 0.0082a + 36.098
Approximate
expression
R1234yf	0	0
Approximate
expression

TABLE 106

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	72.0	60.9	55.8	55.8	52.1	48.6	48.6	45.4	41.8
HFO-1123	0	0	0	0	0	0	0	0	0
R1234yf	28.0	32.0	33.1	33.1	33.4	33.2	33.2	32.7	31.5

R32	a	a	a
HFO-1132(E)	0.026a²− 1.7478a + 72.0	0.02a²− 1.6013a + 71.105	0.0135a²− 1.4068a + 69.727
Approximate
expression
HFO-1123	0	0	0
Approximate
expression
R1234yf	−0.026a²+ 0.7478a + 28.0	−0.02a²+ 0.6013a + 28.895	−0.0135a²+ 0.4068a + 30.273
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	46.7 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	41.8	40.0	35.7	35.7	32.0	30.4
HFO-1123	0	0	0	0	0	0
R1234yf	31.5	30.7	23.6	23.6	23.5	21.8

R32	x	x
HFO-1132(E)	0.0111a²− 1.3152a + 68.986	0.0061a²− 0.9918a + 63.902
Approximate
expression
HFO-1123	0	0
Approximate
expression
R1234yf	−0.0111a²+ 0.3152a + 31.014	−0.0061a²− 0.0082a + 36.098
Approximate
expression

The results in Tables 101 to 104 indicate that the refrigerant is determined to have a WCFF lower flammability, and the flammability classification according to the ASHRAE Standard is “2L (flammability)” in the following cases:

When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the mixed refrigerant of HFO-1132(E), HFO-1123, R1234yf, and R32 is respectively represented by x, y, z, and a, in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % and a straight line connecting a point (0.0, 100.0−a, 0.0) and a point (0.0, 0.0, 100.0−a) is the base, if 0<a≤11.1, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line JK′ that connects point J (0.0049a²−0.9645a+47.1, −0.0049a²−0.0355a+52.9, 0.0) and point K′(0.0514a²−2.4353a+61.7, −0.0323a²+0.4122a+5.9, −0.0191a²+1.0231a+32.4); if 11.1<a≤18.2, coordinates are on a straight line JK′ that connects point J (0.0243a²−1.4161a+49.725, −0.0243a²+0.4161a+50.275, 0.0) and point K′(0.0341a²−2.1977a+61.187, −0.0236a²+0.34a+5.636, −0.0105a²+0.8577a+33.177); if 18.2<a≤26.7, coordinates are on or below a straight line JK′ that connects point J (0.0246a²−1.4476a+50.184, −0.0246a²+0.4476a+49.816, 0.0) and point K′ (0.0196a²−1.7863a+58.515, −0.0079a²−0.1136a+8.702, −0.0117a²+0.8999a+32.783); if 26.7<a≤36.7, coordinates are on or below a straight line JK′ that connects point J (0.0183a²−1.1399a+46.493, −0.0183a²+0.1399a+53.507, 0.0) and point K′ (−0.0051a²+0.0929a+25.95, 0.0, 0.0051a²−1.0929a+74.05); and if 36.7<a≤46.7, coordinates are on or below a straight line JK′ that connects point J (−0.0134a²+1.0956a+7.13, 0.0134a²−2.0956a+92.87, 0.0) and point K′(−1.892a+29.443, 0.0, 0.892a+70.557).

Actual points having a WCFF lower flammability form a curved line that connects point J and point K′ (on the straight line AB) in FIG. 3 and extends toward the HFO-1132(E) side. Accordingly, when coordinates are on or below the straight line JK′, WCFF lower flammability is achieved.

Three points corresponding to point J (Table 107) and point K′ (Table 108) were individually obtained in each of the following five ranges by calculation, and their approximate expressions were obtained.

TABLE 107

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	47.1	40.5	37	37.0	34.3	32.0	32.0	30.3	29.1
HFO-1123	52.9	52.4	51.9	51.9	51.2	49.8	49.8	47.8	44.2
R1234yf	0	0	0	0	0	0	0	0	0

R32	a	a	a
HFO-1132(E)	0.0049a²− 0.9645a + 47.1	0.0243a²− 1.4161a + 49.725	0.0246a²− 1.4476a + 50.184
Approximate
expression
HFO-1123	−0.0049a²− 0.0355a + 52.9	−0.0243a²+ 0.4161a + 50.275	−0.0246a²+ 0.4476a + 49.816
Approximate
expression
R1234yf	0	0	0
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	47.8 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	29.1	28.8	29.3	29.3	29.4	28.9
HFO-1123	44.2	41.9	34.0	34.0	26.5	23.3
R1234yf	0	0	0	0	0	0

R32	a	a
HFO-1132(E)	0.0183a²− 1.1399a + 46.493	−0.0134a²+ 1.0956a + 7.13
Approximate
expression
HFO-1123	−0.0183a²+ 0.1399a + 53.507	0.0134a²− 2.0956a + 92.87
Approximate
expression
R1234yf	0	0
Approximate
expression

TABLE 108

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	61.7	47.0	41.0	41.0	36.5	32.5	32.5	28.8	24.8
HFO-1123	5.9	7.2	6.5	6.5	5.6	4.0	4.0	2.4	0
R1234yf	32.4	38.7	41.4	41.4	43.4	45.3	45.3	46.9	48.5

R32	x	x	x
HFO-1132(E)	0.0514a²− 2.4353a + 61.7	0.0341a²− 2.1977a + 61.187	0.0196a²− 1.7863a + 58.515
Approximate
expression
HFO-1123	−0.0323a²+ 0.4122a + 5.9	−0.0236a²+ 0.34a + 5.636	−0.0079a²− 0.1136a + 8.702
Approximate
expression
R1234yf	−0.0191a²+ 1.0231a + 32.4	−0.0105a²+ 0.8577a + 33.177	−0.0117a²+ 0.8999a + 32.783
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	46.7 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	24.8	24.3	22.5	22.5	21.1	20.4
HFO-1123	0	0	0	0	0	0
R1234yf	48.5	46.4	40.8	40.8	34.8	31.8

R32	x	x
HFO-1132(E)	−0.0051a²+ 0.0929a + 25.95	−1.892a + 29.443
Approximate
expression
HFO-1123	0	0
Approximate
expression
R1234yf	0.0051a²− 1.0929a + 74.05	0.892a + 70.557
Approximate
expression

FIGS. 3 to 13 show compositions whose R32 content a (mass %) is 0 mass %, 7.1 mass %, 11.1 mass %, 14.5 mass %, 18.2 mass %, 21.9 mass %, 26.7 mass %, 29.3 mass %, 36.7 mass %, 44.1 mass %, and 47.8 mass %, respectively.

Points A, B, C, and D′ were obtained in the following manner according to approximate calculation.

Point A is a point where the content of HFO-1123 is 0 mass %, and a refrigerating capacity ratio of 85% relative to that of R410A is achieved. Three points corresponding to point A were obtained in each of the following five ranges by calculation, and their approximate expressions were obtained (Table 109).

TABLE 109

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	68.6	55.3	48.4	48.4	42.8	37	37	31.5	24.8
HFO-1123	0	0	0	0	0	0	0	0	0
R1234yf	31.4	37.6	40.5	40.5	42.7	44.8	44.8	46.6	48.5

R32	a	a	a
HFO-1132(E)	0.0134a²− 1.9681a + 68.6	0.0112a²− 1.9337a + 68.484	0.0107a²− 1.9142a + 68.305
Approximate
expression
HFO-1123	0	0	0
Approximate
expression
R1234yf	−0.0134a²+ 0.9681a + 31.4	−0.0112a²+ 0.69337a + 31.516	−0.0107a²+ 0.9142a + 31.695
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	46.7 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	24.8	21.3	12.1	12.1	3.8	0
HFO-1123	0	0	0	0	0	0
R1234yf	48.5	49.4	51.2	51.2	52.1	52.2

R32	a	a
HFO-1132(E)	0.0103a²− 1.9225a + 68.793	0.0085a²− 1.8102a + 67.1
Approximate
expression
HFO-1123	0	0
Approximate
expression
R1234yf	−0.0103a²+ 0.9225a + 31..207	−0.0085a²+ 0.8102a + 32.9
Approximate
expression

Point B is a point where the content of HFO-1132(E) is 0 mass %, and a refrigerating capacity ratio of 85% relative to that of R410A is achieved.

Three points corresponding to point B were obtained in each of the following five ranges by calculation, and their approximate expressions were obtained (Table 110).

TABLE 110

Item	11.1 ≥ R32 > 0	18.2 ≥ R32 ≥ 11.1	26.7 ≥ R32 ≥ 18.2

R32	0	7.1	11.1	11.1	14.5	18.2	18.2	21.9	26.7
HFO-1132(E)	0	0	0	0	0	0	0	0	0
HFO-1123	58.7	47.8	42.3	42.3	37.8	33.1	33.1	28.5	22.9
R1234yf	41.3	45.1	46.6	46.6	47.7	48.7	48.7	49.6	50.4

R32	a	a	a
HFO-1132(E)	0	0	0
Approximate
expression
HFO-1123	0.0144a²− 1.6377a + 58.7	0.0075a²− 1.5156a + 58.199	0.009a²− 1.6045a + 59.318
Approximate
expression
R1234yf	−0.0144a²+ 0.6377a + 41.3	−0.0075a²+ 0.5156a + 41.801	−0.009a²+ 0.6045a + 40.682
Approximate
expression

	Item	36.7 ≥ R32 ≥ 26.7	46.7 ≥ R32 ≥ 36.7

R32	26.7	29.3	36.7	36.7	44.1	47.8
HFO-1132(E)	0	0	0	0	0	0
HFO-1123	22.9	19.9	11.7	11.8	3.9	0
R1234yf	50.4	50.8	51.6	51.5	52.0	52.2

R32	a	a
HFO-1132(E)	0	0
Approximate
expression
HFO-1123	0.0046a²− 1.41a + 57.286	0.0012a²− 1.1659a + 52.95
Approximate
expression
R1234yf	−0.0046a²+ 0.41a + 42.714	−0.0012a²+ 0.1659a + 47.05
Approximate
expression

Point D′ is a point where the content of HFO-1132(E) is 0 mass %, and a COP ratio of 95.5% relative to that of R410A is achieved.

Three points corresponding to point D′ were obtained in each of the following by calculation, and their approximate expressions were obtained (Table 111).

	TABLE 111

	Item	11.1 ≥ R32 > 0

R32	0	7.1	11.1
HFO-1132(E)	0	0	0
HFO-1123	75.4	83.4	88.9
R1234yf	24.6	9.5	0

	R32	a
	HFO-1132(E)	0
	Approximate
	expression
	HFO-1123	0.0224a²+ 0.968a + 75.4
	Approximate
	expression
	R1234yf	−0.0224a²− 1.968a + 24.6
	Approximate
	expression

Point C is a point where the content of R1234yf is 0 mass %, and a COP ratio of 95.5% relative to that of R410A is achieved.

Three points corresponding to point C were obtained in each of the following by calculation, and their approximate expressions were obtained (Table 112).

	TABLE 112

	Item	11.1 ≥ R32 > 0

R32	0	7.1	11.1
HFO-1132(E)	32.9	18.4	0
HFO-1123	67.1	74.5	88.9
R1234yf	0	0	0

	R32	a
	HFO-1132(E)	−0.2304a²− 0.4062a + 32.9
	Approximate
	expression
	HFO-1123	0.2304a²− 0.5938a + 67.1
	Approximate
	expression
	R1234yf	0
	Approximate
	expression

(5-4) Refrigerant D

The refrigerant D according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

The refrigerant D according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant; i.e., a refrigerating capacity equivalent to that of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:

point I (72.0, 0.0, 28.0),
point J (48.5, 18.3, 33.2),
point N (27.7, 18.2, 54.1), and
point E (58.3, 0.0, 41.7),
or on these line segments (excluding the points on the line segment EI);

the line segment IJ is represented by coordinates (0.0236y²−1.7616y+72.0, y, −0.0236y²+0.7616y+28.0);

the line segment NE is represented by coordinates (0.012y²−1.9003y+58.3, y, −0.012y²+0.9003y+41.7); and

the line segments JN and EI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 125 or less, and a WCF lower flammability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:

the line segment MM′ is represented by coordinates (0.132y²−3.34y+52.6, y, −0.132y²+2.34y+47.4);

the line segment M′N is represented by coordinates (0.0596y²−2.2541y+48.98, y, −0.0596y²+1.2541y+51.02);

the line segment VG is represented by coordinates (0.0123y²−1.8033y+39.6, y, −0.0123y²+0.8033y+60.4); and

the line segments NV and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 70% or more relative to R410A, a GWP of 125 or less, and an ASHRAE lower flammability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:

point O (22.6, 36.8, 40.6),
point N (27.7, 18.2, 54.1), and
point U (3.9, 36.7, 59.4),
or on these line segments;

the line segment ON is represented by coordinates (0.0072y²−0.6701y+37.512, y, −0.0072y²−0.3299y+62.488);

the line segment NU is represented by coordinates (0.0083y²−1.7403y+56.635, y, −0.0083y²+0.7403y+43.365); and

the line segment UO is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 250 or less, and an ASHRAE lower flammability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:

point Q (44.6, 23.0, 32.4),
point R (25.5, 36.8, 37.7),
point T (8.6, 51.6, 39.8),
point L (28.9, 51.7, 19.4), and
point K (35.6, 36.8, 27.6),
or on these line segments;

the line segment QR is represented by coordinates (0.0099y²−1.975y+84.765, y, −0.0099y²+0.975y+15.235);

the line segment RT is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874);

the line segment LK is represented by coordinates (0.0049y²−0.8842y+61.488, y, −0.0049y²−0.1158y+38.512);

the line segment KQ is represented by coordinates (0.0095y²−1.2222y+67.676, y, −0.0095y²+0.2222y+32.324); and

the line segment TL is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and a WCF lower flammability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (20.5, 51.7, 27.8),
point S (21.9, 39.7, 38.4), and
point T (8.6, 51.6, 39.8),
or on these line segments;

the line segment PS is represented by coordinates (0.0064y²−0.7103y+40.1, y, −0.0064y²−0.2897y+59.9);

the line segment ST is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874); and

the line segment TP is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and an ASHRAE lower flammability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ac, cf, fd, and da that connect the following 4 points:

point a (71.1, 0.0, 28.9),
point c (36.5, 18.2, 45.3),
point f (47.6, 18.3, 34.1), and
point d (72.0, 0.0, 28.0),
or on these line segments;

the line segment ac is represented by coordinates (0.0181y²−2.2288y+71.096, y, −0.0181y²+1.2288y+28.904);

the line segment fd is represented by coordinates (0.02y²−1.7y+72, y, −0.02y²+0.7y+28); and

the line segments cf and da are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to R410A, a GWP of 125 or less, and a lower flammability (Class 2L) according to the ASHRAE standard.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ab, be, ed, and da that connect the following 4 points:

point a (71.1, 0.0, 28.9),
point b (42.6, 14.5, 42.9),
point e (51.4, 14.6, 34.0), and
point d (72.0, 0.0, 28.0),
or on these line segments;

the line segment ab is represented by coordinates (0.0181y²−2.2288y+71.096, y, −0.0181y²+1.2288y+28.904);

the line segment ed is represented by coordinates (0.02y²−1.7y+72, y, −0.02y²+0.7y+28); and

the line segments be and da are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to R410A, a GWP of 100 or less, and a lower flammability (Class 2L) according to the ASHRAE standard.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments gi, ij, and jg that connect the following 3 points:

point g (77.5, 6.9, 15.6),
point i (55.1, 18.3, 26.6), and
point j (77.5. 18.4, 4.1),
or on these line segments;

the line segment gi is represented by coordinates (0.02y²−2.4583y+93.396, y, −0.02y²+1.4583y+6.604); and

the line segments ij and jg are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to R410A and a GWP of 100 or less, undergoes fewer or no changes such as polymerization or decomposition, and also has excellent stability.

The refrigerant D according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments gh, hk, and kg that connect the following 3 points:

point g (77.5, 6.9, 15.6),
point h (61.8, 14.6, 23.6), and
point k (77.5, 14.6, 7.9),
or on these line segments;

the line segment gh is represented by coordinates (0.02y²−2.4583y+93.396, y, −0.02y²+1.4583y+6.604); and

the line segments hk and kg are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to R410A and a GWP of 100 or less, undergoes fewer or no changes such as polymerization or decomposition, and also has excellent stability.

The refrigerant D according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), R32, and R1234yf, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), R32, and R1234yf in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more based on the entire refrigerant.

(Examples of Refrigerant D)

The present disclosure is described in more detail below with reference to Examples of refrigerant D. However, the refrigerant D is not limited to the Examples.

The composition of each mixed refrigerant of HFO-1132(E), R32, and R1234yf was defined as WCF. A leak simulation was performed using the NIST Standard Reference Database REFLEAK Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

TABLE 113

		Comparative		Example		Example		Example
		Example 13	Example	12	Example	14	Example	16
Item	Unit	I	11	J	13	K	15	L

WCF	HFO-1132(E)	Mass %	72	57.2	48.5	41.2	35.6	32	28.9
	R32	Mass %	0	10	18.3	27.6	36.8	44.2	51.7
	R1234yf	Mass %	28	32.8	33.2	31.2	27.6	23.8	19.4

Burning Velocity (WCF)	cm/s	10	10	10	10	10	10	10

TABLE 114

		Comparative		Example		Example
		Example 14	Example	19	Example	21	Example
Item	Unit	M	18	W	20	N	22

WCF	HFO-1132(E)	Mass %	52.6	39.2	32.4	29.3	27.7	24.6
	R32	Mass %	0.0	5.0	10.0	14.5	18.2	27.6
	R1234yf	Mass %	47.4	55.8	57.6	56.2	54.1	47.8

Leak condition that	Storage,	Storage,	Storage,	Storage,	Storage,	Storage,
results in WCFF	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°
	C., 0% release,	C., 0% release,	C., 0% release,	C., 0% release,	C., 0% release,	C., 0% release,
	on the gas	on the gas	on the gas	on the gas	on the gas	on the gas
	phase side	phase side	phase side	phase side	phase side	phase side

WCF	HFO-1132(E)	Mass %	72.0	57.8	48.7	43.6	40.6	34.9
	R32	Mass %	0.0	9.5	17.9	24.2	28.7	38.1
	R1234yf	Mass %	28.0	32.7	33.4	32.2	30.7	27.0

Burning Velocity (WCF)	cm/s	8 or less	8 or less	8 or less	8 or less	8 or less	8 or less
Burning Velocity (WCFF)	cm/s	10	10	10	10	10	10

TABLE 115

		Example		Example
		23	Example	25
Item	Unit	O	24	P

WCF	HFO-1132	Mass %	22.6	21.2	20.5
	(E)
	HFO-1123	Mass %	36.8	44.2	51.7
	R1234yf	Mass %	40.6	34.6	27.8

Leak condition	Storage,	Storage,	Storage,
that results	Shipping, −40°	Shipping, −40°	Shipping, −40°
in WCFF	C., 0% release,	C., 0% release,	C., 0% release,

	on the gas	on the gas	on the gas
	phase side	phase side	phase side

WCFF	HFO-1132	Mass %	31.4	29.2	27.1
	(E)
	HFO-1123	Mass %	45.7	51.1	56.4
	R1234yf	Mass %	23.0	19.7	16.5

Burning	cm/s	8 or less	8 or less	8 or less
Velocity (WCF)
Burning	cm/s	10	10	10
Velocity (WCFF)

The results indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in the ternary composition diagram shown in FIG. 14 in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are on the line segment that connects point I, point J, point K, and point L, or below these line segments, the refrigerant has a WCF lower flammability.

The results also indicate that when coordinates (x,y,z) in the ternary composition diagram shown in FIG. 14 are on the line segments that connect point M, point M′, point W, point J, point N, and point P, or below these line segments, the refrigerant has an ASHRAE lower flammability.

Mixed refrigerants were prepared by mixing HFO-1132(E), R32, and R1234yf in amounts (mass %) shown in Tables 116 to 144 based on the sum of HFO-1132(E), R32, and R1234yf. The coefficient of performance (COP) ratio and the refrigerating capacity ratio relative to R410 of the mixed refrigerants shown in Tables 116 to 144 were determined. The conditions for calculation were as described below.

Evaporating temperature: 5° C.

Condensation temperature: 45° C.

Degree of superheating: 5 K

Degree of subcooling: 5 K

Compressor efficiency: 70%

Tables 116 to 144 show these values together with the GWP of each mixed refrigerant.

TABLE 116

			Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
		Comparative	Example 2	Example 3	Example 4	Example 5	Example 6	Example 7
Item	Unit	Example 1	A	B	A′	B′	A″	B″

HFO-1132(E)	Mass %	R410A	81.6	0.0	63.1	0.0	48.2	0.0
R32	Mass %		18.4	18.1	36.9	36.7	51.8	51.5
R1234yf	Mass %		0.0	81.9	0.0	63.3	0.0	48.5
GWP	—	2088	125	125	250	250	350	350
COP Ratio	% (relative	100	98.7	103.6	98.7	102.3	99.2	102.2
	to R410A)
Refrigerating	% (relative	100	105.3	62.5	109.9	77.5	112.1	87.3
Capacity Ratio	to R410A)

TABLE 117

		Comparative		Comparative		Example		Example
		Example 8	Comparative	Example 10	Example	2	Example	4
Item	Unit	C	Example 9	C′	1	R	3	T

HFO-1132(E)	Mass %	85.5	66.1	52.1	37.8	25.5	16.6	8.6
R32	Mass %	0.0	10.0	18.2	27.6	36.8	44.2	51.6
R1234yf	Mass %	14.5	23.9	29.7	34.6	37.7	39.2	39.8
GWP	—	1	69	125	188	250	300	350
COP Ratio	% (relative	99.8	99.3	99.3	99.6	100.2	100.8	101.4
	to R410A)
Refrigerating	% (relative	92.5	92.5	92.5	92.5	92.5	92.5	92.5
Capacity Ratio	to R410A)

TABLE 118

		Comparative		Example		Example	Comparative		Example
		Example 11	Example	6	Example	8	Example 12	Example	10
Item	Unit	E	5	N	7	U	G	9	V

HFO-1132(E)	Mass %	58.3	40.5	27.7	14.9	3.9	39.6	22.8	11.0
R32	Mass %	0.0	10.0	18.2	27.6	36.7	0.0	10.0	18.1
R1234yf	Mass %	41.7	49.5	54.1	57.5	59.4	60.4	67.2	70.9
GWP	—	2	70	125	189	250	3	70	125
COP Ratio	% (relative	100.3	100.3	100.7	101.2	101.9	101.4	101.8	102.3
	to R410A)
Refrigerating	% (relative	80.0	80.0	80.0	80.0	80.0	70.0	70.0	70.0
Capacity Ratio	to R410A)

TABLE 119

		Comparative		Example		Example		Example	Example
		Example 13	Example	12	Example	14	Example	16	17
Item	Unit	I	11	J	13	K	15	L	Q

HFO-1132(E)	Mass %	72.0	57.2	48.5	41.2	35.6	32.0	28.9	44.6
R32	Mass %	0.0	10.0	18.3	27.6	36.8	44.2	51.7	23.0
R1234yf	Mass %	28.0	32.8	33.2	31.2	27.6	23.8	19.4	32.4
GWP	—	2	69	125	188	250	300	350	157
COP Ratio	% (relative	99.9	99.5	99.4	99.5	99.6	99.8	100.1	99.4
	to R410A)
Refrigerating	% (relative	86.6	88.4	90.9	94.2	97.7	100.5	103.3	92.5
Capacity Ratio	to R410A)

TABLE 120

		Comparative		Example		Example
		Example 14	Example	19	Example	21	Example
Item	Unit	M	18	W	20	N	22

HFO-1132(E)	Mass %	52.6	39.2	32.4	29.3	27.7	24.5
R32	Mass %	0.0	5.0	10.0	14.5	18.2	27.6
R1234yf	Mass %	47.4	55.8	57.6	56.2	54.1	47.9
GWP	—	2	36	70	100	125	188
COP Ratio	% (relative	100.5	100.9	100.9	100.8	100.7	100.4
	to R410A)
Refrigerating	% (relative	77.1	74.8	75.6	77.8	80.0	85.5
Capacity Ratio	to R410A)

TABLE 121

		Exam-		Exam-	Exam-
		ple	Exam-	ple	ple
		23	ple	25	26
Item	Unit	O	24	P	S

HFO-1132(E)	Mass %	22.6	21.2	20.5	21.9
R32	Mass %	36.8	44.2	51.7	39.7
R1234yf	Mass %	40.6	34.6	27.8	38.4
GWP	—	250	300	350	270
COP Ratio	% (relative	100.4	100.5	100.6	100.4
	to R410A)
Refrigerating	% (relative	91.0	95.0	99.1	92.5
Capacity	to R410A)
Ratio

TABLE 122

		Comparative	Comparative	Comparative	Comparative	Example	Example	Comparative	Comparative
Item	Unit	Example 15	Example 16	Example 17	Example 18	27	28	Example 19	Example 20

HFO-1132(E)	Mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
R32	Mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
R1234yf	Mass %	85.0	75.0	65.0	55.0	45.0	35.0	25.0	15.0
GWP	—	37	37	37	36	36	36	35	35
COP Ratio	% (relative	103.4	102.6	101.6	100.8	100.2	99.8	99.6	99.4
	to R410A)
Refrigerating	% (relative	56.4	63.3	69.5	75.2	80.5	85.4	90.1	94.4
Capacity Ratio	to R410A)

TABLE 123

		Comparative	Comparative	Example	Comparative	Example	Comparative	Comparative	Comparative
Item	Unit	Example 21	Example 22	29	Example 23	30	Example 24	Example 25	Example 26

HFO-1132(E)	Mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
R32	Mass %	10.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
R1234yf	Mass %	80.0	70.0	60.0	50.0	40.0	30.0	20.0	10.0
GWP	—	71	71	70	70	70	69	69	69
COP Ratio	% (relative	103.1	102.1	101.1	100.4	99.8	99.5	99.2	99.1
	to R410A)
Refrigerating	% (relative	61.8	68.3	74.3	79.7	84.9	89.7	94.2	98.4
Capacity Ratio	to R410A)

TABLE 124

		Comparative	Example	Comparative	Example	Example	Comparative	Comparative	Comparative
Item	Unit	Example 27	31	Example 28	32	33	Example 29	Example 30	Example 31

HFO-1132(E)	Mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
R32	Mass %	15.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
R1234yf	Mass %	75.0	65.0	55.0	45.0	35.0	25.0	15.0	5.0
GWP	—	104	104	104	103	103	103	103	102
COP Ratio	% (relative	102.7	101.6	100.7	100.0	99.5	99.2	99.0	98.9
	to R410A)
Refrigerating	% (relative	66.6	72.9	78.6	84.0	89.0	93.7	98.1	102.2
Capacity Ratio	to R410A)

TABLE 125

		Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
Item	Unit	Example 32	Example 33	Example 34	Example 35	Example 36	Example 37	Example 38	Example 39

HFO-1132(E)	Mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	10.0
R32	Mass %	20.0	20.0	20.0	20.0	20.0	20.0	20.0	25.0
R1234yf	Mass %	70.0	60.0	50.0	40.0	30.0	20.0	10.0	65.0
GWP	—	138	138	137	137	137	136	136	171
COP Ratio	% (relative	102.3	101.2	100.4	99.7	99.3	99.0	98.8	101.9
	to R410A)
Refrigerating	% (relative	71.0	77.1	82.7	88.0	92.9	97.5	101.7	75.0
Capacity Ratio	to R410A)

TABLE 126

		Example	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Example
Item	Unit	34	Example 40	Example 41	Example 42	Example 43	Example 44	Example 45	35

HFO-1132(E)	Mass %	20.0	30.0	40.0	50.0	60.0	70.0	10.0	20.0
R32	Mass %	25.0	25.0	25.0	25.0	25.0	25.0	30.0	30.0
R1234yf	Mass %	55.0	45.0	35.0	25.0	15.0	5.0	60.0	50.0
GWP	—	171	171	171	170	170	170	205	205
COP Ratio	% (relative	100.9	100.1	99.6	99.2	98.9	98.7	101.6	100.7
	to R410A)
Refrigerating	% (relative	81.0	86.6	91.7	96.5	101.0	105.2	78.9	84.8
Capacity Ratio	to R410A)

TABLE 127

		Comparative	Comparative	Comparative	Comparative	Example	Example	Example	Comparative
Item	Unit	Example 46	Example 47	Example 48	Example 49	36	37	38	Example 50

HFO-1132(E)	Mass %	30.0	40.0	50.0	60.0	10.0	20.0	30.0	40.0
R32	Mass %	30.0	30.0	30.0	30.0	35.0	35.0	35.0	35.0
R1234yf	Mass %	40.0	30.0	20.0	10.0	55.0	45.0	35.0	25.0
GWP	—	204	204	204	204	239	238	238	238
COP Ratio	% (relative	100.0	99.5	99.1	98.8	101.4	100.6	99.9	99.4
	to R410A)
Refrigerating	% (relative	90.2	95.3	100.0	104.4	82.5	88.3	93.7	98.6
Capacity Ratio	to R410A)

TABLE 128

		Comparative	Comparative	Comparative	Comparative	Example	Comparative	Comparative	Comparative
Item	Unit	Example 51	Example 52	Example 53	Example 54	39	Example 55	Example 56	Example 57

HFO-1132(E)	Mass %	50.0	60.0	10.0	20.0	30.0	40.0	50.0	10.0
R32	Mass %	35.0	35.0	40.0	40.0	40.0	40.0	40.0	45.0
R1234yf	Mass %	15.0	5.0	50.0	40.0	30.0	20.0	10.0	45.0
GWP	—	237	237	272	272	272	271	271	306
COP Ratio	% (relative	99.0	98.8	101.3	100.6	99.9	99.4	99.0	101.3
	to R410A)
Refrigerating	% (relative	103.2	107.5	86.0	91.7	96.9	101.8	106.3	89.3
Capacity Ratio	to R410A)

TABLE 129

		Example	Example	Comparative	Comparative	Comparative	Example	Comparative	Comparative
Item	Unit	40	41	Example 58	Example 59	Example 60	42	Example 61	Example 62

HFO-1132(E)	Mass %	20.0	30.0	40.0	50.0	10.0	20.0	30.0	40.0
R32	Mass %	45.0	45.0	45.0	45.0	50.0	50.0	50.0	50.0
R1234yf	Mass %	35.0	25.0	15.0	5.0	40.0	30.0	20.0	10.0
GWP	—	305	305	305	304	339	339	339	338
COP Ratio	% (relative	100.6	100.0	99.5	99.1	101.3	100.6	100.0	99.5
	to R410A)
Refrigerating	% (relative	94.9	100.0	104.7	109.2	92.4	97.8	102.9	107.5
Capacity Ratio	to R410A)

TABLE 130

		Comparative	Comparative	Comparative	Comparative	Example	Example	Example	Example
Item	Unit	Example 63	Example 64	Example 65	Example 66	43	44	45	46

HFO-1132(E)	Mass %	10.0	20.0	30.0	40.0	56.0	59.0	62.0	65.0
R32	Mass %	55.0	55.0	55.0	55.0	3.0	3.0	3.0	3.0
R1234yf	Mass %	35.0	25.0	15.0	5.0	41.0	38.0	35.0	32.0
GWP	—	373	372	372	372	22	22	22	22
COP Ratio	% (relative	101.4	100.7	100.1	99.6	100.1	100.0	99.9	99.8
	to R410A)
Refrigerating	% (relative	95.3	100.6	105.6	110.2	81.7	83.2	84.6	86.0
Capacity Ratio	to R410A)

TABLE 131

		Example	Example	Example	Example	Example	Example	Example	Example
Item	Unit	47	48	49	50	51	52	53	54

HFO-1132(E)	Mass %	49.0	52.0	55.0	58.0	61.0	43.0	46.0	49.0
R32	Mass %	6.0	6.0	6.0	6.0	6.0	9.0	9.0	9.0
R1234yf	Mass %	45.0	42.0	39.0	36.0	33.0	48.0	45.0	42.0
GWP	—	43	43	43	43	42	63	63	63
COP Ratio	% (relative	100.2	100.0	99.9	99.8	99.7	100.3	100.1	99.9
	to R410A)
Refrigerating	% (relative	80.9	82.4	83.9	85.4	86.8	80.4	82.0	83.5
Capacity Ratio	to R410A)

TABLE 132

		Example	Example	Example	Example	Example	Example	Example	Example
Item	Unit	55	56	57	58	59	60	61	62

HFO-1132(E)	Mass %	52.0	55.0	58.0	38.0	41.0	44.0	47.0	50.0
R32	Mass %	9.0	9.0	9.0	12.0	12.0	12.0	12.0	12.0
R1234yf	Mass %	39.0	36.0	33.0	50.0	47.0	44.0	41.0	38.0
GWP	—	63	63	63	83	83	83	83	83
COP Ratio	% (relative	99.8	99.7	99.6	100.3	100.1	100.0	99.8	99.7
	to R410A)
Refrigerating	% (relative	85.0	86.5	87.9	80.4	82.0	83.5	85.1	86.6
Capacity Ratio	to R410A)

TABLE 133

Item	Unit	Example 63	Example 64	Example 65	Example 66	Example 67	Example 68	Example 69	Example 70

HFO-1132(E)	Mass %	53.0	33.0	36.0	39.0	42.0	45.0	48.0	51.0
R32	Mass %	12.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
R1234yf	Mass %	35.0	52.0	49.0	46.0	43.0	40.0	37.0	34.0
GWP		83	104	104	103	103	103	103	103
COP Ratio	% (relative	99.6	100.5	100.3	100.1	99.9	99.7	99.6	99.5
	to R410A)
Refrigerating	% (relative	88.0	80.3	81.9	83.5	85.0	86.5	88.0	89.5
Capacity Ratio	to R410A)

TABLE 134

Item	Unit	Example 71	Example 72	Example 73	Example 74	Example 75	Example 76	Example 77	Example 78

HFO-1132(E)	Mass %	29.0	32.0	35.0	38.0	41.0	44.0	47.0	36.0
R32	Mass %	18.0	18.0	18.0	18.0	18.0	18.0	18.0	3.0
R1234yf	Mass %	53.0	50.0	47.0	44.0	41.0	38.0	35.0	61.0
GWP		124	124	124	124	124	123	123	23
COP Ratio	% (relative	100.6	100.3	100.1	99.9	99.8	99.6	99.5	101.3
	to R410A)
Refrigerating	% (relative	80.6	82.2	83.8	85.4	86.9	88.4	89.9	71.0
Capacity Ratio	to R410A)

TABLE 135

Item	Unit	Example 79	Example 80	Example 81	Example 82	Example 83	Example 84	Example 85	Example 86

HFO-1132(E)	Mass %	39.0	42.0	30.0	33.0	36.0	26.0	29.0	32.0
R32	Mass %	3.0	3.0	6.0	6.0	6.0	9.0	9.0	9.0
R1234yf	Mass %	58.0	55.0	64.0	61.0	58.0	65.0	62.0	59.0
GWP	—	23	23	43	43	43	64	64	63
COP Ratio	% (relative	101.1	100.9	101.5	101.3	101.0	101.6	101.3	101.1
	to R410A)
Refrigerating	% (relative	72.7	74.4	70.5	72.2	73.9	71.0	72.8	74.5
Capacity Ratio	to R410A)

TABLE 136

Item	Unit	Example 87	Example 88	Example 89	Example 90	Example 91	Example 92	Example 93	Example 94

HFO-1132(E)	Mass %	21.0	24.0	27.0	30.0	16.0	19.0	22.0	25.0
R32	Mass %	12.0	12.0	12.0	12.0	15.0	15.0	15.0	15.0
R1234yf	Mass %	67.0	64.0	61.0	58.0	69.0	66.0	63.0	60.0
GWP	—	84	84	84	84	104	104	104	104
COP Ratio	% (relative	101.8	101.5	101.2	101.0	102.1	101.8	101.4	101.2
	to R410A)
Refrigerating	% (relative	70.8	72.6	74.3	76.0	70.4	72.3	74.0	75.8
Capacity Ratio	to R410A)

TABLE 137

Item	Unit	Example 95	Example 96	Example 97	Example 98	Example 99	Example 100	Example 101	Example 102

HFO-1132(E)	Mass %	28.0	12.0	15.0	18.0	21.0	24.0	27.0	25.0
R32	Mass %	15.0	18.0	18.0	18.0	18.0	18.0	18.0	21.0
R1234yf	Mass %	57.0	70.0	67.0	64.0	61.0	58.0	55.0	54.0
GWP	—	104	124	124	124	124	124	124	144
COP Ratio	% (relative	100.9	102.2	101.9	101.6	101.3	101.0	100.7	100.7
	to R410A)
Refrigerating	% (relative	77.5	70.5	72.4	74.2	76.0	77.7	79.4	80.7
Capacity Ratio	to R410A)

TABLE 138

Item	Unit	Example 103	Example 104	Example 105	Example 106	Example 107	Example 108	Example 109	Example 110

HFO-1132(E)	Mass %	21.0	24.0	17.0	20.0	23.0	13.0	16.0	19.0
R32	Mass %	24.0	24.0	27.0	27.0	27.0	30.0	30.0	30.0
R1234yf	Mass %	55.0	52.0	56.0	53.0	50.0	57.0	54.0	51.0
GWP	—	164	164	185	185	184	205	205	205
COP Ratio	% (relative	100.9	100.6	101.1	100.8	100.6	101.3	101.0	100.8
	to R410A)
Refrigerating	% (relative	80.8	82.5	80.8	82.5	84.2	80.7	82.5	84.2
Capacity Ratio	to R410A)

TABLE 139

Item	Unit	Example 111	Example 112	Example 113	Example 114	Example 115	Example 116	Example 117	Example 118

HFO-1132(E)	Mass %	22.0	9.0	12.0	15.0	18.0	21.0	8.0	12.0
R32	Mass %	30.0	33.0	33.0	33.0	33.0	33.0	36.0	36.0
R1234yf	Mass %	48.0	58.0	55.0	52.0	49.0	46.0	56.0	52.0
GWP	—	205	225	225	225	225	225	245	245
COP Ratio	% (relative	100.5	101.6	101.3	101.0	100.8	100.5	101.6	101.2
	to R410A)
Refrigerating	% (relative	85.9	80.5	82.3	84.1	85.8	87.5	82.0	84.4
Capacity Ratio	to R410A)

TABLE 140

Item	Unit	Example 119	Example 120	Example 121	Example 122	Example 123	Example 124	Example 125	Example 126

HFO-1132(E)	Mass %	15.0	18.0	21.0	42.0	39.0	34.0	37.0	30.0
R32	Mass %	36.0	36.0	36.0	25.0	28.0	31.0	31.0	34.0
R1234yf	Mass %	49.0	46.0	43.0	33.0	33.0	35.0	32.0	36.0
GWP	—	245	245	245	170	191	211	211	231
COP Ratio	% (relative	101.0	100.7	100.5	99.5	99.5	99.8	99.6	99.9
	to R410A)
Refrigerating	% (relative	86.2	87.9	89.6	92.7	93.4	93.0	94.5	93.0
Capacity Ratio	to R410A)

TABLE 141

Item	Unit	Example 127	Example 128	Example 129	Example 130	Example 131	Example 132	Example 133	Example 134

HFO-1132(E)	Mass %	33.0	36.0	24.0	27.0	30.0	33.0	23.0	26.0
R32	Mass %	34.0	34.0	37.0	37.0	37.0	37.0	40.0	40.0
R1234yf	Mass %	33.0	30.0	39.0	36.0	33.0	30.0	37.0	34.0
GWP	—	231	231	252	251	251	251	272	272
COP Ratio	% (relative	99.8	99.6	100.3	100.1	99.9	99.8	100.4	100.2
	to R410A)
Refrigerating	% (relative	94.5	96.0	91.9	93.4	95.0	96.5	93.3	94.9
Capacity Ratio	to R410A)

TABLE 142

Item	Unit	Example 135	Example 136	Example 137	Example 138	Example 139	Example 140	Example 141	Example 142

HFO-1132(E)	Mass %	29.0	32.0	19.0	22.0	25.0	28.0	31.0	18.0
R32	Mass %	40.0	40.0	43.0	43.0	43.0	43.0	43.0	46.0
R1234yf	Mass %	31.0	28.0	38.0	35.0	32.0	29.0	26.0	36.0
GWP	—	272	271	292	292	292	292	292	312
COP Ratio	% (relative	100.0	99.8	100.6	100.4	100.2	100.1	99.9	100.7
	to R410A)
Refrigerating	% (relative	96.4	97.9	93.1	94.7	96.2	97.8	99.3	94.4
Capacity Ratio	to R410A)

TABLE 143

Item	Unit	Example 143	Example 144	Example 145	Example 146	Example 147	Example 148	Example 149	Example 150

HFO-1132(E)	Mass %	21.0	23.0	26.0	29.0	13.0	16.0	19.0	22.0
R32	Mass %	46.0	46.0	46.0	46.0	49.0	49.0	49.0	49.0
R1234yf	Mass %	33.0	31.0	28.0	25.0	38.0	35.0	32.0	29.0
GWP	—	312	312	312	312	332	332	332	332
COP Ratio	% (relative	100.5	100.4	100.2	100.0	101.1	100.9	100.7	100.5
	to R410A)
Refrigerating	% (relative	96.0	97.0	98.6	100.1	93.5	95.1	96.7	98.3
Capacity Ratio	to R410A)

TABLE 144

Item	Unit	Example 151	Example 152

HFO-1132(E)	Mass %	25.0	28.0
R32	Mass %	49.0	49.0
R1234yf	Mass %	26.0	23.0
GWP	—	332	332
COP Ratio	% (relative	100.3	100.1
	to R410A)
Refrigerating Capacity	% (relative	99.8	101.3
Ratio	to R410A)

The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:

point I (72.0, 0.0, 28.0),
point J (48.5, 18.3, 33.2),
point N (27.7, 18.2, 54.1), and
point E (58.3, 0.0, 41.7),
or on these line segments (excluding the points on the line segment EI),

the line segment IJ is represented by coordinates (0.0236y²−1.7616y+72.0, y, −0.0236y²+0.7616y+28.0),

the line segment NE is represented by coordinates (0.012y²−1.9003y+58.3, y, −0.012y²+0.9003y+41.7), and

the line segments JN and EI are straight lines, the refrigerant D has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 125 or less, and a WCF lower flammability.

The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:

the line segment MM′ is represented by coordinates (0.132y²−3.34y+52.6, y, −0.132y²+2.34y+47.4),

the line segment M′N is represented by coordinates (0.0596y²−2.2541y+48.98, y, −0.0596y²+1.2541y+51.02),

the line segment VG is represented by coordinates (0.0123y²−1.8033y+39.6, y, −0.0123y²+0.8033y+60.4), and

the line segments NV and GM are straight lines, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 70% or more relative to R410A, a GWP of 125 or less, and an ASHRAE lower flammability.

The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:

point O (22.6, 36.8, 40.6),
point N (27.7, 18.2, 54.1), and
point U (3.9, 36.7, 59.4),
or on these line segments,

the line segment ON is represented by coordinates (0.0072y²−0.6701y+37.512, y, −0.0072y²−0.3299y+62.488),

the line segment NU is represented by coordinates (0.0083y²−1.7403y+56.635, y, −0.0083y²+0.7403y+43.365), and

the line segment UO is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 250 or less, and an ASHRAE lower flammability.

The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:

point Q (44.6, 23.0, 32.4),
point R (25.5, 36.8, 37.7),
point T (8.6, 51.6, 39.8),
point L (28.9, 51.7, 19.4), and
point K (35.6, 36.8, 27.6),
or on these line segments,

the line segment QR is represented by coordinates (0.0099y²−1.975y+84.765, y, −0.0099y²+0.975y+15.235),

the line segment RT is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874),

the line segment LK is represented by coordinates (0.0049y²−0.8842y+61.488, y, −0.0049y²−0.1158y+38.512),

the line segment KQ is represented by coordinates (0.0095y²−1.2222y+67.676, y, −0.0095y²+0.2222y+32.324), and

the line segment TL is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and a WCF lower flammability.

The results further indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (20.5, 51.7, 27.8),
point S (21.9, 39.7, 38.4), and
point T (8.6, 51.6, 39.8),
or on these line segments,

the line segment PS is represented by coordinates (0.0064y²−0.7103y+40.1, y, −0.0064y²−0.2897y+59.9),

the line segment ST is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874), and

the line segment TP is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and an ASHRAE lower flammability.

(5-5) Refrigerant E

The refrigerant E according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32).

The refrigerant E according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., a coefficient of performance equivalent to that of R410A and a sufficiently low GWP.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IK, KB′, B′H, HR, RG, and GI that connect the following 6 points:

the line segment IK is represented by coordinates (0.025z²−1.7429z+72.00, −0.025z²+0.7429z+28.0, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments KB′ and GI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has WCF lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IJ, JR, RG, and GI that connect the following 4 points:

point I (72.0, 28.0, 0.0),
point J (57.7, 32.8, 9.5),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segment GI);

the line segment IJ is represented by coordinates (0.025z²−1.7429z+72.0, −0.025z²+0.7429z+28.0, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments JR and GI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has WCF lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MP, PB′, B′H, HR, RG, and GM that connect the following 6 points:

the line segment MP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments PB′ and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MN, NR, RG, and GM that connect the following 4 points:

point M (47.1, 52.9, 0.0),
point N (38.5, 52.1, 9.5),
point R (23.1, 67.4, 9.5), and
point G (38.5, 61.5, 0.0),
or on these line segments (excluding the points on the line segment GM);

the line segment MN is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z),

the line segments NR and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 65 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (31.8, 49.8, 18.4),
point S (25.4, 56.2, 18.4), and
point T (34.8, 51.0, 14.2),
or on these line segments;

the line segment ST is represented by coordinates (−0.0982z²+0.9622z+40.931, 0.0982z²−1.9622z+59.069, z),

the line segment TP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z), and

the line segment PS is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 94.5% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments QB″, B″D, DU, and UQ that connect the following 4 points:

point Q (28.6, 34.4, 37.0),
point B″ (0.0, 63.0, 37.0),
point D (0.0, 67.0, 33.0), and
point U (28.7, 41.2, 30.1),
or on these line segments (excluding the points on the line segment B″D);

the line segment DU is represented by coordinates (−3.4962z²+210.71z−3146.1, 3.4962z²−211.71z+3246.1, z),

the line segment UQ is represented by coordinates (0.0135z²−0.9181z+44.133, −0.0135z²−0.0819z+55.867, z), and

the line segments QB″ and B″D are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 96% or more relative to that of R410A, and a GWP of 250 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc′, c′d′, d′e′, e′a′, and a′O that connect the following 5 points:

point O (100.0, 0.0, 0.0),
point c′ (56.7, 43.3, 0.0),
point d′ (52.2, 38.3, 9.5),
point e′ (41.8, 39.8, 18.4), and
point a′ (81.6, 0.0, 18.4),
or on the line segments c′d′, d′e′, and e′a′ (excluding the points c′ and a′);

the line segment c′d′ is represented by coordinates (−0.0297z²−0.1915z+56.7, 0.0297z²+1.1915z+43.3, z),

the line segment d′e′ is represented by coordinates (−0.0535z²+0.3229z+53.957, 0.0535z²+0.6771z+46.043, z), and

the line segments Oc′, e′a′, and a′O are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 92.5% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc, cd, de, ea′, and a′O that connect the following 5 points:

point O (100.0, 0.0, 0.0),
point c (77.7, 22.3, 0.0),
point d (76.3, 14.2, 9.5),
point e (72.2, 9.4, 18.4), and
point a′ (81.6, 0.0, 18.4),
or on the line segments cd, de, and ea′ (excluding the points c and a′);

the line segment cde is represented by coordinates (−0.017z²+0.0148z+77.684, 0.017z²+0.9852z+22.316, z), and

the line segments Oc, ea′, and a′O are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 95% or more relative to that of R410A, and a GWP of 125 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc′, c′d′, d′a, and aO that connect the following 5 points:

point O (100.0, 0.0, 0.0),
point c′ (56.7, 43.3, 0.0),
point d′ (52.2, 38.3, 9.5), and
point a (90.5, 0.0, 9.5),
or on the line segments c′d′ and d′a (excluding the points c′ and a);

the line segment c′d′ is represented by coordinates (−0.0297z²−0.1915z+56.7, 0.0297z²+1.1915z+43.3, z), and

the line segments Oc′, d′a, and aO are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 93.5% or more relative to that of R410A, and a GWP of 65 or less.

The refrigerant E according to the present disclosure is preferably a refrigerant wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc, cd, da, and aO that connect the following 4 points:

point O (100.0, 0.0, 0.0),
point c (77.7, 22.3, 0.0),
point d (76.3, 14.2, 9.5), and
point a (90.5, 0.0, 9.5),
or on the line segments cd and da (excluding the points c and a);

the line segment cd is represented by coordinates (−0.017z²+0.0148z+77.684, 0.017z²+0.9852z+22.316, z), and

the line segments Oc, da, and aO are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 95% or more relative to that of R410A, and a GWP of 65 or less.

The refrigerant E according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, and R32, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, and R32 in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and even more preferably 99.9 mass % or more, based on the entire refrigerant.

(Examples of Refrigerant E)

The present disclosure is described in more detail below with reference to Examples of refrigerant E. However, the refrigerant E is not limited to the Examples.

Mixed refrigerants were prepared by mixing HFO-1132(E), HFO-1123, and R32 at mass % based on their sum shown in Tables 145 and 146.

The composition of each mixture was defined as WCF. A leak simulation was performed using National Institute of Science and Technology (NIST) Standard Reference Data Base Refleak Version 4.0 under the conditions for equipment, storage, shipping, leak, and recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

For each mixed refrigerant, the burning velocity was measured according to the ANSI/ASHRAE Standard 34-2013. When the burning velocities of the WCF composition and the WCFF composition are 10 cm/s or less, the flammability of such a refrigerant is classified as Class 2L (lower flammability) in the ASHRAE flammability classification.

Tables 145 and 146 show the results.

TABLE 145

Item	Unit	I	J	K	L

WCF	HFO-1132(E)	mass %	72.0	57.7	48.4	35.5
	HFO-1123	mass %	28.0	32.8	33.2	27.5
	R32	mass %	0.0	9.5	18.4	37.0

Burning velocity (WCF)	cm/s	10	10	10	10

TABLE 146

Item	Unit	M	N	T	P	U	Q

WCF	HFO-	mass %	47.1	38.5	34.8	31.8	28.7	28.6
	1132(E)
	HFO-1123	mass %	52.9	52.1	51.0	49.8	41.2	34.4
	R32	mass %	0.0	9.5	14.2	18.4	30.1	37.0

Leak condition	Storage,	Storage,	Storage,	Storage,	Storage,	Storage,
that results	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°	Shipping, −40°
in WCFF	C., 92%, release,	C., 92%, release,	C., 92%, release,	C., 92%, release,	C., 92%, release,	C., 92%, release,
	on the liquid	on the liquid	on the liquid	on the liquid	on the liquid	on the liquid
	phase side	phase side	phase side	phase side	phase side	phase side

WCFF	HFO-	mass %	72.0	58.9	51.5	44.6	31.4	27.1
	1132(E)
	HFO-1123	mass %	28.0	32.4	33.1	32.6	23.2	18.3
	R32	mass %	0.0	8.7	15.4	22.8	45.4	54.6

Burning	cm/s	8 or less	8 or less	8 or less	8 or less	8 or less	8 or less
velocity (WCF)
Burning	cm/s	10	10	10	10	10	10
velocity (WCFF)

The results in Table 1 indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R32 in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below line segments IK and KL that connect the following 3 points:

point I (72.0, 28.0, 0.0),
point K (48.4, 33.2, 18.4), and
point L (35.5, 27.5, 37.0);
the line segment IK is represented by coordinates (0.025z²−1.7429z+72.00, −0.025z²+0.7429z+28.00, z), and
the line segment KL is represented by coordinates (0.0098z²−1.238z+67.852, −0.0098z²+0.238z+32.148, z),
it can be determined that the refrigerant has WCF lower flammability.

For the points on the line segment IK, an approximate curve (x=0.025z²−1.7429z+72.00) was obtained from three points, i.e., I (72.0, 28.0, 0.0), J (57.7, 32.8, 9.5), and K (48.4, 33.2, 18.4) by using the least-square method to determine coordinates (x=0.025z²−1.7429z+72.00, y=100−z−x=−0.00922z²+0.2114z+32.443, z).

Likewise, for the points on the line segment KL, an approximate curve was determined from three points, i.e., K (48.4, 33.2, 18.4), Example 10 (41.1, 31.2, 27.7), and L (35.5, 27.5, 37.0) by using the least-square method to determine coordinates.

The results in Table 146 indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R32 in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below line segments MP and PQ that connect the following 3 points:

point M (47.1, 52.9, 0.0),
point P (31.8, 49.8, 18.4), and
point Q (28.6, 34.4, 37.0),
it can be determined that the refrigerant has ASHRAE lower flammability.

In the above, the line segment MP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z), and the line segment PQ is represented by coordinates (0.0135z²−0.9181z+44.133, −0.0135z²−0.0819z+55.867, z).

For the points on the line segment MP, an approximate curve was obtained from three points, i.e., points M, N, and P, by using the least-square method to determine coordinates. For the points on the line segment PQ, an approximate curve was obtained from three points, i.e., points P, U, and Q, by using the least-square method to determine coordinates.

The COP ratio and the refrigerating capacity (which may be referred to as “cooling capacity” or “capacity”) ratio relative to those of R410 of the mixed refrigerants were determined. The conditions for calculation were as described below.

Evaporating temperature: 5° C.
Condensation temperature: 45° C.
Degree of superheating: 5K
Degree of subcooling: 5K
Compressor efficiency: 70%

Tables 147 to 166 show these values together with the GWP of each mixed refrigerant.

TABLE 147

			Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
		Comparative	Example 2	Example 3	Example 4	Example 5	Example 6	Example 7
Item	Unit	Example 1	A	B	A′	B′	A″	B″

HFO-1132(E)	mass %	R410A	90.5	0.0	81.6	0.0	63.0	0.0
HFO-1123	mass %		0.0	90.5	0.0	81.6	0.0	63.0
R32	mass %		9.5	9.5	18.4	18.4	37.0	37.0
GWP	—	2088	65	65	125	125	250	250
COP ratio	% (relative	100	99.1	92.0	98.7	93.4	98.7	96.1
	to R410A)
Refrigerating	% (relative	100	102.2	111.6	105.3	113.7	110.0	115.4
capacity ratio	to R410A)

TABLE 148

		Comparative	Comparative				Comparative
		Example 8	Example 9	Comparative	Example 1		Example 11
Item	Unit	O	C	Example 10	U	Example 2	D

HFO-1132(E)	mass %	100.0	50.0	41.1	28.7	15.2	0.0
HFO-1123	mass %	0.0	31.6	34.6	41.2	52.7	67.0
R32	mass %	0.0	18.4	24.3	30.1	32.1	33.0
GWP	—	1	125	165	204	217	228
COP ratio	% (relative	99.7	96.0	96.0	96.0	96.0	96.0
	to R410A)
Refrigerating	% (relative	98.3	109.9	111.7	113.5	114.8	115.4
capacity ratio	to R410A)

TABLE 149

		Comparative				Comparative
		Example 12	Comparative	Example 3	Example 4	Example 14
Item	Unit	E	Example 13	T	S	F

HFO-1132(E)	mass %	53.4	43.4	34.8	25.4	0.0
HFO-1123	mass %	46.6	47.1	51.0	56.2	74.1
R32	mass %	0.0	9.5	14.2	18.4	25.9
GWP	—	1	65	97	125	176
COP ratio	% (relative	94.5	94.5	94.5	94.5	94.5
	to R410A)
Refrigerating	% (relative	105.6	109.2	110.8	112.3	114.8
capacity ratio	to R410A)

TABLE 150

		Comparative				Comparative
		Example 15		Example 6		Example 16
Item	Unit	G	Example 5	R	Example 7	H

HFO-1132(E)	mass %	38.5	31.5	23.1	16.9	0.0
HFO-1123	mass %	61.5	63.5	67.4	71.1	84.2
R32	mass %	0.0	5.0	9.5	12.0	15.8
GWP	—	1	35	65	82	107
COP ratio	% (relative	93.0	93.0	93.0	93.0	93.0
	to R410A)
Refrigerating	% (relative	107.0	109.1	110.9	111.9	113.2
capacity ratio	to R410A)

TABLE 151

		Comparative				Comparative
		Example 17	Example 8	Example 9	Comparative	Example 19
Item	Unit	I	J	K	Example 18	L

HFO-1132(E)	mass %	72.0	57.7	48.4	41.1	35.5
HFO-1123	mass %	28.0	32.8	33.2	31.2	27.5
R32	mass %	0.0	9.5	18.4	27.7	37.0
GWP	—	1	65	125	188	250
COP ratio	% (relative	96.6	95.8	95.9	96.4	97.1
	to R410A)
Refrigerating	% (relative	103.1	107.4	110.1	112.1	113.2
capacity ratio	to R410A)

TABLE 152

		Compar-
		ative	Exam-	Exam-	Exam-
		Example 20	ple 10	ple 11	ple 12
Item	Unit	M	N	P	Q

HFO-1132(E)	mass %	47.1	38.5	31.8	28.6
HFO-1123	mass %	52.9	52.1	49.8	34.4
R32	mass %	0.0	9.5	18.4	37.0
GWP	—	1	65	125	250
COP ratio	% (relative	93.9	94.1	94.7	96.9
	to R410A)
Refrigerating	% (relative	106.2	109.7	112.0	114.1
capacity	to R410A)
ratio

TABLE 153

		Comparative	Comparative	Comparative				Comparative	Comparative
Item	Unit	Example 22	Example 23	Example 24	Example 14	Example 15	Example 16	Example 25	Example 26

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	80.0
HFO-1123	mass %	85.0	75.0	65.0	55.0	45.0	35.0	25.0	15.0
R32	mass %	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
GWP	—	35	35	35	35	35	35	35	35
COP ratio	% (relative	91.7	92.2	92.9	93.7	94.6	95.6	96.7	97.7
	to R410A)
Refrigerating	% (relative	110.1	109.8	109.2	108.4	107.4	106.1	104.7	103.1
capacity ratio	to R410A)

TABLE 154

		Comparative	Comparative	Comparative				Comparative	Comparative
Item	Unit	Example 27	Example 28	Example 29	Example 17	Example 18	Example 19	Example 30	Example 31

HFO-1132(E)	mass %	90.0	10.0	20.0	30.0	40.0	50.0	60.0	70.0
HFO-1123	mass %	5.0	80.0	70.0	60.0	50.0	40.0	30.0	20.0
R32	mass %	5.0	10.0	10.0	10.0	10.0	10.0	10.0	10.0
GWP	—	35	68	68	68	68	68	68	68
COP ratio	% (relative	98.8	92.4	92.9	93.5	94.3	95.1	96.1	97.0
	to R410A)
Refrigerating	% (relative	101.4	111.7	111.3	110.6	109.6	108.5	107.2	105.7
capacity ratio	to R410A)

TABLE 155

		Comparative						Comparative	Comparative
Item	Unit	Example 32	Example 20	Example 21	Example 22	Example 23	Example 24	Example 33	Example 34

HFO-1132(E)	mass %	80.0	10.0	20.0	30.0	40.0	50.0	60.0	70.0
HFO-1123	mass %	10.0	75.0	65.0	55.0	45.0	35.0	25.0	15.0
R32	mass %	10.0	15.0	15.0	15.0	15.0	15.0	15.0	15.0
GWP	—	68	102	102	102	102	102	102	102
COP ratio	% (relative	98.0	93.1	93.6	94.2	94.9	95.6	96.5	97.4
	to R410A)
Refrigerating	% (relative	104.1	112.9	112.4	111.6	110.6	109.4	108.1	106.6
capacity ratio	to R410A)

TABLE 156

		Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
Item	Unit	Example 35	Example 36	Example 37	Example 38	Example 39	Example 40	Example 41	Example 42

HFO-1132(E)	mass %	80.0	10.0	20.0	30.0	40.0	50.0	60.0	70.0
HFO-1123	mass %	5.0	70.0	60.0	50.0	40.0	30.0	20.0	10.0
R32	mass %	15.0	20.0	20.0	20.0	20.0	20.0	20.0	20.0
GWP	—	102	136	136	136	136	136	136	136
COP ratio	% (relative	98.3	93.9	94.3	94.8	95.4	96.2	97.0	97.8
	to R410A)
Refrigerating	% (relative	105.0	113.8	113.2	112.4	111.4	110.2	108.8	107.3
capacity ratio	to R410A)

TABLE 157

		Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
Item	Unit	Example 43	Example 44	Example 45	Example 46	Example 47	Example 48	Example 49	Example 50

HFO-1132(E)	mass %	10.0	20.0	30.0	40.0	50.0	60.0	70.0	10.0
HFO-1123	mass %	65.0	55.0	45.0	35.0	25.0	15.0	5.0	60.0
R32	mass %	25.0	25.0	25.0	25.0	25.0	25.0	25.0	30.0
GWP	—	170	170	170	170	170	170	170	203
COP ratio	% (relative	94.6	94.9	95.4	96.0	96.7	97.4	98.2	95.3
	to R410A)
Refrigerating	% (relative	114.4	113.8	113.0	111.9	110.7	109.4	107.9	114.8
capacity ratio	to R410A)

TABLE 158

		Comparative	Comparative	Comparative	Comparative	Comparative			Comparative
Item	Unit	Example 51	Example 52	Example 53	Example 54	Example 55	Example 25	Example 26	Example 56

HFO-1132(E)	mass %	20.0	30.0	40.0	50.0	60.0	10.0	20.0	30.0
HFO-1123	mass %	50.0	40.0	30.0	20.0	10.0	55.0	45.0	35.0
R32	mass %	30.0	30.0	30.0	30.0	30.0	35.0	35.0	35.0
GWP	—	203	203	203	203	203	237	237	237
COP ratio	% (relative	95.6	96.0	96.6	97.2	97.9	96.0	96.3	96.6
	to R410A)
Refrigerating	% (relative	114.2	113.4	112.4	111.2	109.8	115.1	114.5	113.6
capacity ratio	to R410A)

TABLE 159

		Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative	Comparative
Item	Unit	Example 57	Example 58	Example 59	Example 60	Example 61	Example 62	Example 63	Example 64

HFO-1132(E)	mass %	40.0	50.0	60.0	10.0	20.0	30.0	40.0	50.0
HFO-1123	mass %	25.0	15.0	5.0	50.0	40.0	30.0	20.0	10.0
R32	mass %	35.0	35.0	35.0	40.0	40.0	40.0	40.0	40.0
GWP	—	237	237	237	271	271	271	271	271
COP ratio	% (relative	97.1	97.7	98.3	96.6	96.9	97.2	97.7	98.2
	to R410A)
Refrigerating	% (relative	112.6	111.5	110.2	115.1	114.6	113.8	112.8	111.7
capacity ratio	to R410A)

TABLE 160

Item	Unit	Example 27	Example 28	Example 29	Example 30	Example 31	Example 32	Example 33	Example 34

HFO-1132(E)	mass %	38.0	40.0	42.0	44.0	35.0	37.0	39.0	41.0
HFO-1123	mass %	60.0	58.0	56.0	54.0	61.0	59.0	57.0	55.0
R32	mass %	2.0	2.0	2.0	2.0	4.0	4.0	4.0	4.0
GWP	—	14	14	14	14	28	28	28	28
COP ratio	% (relative	93.2	93.4	93.6	93.7	93.2	93.3	93.5	93.7
	to R410A)
Refrigerating	% (relative	107.7	107.5	107.3	107.2	108.6	108.4	108.2	108.0
capacity ratio	to R410A)

TABLE 161

Item	Unit	Example 35	Example 36	Example 37	Example 38	Example 39	Example 40	Example 41	Example 42

HFO-1132(E)	mass %	43.0	31.0	33.0	35.0	37.0	39.0	41.0	27.0
HFO-1123	mass %	53.0	63.0	61.0	59.0	57.0	55.0	53.0	65.0
R32	mass %	4.0	6.0	6.0	6.0	6.0	6.0	6.0	8.0
GWP	—	28	41	41	41	41	41	41	55
COP ratio	% (relative	93.9	93.1	93.2	93.4	93.6	93.7	93.9	93.0
	to R410A)
Refrigerating	% (relative	107.8	109.5	109.3	109.1	109.0	108.8	108.6	110.3
capacity ratio	to R410A)

TABLE 162

Item	Unit	Example 43	Example 44	Example 45	Example 46	Example 47	Example 48	Example 49	Example 50

HFO-1132(E)	mass %	29.0	31.0	33.0	35.0	37.0	39.0	32.0	32.0
HFO-1123	mass %	63.0	61.0	59.0	57.0	55.0	53.0	51.0	50.0
R32	mass %	8.0	8.0	8.0	8.0	8.0	8.0	17.0	18.0
GWP	—	55	55	55	55	55	55	116	122
COP ratio	% (relative	93.2	93.3	93.5	93.6	93.8	94.0	94.5	94.7
	to R410A)
Refrigerating	% (relative	110.1	110.0	109.8	109.6	109.5	109.3	111.8	111.9
capacity ratio	to R410A)

TABLE 163

Item	Unit	Example 51	Example 52	Example 53	Example 54	Example 55	Example 56	Example 57	Example 58

HFO-1132(E)	mass %	30.0	27.0	21.0	23.0	25.0	27.0	11.0	13.0
HFO-1123	mass %	52.0	42.0	46.0	44.0	42.0	40.0	54.0	52.0
R32	mass %	18.0	31.0	33.0	33.0	33.0	33.0	35.0	35.0
GWP	—	122	210	223	223	223	223	237	237
COP ratio	% (relative	94.5	96.0	96.0	96.1	96.2	96.3	96.0	96.0
	to R410A)
Refrigerating	% (relative	112.1	113.7	114.3	114.2	114.0	113.8	115.0	114.9
capacity ratio	to R410A)

TABLE 164

Item	Unit	Example 59	Example 60	Example 61	Example 62	Example 63	Example 64	Example 65	Example 66

HFO-1132(E)	mass %	15.0	17.0	19.0	21.0	23.0	25.0	27.0	11.0
HFO-1123	mass %	50.0	48.0	46.0	44.0	42.0	40.0	38.0	52.0
R32	mass %	35.0	35.0	35.0	35.0	35.0	35.0	35.0	37.0
GWP	—	237	237	237	237	237	237	237	250
COP ratio	% (relative	96.1	96.2	96.2	96.3	96.4	96.4	96.5	96.2
	to R410A)
Refrigerating	% (relative	114.8	114.7	114.5	114.4	114.2	114.1	113.9	115.1
capacity ratio	to R410A)

TABLE 165

Item	Unit	Example 67	Example 68	Example 69	Example 70	Example 71	Example 72	Example 73	Example 74

HFO-1132(E)	mass %	13.0	15.0	17.0	15.0	17.0	19.0	21.0	23.0
HFO-1123	mass %	50.0	48.0	46.0	50.0	48.0	46.0	44.0	42.0
R32	mass %	37.0	37.0	37.0	0.0	0.0	0.0	0.0	0.0
GWP	—	250	250	250	237	237	237	237	237
COP ratio	% (relative	96.3	96.4	96.4	96.1	96.2	96.2	96.3	96.4
	to R410A)
Refrigerating	% (relative	115.0	114.9	114.7	114.8	114.7	114.5	114.4	114.2
capacity ratio	to R410A)

TABLE 166

Item	Unit	Example 75	Example 76	Example 77	Example 78	Example 79	Example 80	Example 81	Example 82

HFO-1132(E)	mass %	25.0	27.0	11.0	19.0	21.0	23.0	25.0	27.0
HFO-1123	mass %	40.0	38.0	52.0	44.0	42.0	40.0	38.0	36.0
R32	mass %	0.0	0.0	0.0	37.0	37.0	37.0	37.0	37.0
GWP	—	237	237	250	250	250	250	250	250
COP ratio	% (relative	96.4	96.5	96.2	96.5	96.5	96.6	96.7	96.8
	to R410A)
Refrigerating	% (relative	114.1	113.9	115.1	114.6	114.5	114.3	114.1	114.0
capacity ratio	to R410A)

The above results indicate that under the condition that the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, and the point (0.0, 100.0, 0.0) is on the left side are within the range of a figure surrounded by line segments that connect the following 4 points:

point O (100.0, 0.0, 0.0),
point A″ (63.0, 0.0, 37.0),
point B″ (0.0, 63.0, 37.0), and
point (0.0, 100.0, 0.0),
or on these line segments,
the refrigerant has a GWP of 250 or less.

The results also indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments that connect the following 4 points:

point O (100.0, 0.0, 0.0),
point A′ (81.6, 0.0, 18.4),
point B′ (0.0, 81.6, 18.4), and
point (0.0, 100.0, 0.0),
or on these line segments,
the refrigerant has a GWP of 125 or less.

The results also indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments that connect the following 4 points:

point O (100.0, 0.0, 0.0),
point A (90.5, 0.0, 9.5),
point B (0.0, 90.5, 9.5), and
point (0.0, 100.0, 0.0),
or on these line segments,
the refrigerant has a GWP of 65 or less.

The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:

point C (50.0, 31.6, 18.4),
point U (28.7, 41.2, 30.1), and
point D (52.2, 38.3, 9.5),
or on these line segments, the refrigerant has a COP ratio of 96% or more relative to that of R410A.

In the above, the line segment CU is represented by coordinates (−0.0538z²+0.7888z+53.701, 0.0538z²−1.7888z+46.299, z), and the line segment UD is represented by coordinates (−3.4962z²+210.71z−3146.1, 3.4962z²−211.71z+3246.1, z).

The points on the line segment CU are determined from three points, i.e.,

point C, Comparative Example 10, and point U, by using the least-square method.

The points on the line segment UD are determined from three points, i.e.,

point U, Example 2, and point D, by using the least-square method.

The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:

point E (55.2, 44.8, 0.0),
point T (34.8, 51.0, 14.2), and
point F (0.0, 76.7, 23.3),
or on these line segments,
the refrigerant has a COP ratio of 94.5% or more relative to that of R410A.

In the above, the line segment ET is represented by coordinates (−0.0547z²−0.5327z+53.4, 0.0547z²−0.4673z+46.6, z), and the line segment TF is represented by coordinates (−0.0982z²+0.9622z+40.931, 0.0982z²−1.9622z+59.069, z).

The points on the line segment ET are determined from three points, i.e.,

point E, Example 2, and point T, by using the least-square method.

The points on the line segment TF are determined from three points, i.e., points T, S, and F, by using the least-square method.

The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:

point G (0.0, 76.7, 23.3),
point R (21.0, 69.5, 9.5), and
point H (0.0, 85.9, 14.1),
or on these line segments, the refrigerant has a COP ratio of 93% or more relative to that of R410A.

In the above, the line segment GR is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and the line segment RH is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z).

The points on the line segment GR are determined from three points, i.e.,

point G, Example 5, and point R, by using the least-square method.

The points on the line segment RH are determined from three points, i.e.,

point R, Example 7, and point H, by using the least-square method.

In contrast, as shown in, for example, Comparative Examples 8, 9, 13, 15, 17, and 18, when R32 is not contained, the concentrations of HFO-1132(E) and HFO-1123, which have a double bond, become relatively high; this undesirably leads to deterioration, such as decomposition, or polymerization in the refrigerant compound.

(6) Specific Embodiment

FIG. 16 is a configuration diagram of an air conditioner 1 according to a first embodiment of the present disclosure. In FIG. 16, the air conditioner 1 is constituted by a utilization unit 2 and a heat source unit 3.

(6-1) Configuration of Air Conditioner 1

The air conditioner 1 has a refrigerant circuit 11 in which a compressor 100, a four-way switching valve 16, a heat-source-side heat exchanger 17, an expansion valve 18 serving as a decompression mechanism, and a utilization-side heat exchanger 13 are connected in a loop shape by refrigerant pipes.

In this embodiment, the refrigerant circuit 11 is filled with refrigerant for performing a vapor compression refrigeration cycle. The refrigerant is a refrigerant mixture containing 1,2-difluoroethylene, and any one of the above-described refrigerant A to refrigerant E can be used. The refrigerant circuit 11 is filled with refrigerating machine oil together with the refrigerant mixture.

(6-1-1) Utilization Unit 2

In the refrigerant circuit 11, the utilization-side heat exchanger 13 belongs to the utilization unit 2. In addition, a utilization-side fan 14 is mounted in the utilization unit 2. The utilization-side fan 14 generates an air flow to the utilization-side heat exchanger 13.

A utilization-side communicator 35 and a utilization-side microcomputer 41 are mounted in the utilization unit 2. The utilization-side communicator 35 is connected to the utilization-side microcomputer 41.

The utilization-side communicator 35 is used by the utilization unit 2 to communicate with the heat source unit 3. The utilization-side microcomputer 41 is supplied with a control voltage even during a standby state in which the air conditioner 1 is not operating. Thus, the utilization-side microcomputer 41 is constantly activated.

(6-1-2) Heat Source Unit 3

In the refrigerant circuit 11, the compressor 100, the four-way switching valve 16, the heat-source-side heat exchanger 17, and the expansion valve 18 belong to the heat source unit 3. In addition, a heat-source-side fan 19 is mounted in the heat source unit 3. The heat-source-side fan 19 generates an air flow to the heat-source-side heat exchanger 17.

In addition, a connection unit 30, a heat-source-side communicator 36, and a heat-source-side microcomputer 42 are mounted in the heat source unit 3. The connection unit 30 and the heat-source-side communicator 36 are connected to the heat-source-side microcomputer 42.

(6-2) Configuration of Connection Unit 30

FIG. 17 is an operation circuit diagram of a motor 70 of the compressor 100. In FIG. 17, the connection unit 30 is a circuit that causes power to be supplied from an alternating-current (AC) power source 90 to the motor 70 of the compressor 100 without frequency conversion.

The motor 70 is an induction motor and includes a squirrel-cage rotor 71, and a stator 72 having a main winding 727 and an auxiliary winding 728. The squirrel-cage rotor 71 rotates following a rotating magnetic field generated by the stator 72.

The compressor 100 has an M terminal, an S terminal, and a C terminal. The M terminal and the C terminal are connected by the main winding 727. The S terminal and the C terminal are connected by the auxiliary winding 728.

The AC power source 90 and the compressor 100 are connected by power supply lines 901 and 902 that supply an AC voltage to the compressor 100. The power supply line 901 is connected to the C terminal via a thermostat 26.

The thermostat 26 detects a temperature of a room equipped with the air conditioner 1. The thermostat 26 opens the contact thereof when the room temperature is within a set temperature range and closes the contact when the room temperature is out of the set temperature range.

The power supply line 902 branches off into a first branch line 902A and a second branch line 902B. The first branch line 902A is connected to the M terminal, and the second branch line 902B is connected to the S terminal via an activation circuit 20.

The activation circuit 20 is a circuit in which a positive temperature coefficient (PTC) thermistor 21 and an operation capacitor 22 are connected in parallel to each other.

In this embodiment, the thermostat 26 connected to the power supply line 901 and the activation circuit 20 connected to the power supply line 902 are referred to as the connection unit 30.

(6-3) Operation

In the operation circuit of the compressor 100 having the above-described configuration, turning on of the AC power source 90 causes a current to flow through the auxiliary winding 728 via the PTC thermistor 21 and the motor 70 to be activated.

After the motor 70 has been activated, the PTC thermistor 21 self-heats by using the current flowing therethrough, and the resistance value thereof increases. As a result, the operation capacitor 22, instead of the PTC thermistor 21, is connected to the auxiliary winding 728, and the state shifts to a stable operation state.

(6-4) Features

(6-4-1)

In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor 100 can be driven without interposing a power conversion device between the AC power source 90 and the motor 70. Thus, it is possible to provide the air conditioner 1 that is environmentally friendly and has a relatively inexpensive configuration.

(6-4-2)

In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the connection between the auxiliary winding 728 and the activation circuit 20, which is a parallel circuit of the PTC thermistor 21 and the operation capacitor 22, makes it possible to achieve a large activation torque of the motor 70 of the compressor 100.

After the compressor 100 has been activated, the PTC thermistor 21 self-heats and the resistance value thereof increases, the state changes to a state where the operation capacitor 22 and the auxiliary winding 728 are substantially connected to each other, and the compressor 100 is operated at a constant rotation rate (power source frequency). Thus, the compressor 100 enters a state of being capable of outputting a rated torque. As described above, in the air conditioner 1, switching of connection to the operation capacitor 22 is performed at appropriate timing, and thus the efficiency of the compressor 100 can be increased.

(6-4-3)

The motor 70 is an induction motor and is capable of high output with relatively low cost, and thus the efficiency of the air conditioner 1 can be increased.

(6-5) Modification example

FIG. 18 is an operation circuit diagram of a motor 170 of a compressor 200 in the air conditioner 1 according to a modification example. In FIG. 18, the motor 170 is a three-phase induction motor and is connected to a three-phase AC power source 190 via a connection unit 130.

The connection unit 130 is a relay having contacts 130u, 130v, and 130w. The contact 130u opens or closes a power supply line 903 between an R terminal of the three-phase AC power source 190 and a U-phase winding Lu of the motor 170. The contact 130v opens or closes a power supply line 904 between an S terminal of the three-phase AC power source 190 and a V-phase winding Lv of the motor 170. The contact 130w opens or closes a power supply line 905 between a T terminal of the three-phase AC power source 190 and a W-phase winding Lw of the motor 170.

AC voltages are supplied from the R terminal, the S terminal, and the T terminal of the three-phase AC power source 190 to the corresponding U-phase winding Lu, the V-phase winding Lv, and the W-phase winding Lw of the motor 170. The AC voltage supplied to the V-phase winding Lv of the motor 170 has a phase difference of 120 degrees with respect to the AC voltage supplied to the U-phase winding Lu. Also, the AC voltage supplied to the W-phase winding Lw of the motor 170 has a phase difference of 120 degrees with respect to the AC voltage supplied to the V-phase winding Lv.

Thus, only the supply of AC voltages from the three-phase AC power source 190 to the motor 170 causes a rotating magnetic field to be generated in the stator 172, and the rotor 171 rotates following the rotating magnetic field. As a result, the compressor 200 is operated at a constant rotation rate (power source frequency). Thus, the operation circuit of the motor 170 does not require the activation circuit 20 according to the foregoing embodiment, and only a relay circuit of the connection unit 130 is used.

(6-6) Features of Modification Example

(6-6-1)

In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor 200 can be driven without interposing a power conversion device between the three-phase AC power source 190 and the motor 170. Thus, it is possible to provide the air conditioner 1 that is environmentally friendly and has a relatively inexpensive configuration.

(6-6-2)

The motor 170 is an induction motor and is capable of high output with relatively low cost, and thus the efficiency of the air conditioner 1 can be increased.

An embodiment of the present disclosure has been described above. It is to be understood that various changes of the embodiment and details are possible without deviating from the gist and scope of the present disclosure described in the claims.

REFERENCE SIGNS LIST

- 1: air conditioner
- 20: activation circuit
- 21: positive temperature coefficient thermistor
- 22: operation capacitor
- 30: connection unit
- 70: motor
- 90: single-phase AC power source
- 100: compressor
- 130: connection unit
- 170: motor
- 190: three-phase AC power source
- 200: compressor

CITATION LIST

Patent Literature

PTL 1: Japanese Unexamined Patent Application Publication No. 2013-124848

Claims

1. An air conditioner comprising:

a compressor that compresses a refrigerant containing at least 1,2-difluoroethylene;

a motor that drives the compressor; and

a connection unit that causes power to be supplied from an alternating-current (AC) power source to the motor without frequency conversion.

2. The air conditioner according to claim 1, wherein the connection unit directly applies an AC voltage of the AC power source between at least two terminals of the motor.

3. The air conditioner according to claim 1, wherein the AC power source is a single-phase power source.

4. The air conditioner according to claim 1, wherein one terminal of the motor is connected in series to an activation circuit.

5. The air conditioner according to claim 4, wherein the activation circuit is a circuit in which a positive temperature coefficient thermistor and an operation capacitor are connected in parallel to each other.

6. The air conditioner according to claim 1, wherein the AC power source is a three-phase power source.

7. The air conditioner according to claim 1, wherein the motor is an induction motor.

8. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

9. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:

point A (68.6, 0.0, 31.4),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point D (0.0, 80.4, 19.6),

point C′ (19.5, 70.5, 10.0),

point C (32.9, 67.1, 0.0), and

point O (100.0, 0.0, 0.0),

or on the above line segments (excluding the points on the line segments BD, CO, and OA);

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments BD, CO, and OA are straight lines.

10. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:

point G (72.0, 28.0, 0.0),

point I (72.0, 0.0, 28.0),

point A (68.6, 0.0, 31.4),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point D (0.0, 80.4, 19.6),

point C′ (19.5, 70.5, 10.0), and

point C (32.9, 67.1, 0.0),

or on the above line segments (excluding the points on the line segments IA, BD, and CG);

the line segment AA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments GI, IA, BD, and CG are straight lines.

11. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

point J (47.1, 52.9, 0.0),

point P (55.8, 42.0, 2.2),

point N (68.6, 16.3, 15.1),

point K (61.3, 5.4, 33.3),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point D (0.0, 80.4, 19.6),

point C′ (19.5, 70.5, 10.0), and

point C (32.9, 67.1, 0.0),

or on the above line segments (excluding the points on the line segments BD and CJ);

the line segment PN is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment NK is represented by coordinates (x, 0.2421x²−29.955x+931.91, −0.2421x²+28.955x−831.91),

the line segment KA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, BD, and CG are straight lines.

12. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:

point J (47.1, 52.9, 0.0),

point P (55.8, 42.0, 2.2),

point L (63.1, 31.9, 5.0),

point M (60.3, 6.2, 33.5),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point D (0.0, 80.4, 19.6),

point C′ (19.5, 70.5, 10.0), and

point C (32.9, 67.1, 0.0),

or on the above line segments (excluding the points on the line segments BD and CJ);

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43)

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment DC′ is represented by coordinates (x, 0.0082x²−0.6671x+80.4, −0.0082x²−0.3329x+19.6),

the line segment C′C is represented by coordinates (x, 0.0067x²−0.6034x+79.729, −0.0067x²−0.3966x+20.271), and

the line segments JP, LM, BD, and CG are straight lines.

13. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:

point P (55.8, 42.0, 2.2),

point L (63.1, 31.9, 5.0),

point M (60.3, 6.2, 33.5),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point F (0.0, 61.8, 38.2), and

point T (35.8, 44.9, 19.3),

or on the above line segments (excluding the points on the line segment BF);

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LM and BF are straight lines.

14. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:

point P (55.8, 42.0, 2.2),

point L (63.1, 31.9, 5.0),

point Q (62.8, 29.6, 7.6), and

point R (49.8, 42.3, 7.9),

or on the above line segments;

the line segment PL is represented by coordinates (x, −0.1135x²+12.112x−280.43, 0.1135x²−13.112x+380.43),

the line segment RP is represented by coordinates (x, 0.00672x²−0.7607x+63.525, −0.00672x²−0.2393x+36.475), and

the line segments LQ and QR are straight lines.

15. The air conditioner according to claim 8,

wherein

when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:

point S (62.6, 28.3, 9.1),

point M (60.3, 6.2, 33.5),

point A′ (30.6, 30.0, 39.4),

point B (0.0, 58.7, 41.3),

point F (0.0, 61.8, 38.2), and

point T (35.8, 44.9, 19.3),

or on the above line segments,

the line segment MA′ is represented by coordinates (x, 0.0016x²−0.9473x+57.497, −0.0016x²−0.0527x+42.503),

the line segment A′B is represented by coordinates (x, 0.0029x²−1.0268x+58.7, −0.0029x²+0.0268x+41.3),

the line segment FT is represented by coordinates (x, 0.0078x²−0.7501x+61.8, −0.0078x²−0.2499x+38.2),

the line segment TS is represented by coordinates (x, −0.0017x²−0.7869x+70.888, −0.0017x²−0.2131x+29.112), and

the line segments SM and BF are straight lines.

16. The air conditioner according claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and

the refrigerant comprises 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire refrigerant.

17. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and

the refrigerant comprises 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.

18. The air conditioner according to claim 1,

wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)),

trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,

point G (0.026a²−1.7478a+72.0, −0.026a²+0.7478a+28.0, 0.0),

point I (0.026a²−1.7478a+72.0, 0.0, −0.026a²+0.7478a+28.0),

point A (0.0134a²−1.9681a+68.6, 0.0, −0.0134a²+0.9681a+31.4),

point B (0.0, 0.0144a²−1.6377a+58.7, −0.0144a²+0.6377a+41.3),

point D′ (0.0, 0.0224a²+0.968a+75.4, −0.0224a²−1.968a+24.6), and

point C (−0.2304a²−0.4062a+32.9, 0.2304a²−0.5938a+67.1, 0.0),

or on the straight lines GI, AB, and D′C (excluding point G, point I, point A, point B, point D′, and point C);

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.02a²−1.6013a+71.105, −0.02a²+0.6013a+28.895, 0.0),

point I (0.02a²−1.6013a+71.105, 0.0, −0.02a²+0.6013a+28.895),

point A (0.0112a²−1.9337a+68.484, 0.0, −0.0112a²+0.9337a+31.516),

point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0135a²−1.4068a+69.727, −0.0135a²+0.4068a+30.273, 0.0),

point I (0.0135a²−1.4068a+69.727, 0.0, −0.0135a²+0.4068a+30.273),

point A (0.0107a²−1.9142a+68.305, 0.0, −0.0107a²+0.9142a+31.695),

point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0111a²−1.3152a+68.986, −0.0111a²+0.3152a+31.014, 0.0),

point I (0.0111a²−1.3152a+68.986, 0.0, −0.0111a²+0.3152a+31.014),

point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),

point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W); and

if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:

point G (0.0061a²−0.9918a+63.902, −0.0061a²−0.0082a+36.098, 0.0),

point I (0.0061a²−0.9918a+63.902, 0.0, −0.0061a²−0.0082a+36.098),

point A (0.0085a²−1.8102a+67.1, 0.0, −0.0085a²+0.8102a+32.9),

point B (0.0, 0.0012a²−1.1659a+52.95, −0.0012a²+0.1659a+47.05), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W).

19. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,

if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines JK′, K′B, BD′, D′C, and CJ that connect the following 5 points:

point J (0.0049a²−0.9645a+47.1, −0.0049a²−0.0355a+52.9, 0.0),

point K′ (0.0514a²−2.4353a+61.7, −0.0323a²+0.4122a+5.9, −0.0191a²+1.0231a+32.4),

point B (0.0, 0.0144a²−1.6377a+58.7, −0.0144a²+0.6377a+41.3),

point D′ (0.0, 0.0224a²+0.968a+75.4, −0.0224a²−1.968a+24.6), and

point C (−0.2304a²−0.4062a+32.9, 0.2304a²−0.5938a+67.1, 0.0),

or on the straight lines JK′, K′B, and D′C (excluding point J, point B, point D′, and point C);

if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0243a²−1.4161a+49.725, −0.0243a²+0.4161a+50.275, 0.0),

point K′ (0.0341a²−2.1977a+61.187, −0.0236a²+0.34a+5.636, −0.0105a²+0.8577a+33.177),

point B (0.0, 0.0075a²−1.5156a+58.199, −0.0075a²+0.5156a+41.801), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:

point J (0.0246a²−1.4476a+50.184, −0.0246a²+0.4476a+49.816, 0.0),

point K′ (0.0196a²−1.7863a+58.515, −0.0079a²−0.1136a+8.702, −0.0117a²+0.8999a+32.783),

point B (0.0, 0.009a²−1.6045a+59.318, −0.009a²+0.6045a+40.682), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

point J (0.0183a²−1.1399a+46.493, −0.0183a²+0.1399a+53.507, 0.0),

point K′ (−0.0051a²+0.0929a+25.95, 0.0, 0.0051a²−1.0929a+74.05),

point A (0.0103a²−1.9225a+68.793, 0.0, −0.0103a²+0.9225a+31.207),

point B (0.0, 0.0046a²−1.41a+57.286, −0.0046a²+0.41a+42.714), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W); and

point J (−0.0134a²+1.0956a+7.13, 0.0134a²−2.0956a+92.87, 0.0),

point K′ (−1.892a+29.443, 0.0, 0.892a+70.557),

point A (0.0085a²−1.8102a+67.1, 0.0, −0.0085a²+0.8102a+32.9),

point B (0.0, 0.0012a²−1.1659a+52.95, −0.0012a²+0.1659a+47.05), and

point W (0.0, 100.0−a, 0.0),

or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W).

20. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

point I (72.0, 0.0, 28.0),

point J (48.5, 18.3, 33.2),

point N (27.7, 18.2, 54.1), and

point E (58.3, 0.0, 41.7),

or on these line segments (excluding the points on the line segment EI;

the line segment U is represented by coordinates (0.0236y²−1.7616y+72.0, y, −0.0236y²+0.7616y+28.0);

the line segment NE is represented by coordinates (0.012y²−1.9003y+58.3, y, −0.012y²+0.9003y+41.7); and

the line segments JN and EI are straight lines.

21. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)),

difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:

point M (52.6, 0.0, 47.4),

point M′(39.2, 5.0, 55.8),

point N (27.7, 18.2, 54.1),

point V (11.0, 18.1, 70.9), and

point G (39.6, 0.0, 60.4),

or on these line segments (excluding the points on the line segment GM);

the line segment MM′ is represented by coordinates (0.132y²−3.34y+52.6, y, −0.132y²+2.34y+47.4);

the line segment M′N is represented by coordinates (0.0596y²−2.2541y+48.98, y, −0.0596y²+1.2541y+51.02);

the line segment VG is represented by coordinates (0.0123y²−1.8033y+39.6, y, −0.0123y²+0.8033y+60.4); and

the line segments NV and GM are straight lines.

22. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

point O (22.6, 36.8, 40.6),

point N (27.7, 18.2, 54.1), and

point U (3.9, 36.7, 59.4),

or on these line segments;

the line segment ON is represented by coordinates (0.0072y²−0.6701y+37.512, y, −0.0072y²−0.3299y+62.488);

the line segment NU is represented by coordinates (0.0083y²−1.7403y+56.635, y, −0.0083y²+0.7403y+43.365); and

the line segment UO is a straight line.

23. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)),

difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:

point Q (44.6, 23.0, 32.4),

point R (25.5, 36.8, 37.7),

point T (8.6, 51.6, 39.8),

point L (28.9, 51.7, 19.4), and

point K (35.6, 36.8, 27.6),

or on these line segments;

the line segment QR is represented by coordinates (0.0099y²−1.975y+84.765, y, −0.0099y²+0.975y+15.235);

the line segment RT is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874);

the line segment LK is represented by coordinates (0.0049y²−0.8842y+61.488, y, −0.0049y²−0.1158y+38.512);

the line segment KQ is represented by coordinates (0.0095y²−1.2222y+67.676, y, −0.0095y²+0.2222y+32.324); and

the line segment TL is a straight line.

24. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)),

difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),

wherein

when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (20.5, 51.7, 27.8),

point S (21.9, 39.7, 38.4), and

point T (8.6, 51.6, 39.8),

or on these line segments;

the line segment PS is represented by coordinates (0.0064y²−0.7103y+40.1, y, −0.0064y²−0.2897y+59.9);

the line segment ST is represented by coordinates (0.0082y²−1.8683y+83.126, y, −0.0082y²+0.8683y+16.874); and

the line segment TP is a straight line.

25. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

point I (72.0, 28.0, 0.0),

point K (48.4, 33.2, 18.4),

point B′ (0.0, 81.6, 18.4),

point H (0.0, 84.2, 15.8),

point R (23.1, 67.4, 9.5), and

point G (38.5, 61.5, 0.0),

or on these line segments (excluding the points on the line segments B′H and GI);

the line segment IK is represented by coordinates (0.025z²−1.7429z+72.00, −0.025z²+0.7429z+28.0, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments KB′ and GI are straight lines.

26. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments U, JR, RG, and GI that connect the following 4 points:

point I (72.0, 28.0, 0.0),

point J (57.7, 32.8, 9.5),

point R (23.1, 67.4, 9.5), and

point G (38.5, 61.5, 0.0),

or on these line segments (excluding the points on the line segment GI);

the line segment U is represented by coordinates (0.025z²−1.7429z+72.0, −0.025z²+0.7429z+28.0, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments JR and GI are straight lines.

27. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MP, PB′, B′H, HR, RG, and GM that connect the following 6 points:

point M (47.1, 52.9, 0.0),

point P (31.8, 49.8, 18.4),

point B′ (0.0, 81.6, 18.4),

point H (0.0, 84.2, 15.8),

point R (23.1, 67.4, 9.5), and

point G (38.5, 61.5, 0.0),

or on these line segments (excluding the points on the line segments B′H and GM);

the line segment MP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment HR is represented by coordinates (−0.3123z²+4.234z+11.06, 0.3123z²−5.234z+88.94, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments PB′ and GM are straight lines.

28. The air conditioner according to claim 1,

wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MN, NR, RG; and GM that connect the following 4 points:

point M (47.1, 52.9, 0.0),

point N (38.5, 52.1, 9.5),

point R (23.1, 67.4, 9.5), and

point G (38.5, 61.5, 0.0),

or on these line segments (excluding the points on the line segment GM);

the line segment MN is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z),

the line segment RG is represented by coordinates (−0.0491z²−1.1544z+38.5, 0.0491z²+0.1544z+61.5, z), and

the line segments JR and GI are straight lines.

29. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:

point P (31.8, 49.8, 18.4),

point S (25.4, 56.2, 18.4), and

point T (34.8, 51.0, 14.2),

or on these line segments;

the line segment ST is represented by coordinates (−0.0982z²+0.9622z+40.931, 0.0982z²−1.9622z+59.069, z),

the line segment TP is represented by coordinates (0.0083z²−0.984z+47.1, −0.0083z²−0.016z+52.9, z), and

the line segment PS is a straight line.

30. The air conditioner according to claim 1,

wherein

the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),

wherein

when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments QB″, B″D, DU, and UQ that connect the following 4 points:

point Q (28.6, 34.4, 37.0),

point B″ (0.0, 63.0, 37.0),

point D (0.0, 67.0, 33.0), and

point U (28.7, 41.2, 30.1),

or on these line segments (excluding the points on the line segment B″D);

the line segment DU is represented by coordinates (−3.4962z²+210.71z−3146.1, 3.4962z²−211.71z+3246.1, z),

the line segment UQ is represented by coordinates (0.0135z²−0.9181z+44.133, −0.0135z²−0.0819z+55.867, z), and

the line segments QB″ and B″D are straight lines.

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