AVOIDING STAINS IN DYED CATIONICALLY MODIFIED COTTON FABRICS

Description

TECHNICAL FIELD

The current disclosure pertains to a process for improving the stain resistance of a cationically modified fabric containing natural fibers (e.g., cotton-based).

BACKGROUND

Textile dyeing is the process of applying pigments or dyes on textile materials such as fabrics, yarns, and fibers. Desirably, the dyeing process is efficient and rapid, and provides the dyed textile with a desired degree of coloring, and resistance to fading and running of the dye (color fastness). Further, the dyeing process and the materials used therein preferably do not adversely affect the aspects of the textile, such as its flexibility, durability, and tactile properties like softness, smoothness, stiffness.

Creating “cationic cotton” by introducing a positive charge to a cotton fabric or textile for increased dye uptake is well known. One of the most common methods to cationically modify natural fibers such as cotton is to use epoxy-based ammonium compounds, such as 3-chloro-2-hydroxypropyltrimethylammonium chloride, to add a charge to the natural fiber's cellulose polymer backbone. Other agents, such as the ether amino salts described in U.S. Pat. No. 9,493,398 have also been proved to be effective in creating cationic fibers such as cotton.

Ammonium quaternary suppliers typically suggest the use of different amounts of the cationic agent, depending on the desired color shade after dyeing, with darker shades demanding a higher content of the agent, and lighter shades demanding a lower content. However, the use of different amounts of the agent complicates the production and handling and therefore is not desired by textile mills. A single cationic agent recommended content for all shades is becoming a reality, with high amounts of ammonium quaternaries on cationic cotton. However, it has been observed that this single content of cationic agents tends to allow light and medium shades of dyed cationic fabric to be more subject to staining during home washes, which is believed to be due to the released dye from darker clothes produced from conventional dyeing methods in the same wash.

It is desired to have a process to prevent such staining.

To avoid this staining, a method of applying acrylic polymers in cationic fabrics is presented involving the step of having an acrylic polymer in contact with a cationic cotton. For a longer life cycles of the staining resistance, the pH of the environment with a modified dyed natural fiber which has previously been reacted with cationic agent should be similar to the regular pH of the acrylic polymer sample. However, for shorter life cycles, the staining resistance does not present significant relationship with the standard pH of the acrylic polymer sample and the pH of the environment with a modified dyed natural fiber which has previously been reacted with cationic agent.

SUMMARY

It is proposed to have an acrylic polymer in contact with a modified dyed cotton or other natural fiber, which fiber had previously been reacted with cationic agent to avoid staining in the cationic material. For long lasting life cycles of the staining resistance, the environment pH should be similar to the regular pH of the acrylic polymer sample. It has been observed that when the acrylic polymer is contacted with the cationized fabric at a pH which is similar to the standard pH of the acrylic polymer, the acrylic polymer tends to attach to the fabric more robustly. When the acrylic polymer molecule attaches to the cationic cotton, it is believed that it will block spots susceptible to dye staining from the fabric, thereby avoiding the stains during different process, like home washes. However, for short lasting (or “short term”) life cycles, the staining resistance does not strongly present significant relationship between the standard pH of the acrylic polymer sample and the environment, being more related with the contact between the acrylic polymer and the cationic cotton.

The proposed solution is believed to be effective with all of the different cationic agents currently applied in cationic fabric, but it is recommended to use the ether amino salt type of cationic reagents disclosed in US patent U.S. Pat. No. 9,493,398B2.

Cationic cotton (or other natural fiber) is prepared either by continuous or jet exhaust application. These processes use sodium hydroxide aqueous solution maximum 50% wt., and a cationic reagent (preferably of the sort identified in U.S. Pat. No. 9,493,398B2). With that, a cationic cotton is obtained.

The cationic cotton (or other natural fiber) is then dyed in a latter process step as is known in the art.

In the method of the present invention, for long lasting life cycles, either during dyeing or after it, the fiber is allowed to be in contact with an acrylic polymer under a pH environment similar to the regular pH of the acrylic polymer sample, controlled by the addition of sodium carbonate or other basic substance, to increase the pH, or citric acid or other acidic substance to decrease the pH. Also, the method of this application can also be with acrylic polymer by itself or in mixture with common chemistries present in textile process, such as softener agents in finishing steps.

DETAILED DESCRIPTION OF THE INVENTION

The embodiments of the present invention described below are not intended to be exhaustive or to limit the invention to the precise forms disclosed in the following detailed description. Rather, the embodiments are chosen and described so that others skilled in the art can appreciate and understand the principles and practices of the present invention.

All publications and patents mentioned herein are hereby incorporated by reference to the full extent permitted under the relevant laws. The publications and patents disclosed herein are provided solely for their disclosure. Nothing herein is to be construed as an admission that the inventors are not entitled to antedate any publication and/or patent, including any publication and/or patent cited herein.

The term “about” used preceding any numerical value of the disclosure or appended claims allows some slight imprecision in that stated numerical value, which imprecision may either be understood in the art, or may result from methods of measuring to obtain such numerical values (e.g., such as with chemical or physical measurements), and any numerical value not preceded by the term “about” of the disclosure or appended claims may also be understood the same way.

Methods and compositions of the disclosure described as “comprising” or “including” can include those recited step and compounds, respectively, and optionally can include other steps and components. If methods or compositions of the disclosure are described as “consisting of,” those methods or compositions have the recited steps or compounds but do not include steps or compounds that are not recited. The term “consisting essentially of” generally refers to compositions that include the recited compounds and may include other non-recited compounds, but in unsubstantial amounts. For example, such compositions can include one or more other non-recited components but not in an amount that is greater than about 1% (by weight), greater than about 0.5% (by weight), or greater than about 0.1% (by weight) of the total composition. In a composition “consisting of” the recited components there is no other measurable amount of component other than the recited component, or a method “consisting” of certain steps includes no other steps than those ones recited.

For the purposes of the present invention, it should be understood that “textiles” includes yarns, fabrics, as well as articles made from fabric or yarns such as garments or linens.

In its broadest sense, the present invention is a method for improving the stain resistance of a cationized fiber or textile comprising natural fiber. The method comprises the steps of immersing the cationized fiber or textile in an aqueous solution having a given pH and then contacting the fabric immersed in the aqueous solution with an acrylic polymer having or not a standard pH under conditions sufficient to allow at least a portion of the acrylic polymer to attach to the fiber or fabric. Notably, the aqueous solution has been selected or adjusted to have a pH that is similar to the standard pH of the acrylic polymer prior to the addition of the acrylic polymer. The adjustment or not of the environment pH to a similar standard pH of the acrylic polymer will depend on the desire or not of the long lasting staining resistance of the cationic fabric material. If a shorter staining resistance shelf life is desired, no pH adjustments are necessary. However, if a longer staining resistance shelf life is desired, the environment pH should be similar to the standard pH of the acrylic polymer.

The present invention involves modifying a natural fiber which has been cationized and dyed. The cationization can be done using agents known in the art. It is preferred that the ether amino salts described in US U.S. Pat. No. 9,493,398B2 be used. As is known in the art, the cationization process typically involves reacting the natural fiber or textile with the cationic agent in a continuous (e.g., cold pad bath) or jet exhaust application in the presence of an aqueous sodium hydroxide solution have no more than about 50 weight percent sodium hydroxide. Time and temperature of such cationization process as well as the identity and amount of cationization agent used, may be varied as is generally known in the art.

After the cationization step, the fiber or textile is typically washed and neutralized with an aqueous solution of up to 5 grams per liter acetic or citric acid. After neutralization the fiber or textile may optionally be dried and then subjected to an aqueous dying process, as per the recommendations of the dye manufacturers.

In the present invention, the fiber or textile is kept in contact with an acrylic polymer. This contact may be conducted simultaneously with the dying or in a separate step after the dying, like in finishing step. This step involves placing the fiber or textile in an aqueous solution having a pH similar to the original pH of the acrylic polymer additive that will be used for long lasting staining resistance cycles. For shorter staining resistance cycles, the pH of the environment does not need a previous modification, as there is no significant dependence on the standard pH of the acrylic polymer being used as antistaing additive. The terms “regular”, “original” or “standard” pH are used interchangeably in the present application, and are meant to denote the pH of the acrylic polymer as produced or if purchased, the sales specification, which may be stated as a range. For purposes of this application, the term “similar” means a pH with a value within plus or minus 1, preferably plus or minus 0.5, even more preferably plus or minus 0.25, of the regular pH of the acrylic polymer. If the aqueous solution used in this step does not naturally have a pH which is similar to the acrylic polymer which will be used, then the pH can be adjusted prior to the addition of the acrylic polymer. To increase the pH of the aqueous solution, sodium carbonate, or other alkaline substance, like soda ash, sodium hydroxide, etc., can be added, and to decrease the pH, citric acid, acetic acid or other acidic solution can be added. The amount of substance added in order to adjust the pH of the aqueous solution will depend on the target pH desired to be achieved, as is generally known in the art.

As textile processes in mills tend to be conducted under alkaline conditions, it may be preferred that acrylic polymers having a higher standard pH be used, such that less adjustment of an aqueous solution resulting from a previous process will be needed. In other circumstances though, the use of acrylic polymers having a more neutral pH will be preferred as the more neutral aqueous solutions may require less care in handling.

For long lasting staining resistance cycles, when the desired pH for the aqueous solution has been achieved, the fiber or textile is contacted with an acrylic polymer with a standard pH which is then similar to the reactive environment. The acrylic polymer can be any polymer derived from acrylic acid or methacrylic acid, including acrylate or methacrylate esters, and salts thereof. Thus, the monomers can advantageously include acrylic acid, t-butyl acrylate, or methyl methacrylate and mixtures thereof. The acrylic polymer can be a homopolymer or may contain two or more monomers. It is generally preferred that the acrylic polymer have a molecular weight in the range of from 2,000, 2,500, 3,000 or even 3,300 to 4,500, 4,300, 4,100 or even 3,900 g/mol. These polymers can be produced as is generally known in the art or can be commercially obtained.

The amount of acrylic polymer in the aqueous solution can be in a range of from 5 g/L, 20 g/L, 30 g/L, 50 g/L or even 90 g/L up to a maximum of 100 g/L, 90 g/L. 80 g/L or even 70 g/L. For example, for some applications it may be beneficial to have a concentration of acrylic polymer in the aqueous solution in the range of from 90 to 100 g/L while in other application it may be desirable to have a concentration of acrylic polymer in the aqueous solution in the range of from 30 to 70 g/L.

The fiber or textile is contacted with the acrylic polymer under conditions to allow the polymer to become at least partially attached to the fiber or textile the contact between the acrylic polymer and the cationic cotton. This can advantageously be done at room temperature for a period of up to an hour, preferably from 10 to 30 minutes.

For long lasting staining resistance cycles, the fiber or textile is then neutralized by the addition of an acidic solution, which can be citric acid, acetic acid or any other acidic substance. Typically, this neutralization is carried out by the addition of 5-100 g/L of the acidic substance.

Different methodologies are proposed to evaluate the method of the present invention efficacy against stain which, in general, they depend on: dyed cationic cotton with or without the additive is left in contact with an aqueous solution of dark dye for a period of time, after which the fabric is removed and both the fabric's color and the bath's color are evaluated. Unchanged fabric and darker bath are both indications that the additive was successful at preventing staining because it keeps the dye from attaching to the cationic fabric.

Examples

The process of the current invention is demonstrated in the following examples.

Table 1A presents a table of materials used in the Examples:

TABLE 1A
Compound	Structure	Function
Cationic Reagent A	1-Propanaminium, N,N′-(oxydi-	Cationic agent for cotton
	2,1-ethanediyl)bis[3-chloro-2-	material
	hydroxy-N,N-dimethyl-,
	chloride (1:2)
Acrylic Polymer A	Acrylic homopolymer	Anti-staining Additive
	Type Poly Acrylic Acid, MW
	2,000 g/mol
	End group sodium metabisulfite
	Standard pH: 3.0-4.0
Acrylic Polymer B	Acrylic homopolymer	Anti-staining Additive
	Type Poly Acrylic Acid, MW
	4,500
	End group sodium metabisulfite
	Standard pH: 3.0-4.0
Acrylic Polymer C	Acrylic terpolymer	Anti-staining Additive
	Type Acrylic Acid, 2-
	Acrylamido-2-methylpropane
	sulfonic acid, t-butylacrylamide
	MW 4,500
	End group sodium metabisulfite
	Standard pH: 2.0-3.0
Acrylic Polymer D	Acrylic homopolymer	Anti-staining Additive
	Type Poly Acrylic Acid
	MW 3,600
	End group sodium
	hypophosphite
	Standard pH: 3.0-4.0
Acrylic Polymer E	Acrylic homopolymer	Anti-staining Additive
	Poly Acrylic Acid
	MW 3,500
	End group sodium phosphinate
	Standard pH: 6.5-7.5
Acrylic Polymer F	Acrylic homopolymer	Anti-staining additive
	Poly Acrylic Acid
	MW 2,150
	End group sodium metabisulfite
	Standard pH: 3.0-4.0
Acrylic Polymer G	Acrylic homopolymer	Anti-staining additive
	Poly Acrylic Acid
	MW 4,500
	End group sodium metabisulfite
	Standard pH: 6.5-7.5
Acrylic Polymer H	Acrylic homopolymer	Anti-staining additive
	Poly Methacrylic Acid
	MW 30,000
	End group sodium metabisulfite
	Standard pH: 9.0-11.0
Sodium hydroxide	NaOH	Increases the pH of the
		environment during cotton
		cationization
Soda ash/sodium carbonate	CaCO3	Increases the pH of the
		environment during dyeing
		and/or additive reaction with
		cationic cotton
Citric Acid	C6H8O7	Reduces the pH of the
		environment during cotton
		cationization
Acetic Acid	CH3COOH	Reduces the pH of the
		environment during cotton
		cationization
Water	H2O	Reaction medium (aqueous
		phase) for both cationization
		and cationic cotton modification
Acid Compound	Aqueous dissolution of organic	Reduces the pH of the
	acids	environment during cotton
		cationization
Dycs Vicunha	Reactive dyestuff for cellulosic	Dycstuff for coloration of the
	fibers with bireactive and	fabric
	trireactive chemistry
Softener	Emulsion of a functional	Fabric finishing agent
	polydimethysiloxanc

Examples to Understand Acrylic Polymers Efficacy and the Interaction Between the pHs—

In a set of experiments, fabric which has been cationized with 75 g/L of Cationic Reagent A in continuous (cold pad batch) application and then dyed using NOVACRON™ Yellow P-6GS dye at a concentration of 250 μL per 10 g swatch, is treated with different “stain resisting” materials. To achieve this, the dyed fabric is added to an aqueous bath in a bath ratio of 10 (water):1 (fabric) by weight. The pH of the bath is then adjusted with sodium carbonate to achieve more alkaline conditions or with citric acid to achieve more acidic conditions in order to bring the bath to the standard pH of the anti-staining additive to be used as necessary (the starting pH and concentration of acidic or alkaline material will determine the amount to be added). After the pH was adjusted (if necessary) to the desired pH, the reaction between the anti-stain additive and the cationized fabric is allowed to proceed for 10 minutes at 30° C. These fabrics are then placed in a bath containing an aqueous solution with NOVACRON™ Black C-NN dye in order to simulate a staining condition in a home washing activity. All the examples in Tables 1-10 use the same black dye at the same concentration (0.1% on weight of goods (OWG) in 200 g of water), same bath ratio (20:1 wt.) for the same amount of time (30 minutes per “wash”) at the same temperature (30° C.). Color analysis is then done on a quantitative basis for both the fabric and the bath. For the quantitative analysis a spectrophotometer is used to measure the L, a*, and b* parameters to measure the color intensity of the fabric (reflectance mode) and those parameters were used to calculate dE (delta E, ΔE) as known in the art.

TABLE 1
Additive A at 25 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer A

4.9

7.4

10

(25 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.8	−7.4	82.4	—	90.0	−6.8	80.9	—	89.8	−6.6	79.4	—
dye + treat + 1 wash	83.7	−9.3	66.0	18.0	86.2	−8.0	71.6	10.1	78.5	−11.5	61.5	21.7
dye + treat + 2 washes	75.8	−10.2	54.2	32.1	80.3	−9.2	62.8	20.7	67.8	−13.3	46.7	40.0

dye + treat + 3 washes

69.0

−10.9

43.9

44.4

74.6

−10.2

54.2

31.0

Stained after 2 washes

dye + treat + 4 washes	Stained after 3 washes	67.8	−11.7	45.1	42.4

Acrylic Polymer A has a 2,000 g/mol as molecular weight (MW). Table 1 presents the results for the application of Additive A at 25 g/L. As it can be observed, L parameter reduces and dE parameter increases with the increase in staining washes. This means that the cationic cotton with the anti staining additive become more stained with the increase of staining washes. This result was similar in all pH conditions (acid, neutral or alkaline) and in all staining washes, so it is understood that acrylic polymers with up to 2,000 g/mol as MW and applied at 25 g/L will not work in avoiding the stains.

TABLE 2
Additive A at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer A

4.9

7.7

9.5

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.9	−7.7	82.5	—	89.9	−6.9	81.2	—	89.7	−6.3	80.9	—
dye + treat + 1 wash	85.1	−9.5	69.3	14.5	87.5	−7.9	75.3	6.4	84.8	−8.5	73	9.6
dye + treat + 2 washes	79.4	−10.3	58.5	26.7	84.5	−8.8	69.9	12.7	77.2	−11.6	60.8	24.3
dye + treat + 3 washes	72.1	−10.9	48.1	39.3	75.4	−11.6	56.3	29.2	70.7	−12.6	51.8	35.3
dye + treat + 4 washes	66.9	−10.9	40.8	48.2	68.6	−12.2	47.3	40.4	65.1	−12.6	44.9	44.1

In order to evaluate if the low Acrylic Polymer A concentration was the cause for the results presented in Table 1, the study was replicate for the same additive, but with 100 g/L instead. The obtained results are presented in Table 2 and the conclusions are as similar to the previous example, with a small increase in the staining resistance at the initial staining washes. This corroborates to the conclusion that acrylic polymers with up to 2,000 g/mol as MW will not work in avoiding the stains, even in higher concentration applications, but this concentration will support a short lasting staining resistance with application at any proposed pHs

TABLE 3
Additive B at 100 g/L application in cationic cotton, with contamination wash at
different pH conditions

Adjusted pH

Acrylic Polymer B

5.1

7.7

9.5

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.8	−7.4	83.5	—	89.5	−6	82.8	—	89.3	−5.7	81.2	—
dye + treat + 1 wash	90.5	−8.1	77	6.5	87.3	−7.1	77.5	5.8	82.1	−8.8	68.9	14.6
dye + treat + 2 washes	90.8	−8.7	74.8	8.8	85.6	−7.7	74.1	9.7	79.2	−9.6	64.4	20.0
dye + treat + 3 washes	90.5	−8.9	73.1	10.5	81.7	−8.9	67.7	17.2	74.9	−10.9	57.6	28.1
dye + treat + 4 washes	89.8	−8.5	71.1	12.5	70.1	−12.5	51.1	37.7	70.7	−11.8	51.3	35.7

Acrylic Polymer B has a 4,500 g/mol as molecular weight (MW) and it is produced in an acid pH. Table 3 presents the results for the application of Acrylic Polymer B at 100 g/L. As it can be observed, L parameter generally reduces and dE parameter increases with the increase in staining washes. When we compare the L or dE parameters after several washes, with the data before contamination (“dye+treat”), there is a modification in those parameters for the cases where the additive was applied in neutral or alkaline pHs, which indicates that the fabric do not present a long lasting staining resistance at those application pHs. However, there was no significant modification in the L and dE parameters for the case when the Acrylic Polymer B was applied at an acidic pH, which is a similar pH for the pH of the production of Acrylic Polymer B. It is concluded that Acrylic Polymer B was effective in avoiding stains after several staining washes when the application was in acid pH, which is a similar pH of the production of Acrylic Polymer B. It is concluded that Acrylic Polymer B was effective in presenting a long lasting resistance to stains at 100 g/L in acid pH, which is a similar pH of the production of Acrylic Polymer B.

However, there was not significant modification in L and dE parameters for the initial staining washes when the application was at an acid pH (similar to the pH of the acrylic polymer) or neutral pH (different than the pH of the acrylic polymer). This indicates that for desired short lasting staining resistance, the application does not need to be in a pH too close to the acrylic polymer pH. For acid acrylic polymers, short lasting staining resistance present better results for acid or neutral application pH, but depending on the qualitative criteria, alkaline application pH can also be applied.

TABLE 4
Additive C at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer C

4.9

7.6

9.8

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.8	−7.3	83.2	—	90	−6.7	81	—	89.3	−5.5	80.4	—
dye + treat + 1 wash	89.6	−7.9	72.5	10.8	86.1	−8.2	72.1	9.8	78.9	−10.9	61.4	22.3
dye + treat + 2 washes	89.9	−7.8	69.9	13.3	82.2	−8.8	66.8	16.3	76.4	−10.6	58	26.3
dye + treat + 3 washes	90.1	−7.9	69.1	14.1	77.5	−10	59.3	25.3	72.7	−11.1	52.8	32.7
dye + treat + 4 washes	89.7	−8.2	67.9	15.4	72.4	−11.3	52.4	33.9	68.7	−11.5	47.6	39.2

Acrylic Polymer C has a 4.500 g/mol as molecular weight (MW) and it is produced in an acid pH.

Table 4 presents the results for the application of Acrylic Polymer C at 100 g/L. L parameter generally reduces and dE parameter increases with the increase in staining washes. When we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a modification in those parameters for the cases where the additive was applied in neutral or alkaline pHs, which indicates that the fabric do not present a long lasting staining resistance at those application pHs. However, there was no significant modification in the L and dE parameters for the case when the Acrylic Polymer C was applied at an acidic pH, which is a similar pH for the pH of the production of Acrylic Polymer C. The Acrylic Polymer C was effective in avoiding stains after several staining washes when the application was in acid pH, which is a similar pH of the production of Acrylic Polymer C. It is concluded that Acrylic Polymer C was effective in presenting a long lasting resistance to stains at 100 g/L in acid pH, which is a similar pH of the production of Acrylic Polymer C.

However, there was not significant modification in L and dE parameters for the initial staining washes, when the application was at an acid pH (similar to the pH of the acrylic polymer) or neutral pH (different than the pH of the acrylic polymer). This indicates that for desired short term staining resistance, the application does not need to be in a pH too close to the acrylic polymer pH. For acid acrylic polymers, short lasting staining resistance present better results for acid or neutral application pH, but depending on the qualitative criteria, alkaline application pH can also be applied.

TABLE 5
Additive D at 25 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer D

5.0

7.8

10

(25 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.8	−7.3	82.7	—	89.9	−6.7	81.5	—	89.3	−5.9	80.2	—
dye + treat + 1 wash	90.1	−7.5	76.8	5.9	87.3	−7.2	75	7.0	79.1	−11	63.8	20.0
dye + treat + 2 washes	89.4	−7.3	74.3	8.5	82.4	−8.5	67.2	16.2	69.9	−12.8	50.9	35.8

dye + treat + 3 washes	88.4	−7.4	72.1	10.9	76.1	−10.2	58.3	27.2	Stained after 2 washes
dye + treat + 4 washes	83.8	−8.6	65	19.1	69.3	−11.8	48.5	39.2

Acrylic Polymer D has a 3,600 g/mol as molecular weight (MW) and it is produced in an acid pH. Table 5 presents the results for the application of Acrylic Polymer D at 25 g/L. L parameter generally reduces and dE parameter increases with the increase in staining washes. When we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a modification in those parameters for the cases where the additive was applied in neutral or alkaline pHs, which indicates that the fabric do not present a long lasting staining resistance at those application pHs. However, there was no significant modification in the L and dE parameters for the case when the Acrylic Polymer D was applied at an acidic pH, which is a similar pH for the pH of the production of Acrylic Polymer D The Acrylic Polymer D was effective in avoiding stains after several staining washes when the application was at 25 g/L in acid pH, which is a similar pH of the production of Acrylic Polymer D. It is concluded that Acrylic Polymer D was effective in presenting a long lasting resistance to stains at 25 g/L in acid pH, which is a similar pH of the production of Acrylic Polymer D.

However, there was not significant modification in L and dE parameters for the initial staining washes, when the application was at an acid pH (similar to the pH of the acrylic polymer) or neutral pH (different than the pH of the acrylic polymer). This indicates that for desired short term staining resistance, the application does not need to be in a pH too close to the acrylic polymer pH, even when the application needs only 25 g/L of the additive. For acid acrylic polymers, short lasting staining resistance present better results for acid or neutral application pH, but depending on the qualitative criteria, alkaline application pH can also be applied.

TABLE 6
Additive D at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer D

5.1

7.4

9.5

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.7	−8.1	82.1	—	89.8	−6.5	81.7	—	89.3	−5.6	82.1	—
dye + treat + 1 wash	89.9	−8.9	73	9.2	86.7	−7.9	74.2	8.2	83.1	−9	70.4	13.7
dye + treat + 2 washes	90.3	−9.2	72.7	9.5	86.1	−8	72.3	10.2	81.1	−9.3	66.9	17.7
dye + treat + 3 washes	90.4	−9.2	71.3	10.9	83.4	−8.3	68.3	15.0	75.9	−10.7	59.5	26.8
dye + treat + 4 washes	90.1	−9.2	70.4	11.8	78.8	−9.6	61.7	23.0	70.8	−11.4	52	35.8

In order to evaluate if an increase in the content of the Acrylic Polymer D would change the results presented in Table 5, the study was replicate for the same additive, but with 100 g/L instead. The obtained results are presented in Table 6 and it can be concluded that, even after 4 contamination washes, the change in L and dE parameters were even lower than the previous case, for all pH conditions, with acidic pH being the best application pH. It can be concluded that a higher concentration of the additive, 100 g/L in this case, is a better application conditions, probably because there will be more polymer avoiding the contamination dye to be attached to the fabric.

Also, for short lasting resistance to stain, as data presented after one staining wash, the difference in L and dE parameters are not significant, when we compare different application pHs. So for short lasting staining resistance, the application pH does not need to be too close to the standard pH of the acrylic polymer, but higher differences in L and dE parameters, indicating a worse staining protection, occur when the application pH is more different than the acrylic polymer pH (alkaline application pH is worse than neutral or acidic application pHs).

TABLE 7
Additive E at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer E

5.0

7.6

10.2

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	91	−7.9	80.5	—	89.6	−7.3	81.4	—	87.7	−9.3	77	—
dye + treat + 1 wash	89.4	−8.1	74	6.7	88.5	−7.9	74.2	7.3	86.2	−9.3	71.5	5.7
dye + treat + 2 washes	86.4	−8.2	68.2	13.1	88.9	−7.4	72.4	9.0	86.2	−8.6	69.3	7.9
dye + treat + 3 washes	79.1	−10.1	56.1	27.2	89.1	−7.8	71.3	10.1	84.5	−8.7	66.4	11.1
dye + treat + 4 washes	69	−12.1	41.4	45.1	88.7	−7.8	70.3	11.1	81.2	−9.1	61.7	16.6

Acrylic Polymer E has a 3,500 g/mol as molecular weight (MW) and it is produced in a neutral pH. Table 7 presents the results for the application of Acrylic Polymer E at 100 g/L. As it can be observed, when we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a higher modification in those parameters for the cases where the additive was applied in acidic or alkaline pHs, which indicates that the fabric was stained after the four contamination washes. This indicates that for long lasting staining resistance, the application should be in a neutral pH, similar to the standard pH of the acrylic polymer E, because this application conditions present the lowest modification in L and dE parameters. It is concluded that Acrylic Polymer E was effective in presenting a long lasting or resistance to stains at 100 g/L in neutral pH, which is a similar pH of the production of Acrylic Polymer E.

However, for a short lasting resistance to stains, as noticed by comparing L and dE parameters before any staining wash with after one staining wash significant difference was noticed. It can be concluded that for demands with short lasting resistance to stains, the application pH being close to the standard pH of the acrylic polymer result in an application at any pH for a neutral acrylic polymer, because a close pH to a neutral pH are both acid or alkaline pHs. So, for a short lasting resistance, if the standard pH of the acrylic polymer is neutral, the application pH can be any.

TABLE 8
Additive F at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer F

5.1

7.7

9.4

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.5	−6.8	81.2	—	89.8	−6.2	81.3	—	89.4	−5.8	81.1	—
dye + treat + 1 wash	90.5	−8.1	77	4.4	87.3	−7.1	77.5	4.6	82.1	−8.8	68.9	14.5
dye + treat + 2 washes	90.8	−8.7	74.8	6.7	85.6	−7.7	74.1	8.5	79.2	−9.6	64.4	19.9
dye + treat + 3 washes	90.5	−8.9	73.1	8.4	81.7	−8.9	67.7	16.1	74.9	−10.9	57.6	28.1
dye + treat + 4 washes	89.8	−8.5	71.1	10.3	70.1	−12.5	51.1	36.6	70.7	−11.8	51.3	35.7

Acrylic Polymer F has a 2.150 g/mol as molecular weight (MW) and it is produced in an acid pH.

Table 8 presents the results for the application of Acrylic Polymer F at 100 g/L.L parameter generally reduces and dE parameter increases with the increase in staining washes. When we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a modification in those parameters for the cases where the additive was applied in neutral or alkaline pHs, which indicates that the fabric do not present a long lasting staining resistance at those application pHs. However, there was no significant modification in the L and dE parameters for the case when the Acrylic Polymer F was applied at an acidic pH, which is a similar pH for the pH of the production of Acrylic Polymer F. The Acrylic Polymer F was effective in avoiding stains after several staining washes when the application was in acid pH, which is a similar pH of the production of Acrylic Polymer F. It is concluded that Acrylic Polymer F was effective in presenting a long lasting resistance to stains at 100 g/L in acid pH, which is a similar pH of the production of Acrylic Polymer F.

However, there was not significant modification in L and dE parameters for the initial staining washes, when the application was at an acid pH (similar to the pH of the acrylic polymer) or neutral pH (different than the pH of the acrylic polymer). This indicates that for desired short term staining resistance, the application does not need to be in a pH too close to the acrylic polymer. For acid acrylic polymers, short lasting staining resistance present better results for acid or neutral application pH, but depending on the qualitative criteria, alkaline application pH can also be applied. pH.

TABLE 9
Additive G at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer G

5.1

7.5

10.1

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.9	−7.4	82.1	—	90	−6.4	82.1	—	89.7	−6.2	80.7	—
dye + treat + 1 wash	89.2	−7.5	77.6	4.8	89.1	−7	77.2	5.0	87.2	−6.9	76.5	4.9
dye + treat + 2 washes	87.5	−8.2	74.4	8.5	89.4	−7.7	75.8	6.5	84.1	−8.3	71.2	11.2
dye + treat + 3 washes	83.8	−8.3	67.9	15.9	89.4	−7.2	74.9	7.3	77.9	−9.9	61.6	22.8
dye + treat + 4 washes	77	−9.9	57.6	28.3	89.5	−7.2	74.8	7.4	72.3	−11.1	53.5	32.7

Acrylic Polymer G has a 4,500 g/mol as molecular weight (MW) and it is produced in an neutral pH. Table 9 presents the results for the application of Acrylic Polymer G at 100 g/L. As it can be observed, when we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a higher modification in those parameters for the cases where the additive was applied in acidic or alkaline pHs, which indicates that the fabric was stained after the four contamination washes. This indicates that for long lasting staining resistance, the application should be in a neutral pH, similar to the standard pH of the acrylic polymer G, because this application conditions present the lowest modification in L and dE parameters. It is concluded that Acrylic Polymer G was effective in presenting a long lasting or resistance to stains at 100 g/L in neutral pH, which is a similar pH of the production of Acrylic Polymer G.

However, for a short lasting resistance to stains, as notice by comparing L and dE parameters before any staining wash with after one staining wash significant difference was noticed. It can be concluded that for demands with short lasting resistance to stains, the application pH being close to the standard pH of the acrylic polymer result in an application at any pH for a neutral acrylic polymer, because a close pH to a neutral pH are both acid or alkaline pHs. So, for a short lasting resistance, if the standard pH of the acrylic polymer is neutral, the application pH can be any.

TABLE 10
Additive H at 100 g/L application in cationic cotton, with contamination
wash at different pH conditions

Adjusted pH

Acrylic Polymer H

5.1

7.4

10.0

(100 g/L)	L	a*	b*	dE	L	a*	b*	dE	L	a*	b*	dE
dye + treat	90.7	−7.1	82.9	—	89.9	−6.3	81.6	—	89.1	−6.7	79.9	−
dye + treat + 1 wash	77.9	−11.7	63.3	23.9	88.4	−7	79.7	2.5	88	−7.1	78.6	1.7
dye + treat + 2 washes	68.9	−13.2	50.1	39.9	86.5	−7.5	76.5	6.2	86.2	−7.5	75.3	5.5

dye + treat + 3 washes	Stained after 2 washes	80.4	−9.6	67.1	17.6	80.1	−9.7	65.8	17.0
dye + treat + 4 washes		71.4	−12.2	54	33.7	72.8	−11.5	55.3	29.9

Acrylic Polymer H has a 30,000 g/mol as molecular weight (MW) and it is produced in an alkaline pH. Table 10 presents the results for the application of Acrylic Polymer Hat 100 g/L. As it can be observed, when we compare the L and dE parameters after several washes, with the data before contamination (“dye+treat”), there is a higher modification in those parameters for the cases where the additive was applied in acidic pHs, which indicates that the fabric was stained after only two contamination washes. However, after four staining washes, there was also reduction in the L parameter and an increase in dE for the case when the Acrylic Polymer H was applied at a neutral or alkaline pH, even with the staining being better than the acidic situation. It is concluded that Acrylic Polymer H was not effective in a long lasting resistance to avoiding stains at 100 g/L in pH condition. It is understood that the result is not caused by the molecular weight, which is higher than the minimum concluded from Acrylic Polymer A and Acrylic Polymer F. Also, it can be observed that the best results for Acrylic Polymer H are obtained at pH conditions similar to its production pH (neutral-alkaline). The obtained result is associated to the fact the dye reacts with cotton by creating covalent bonds at alkaline conditions and, even with the additive creating a physical barrier to the contact cotton fabric and dye, it cannot avoid all potential interaction between those two species. In an alkaline condition, when both cotton and dye meet each other, covalent bonds are created, causing the observed stains for this additive, even in the application pH similar to the production pH of Acrylic Polymer H.

However, for a short term resistance to stains, as noticed by comparing L and dE parameters before any staining wash with after one staining wash significant difference was detected for application pH close to the production pH of acrylic polymer H. It can be concluded that for demands with short lasting resistance to stains, the application pH being close to the standard pH of the acrylic polymer result in an application at neutral or alkaline pHs for a alkaline acrylic polymers. So, for a short lasting resistance, if the standard pH of the acrylic polymer is alkaline, the application pH should be alkaline or neutral.

Conclusions

Examples show that acrylic polymers with at least 2,150 g/mol as MW can be effective in avoiding stains in cationic cotton, in home washes, for example. For short term resistance in avoiding stains, the application pH should be close, but not necessarily to the same as the standard pH of the acrylic polymer used as anti stain additive. So, if the standard pH of the acrylic polymer is acidic, it is preferred that the application is at acidic or neutral pH. If the standard pH of the acrylic polymer is alkaline, it is preferred that the application is at neutral or alkaline pH. And if the standard pH of the acrylic polymer is neutral, then the application pH can be any (acid, neutral or alkaline).

However, for long lasting resistance in avoiding stains, the application of the additive should be in an environment with a pH similar to the production of the additive, in order to avoid undesirable reactions between the environment medium and the additive. So, for the additive to be effective in long lasting avoiding stains, if it is produced in an acidic pH, then the application of the additive in the cationic cotton should be in acidic pH. If the additive is produced in a neutral pH, the application of the additive in the cationic cotton should be in a neutral pH. If the additive is produced in alkaline pH, the application should also be in alkaline pH. However, this last situation is the one where probably covalent bonds are created between cotton and dye. So, if the fabric is not neutralized after the additive application, the alkaline additive will not be as long lasting effective in avoiding stains.

It is understood that while the easiest acrylic polymers to use might be the ones with an alkaline standard pH, because this is the regular environment in textile mills, according to the results, alkaline conditions were not as effective in avoiding stains. Thus it may be preferred that acrylic polymers with standard neutral pH are the best ones to be used by textile mills because it will also provide good short term efficacy in avoiding stains at any application pH.

Examples to Prove Previous Conclusions, to Understand Interaction Between Acrylic Polymer And Common Used Softeners by Textile Industry, and to Understand if the pH of the Cotton to be Treated Has Influence on the Short Lasting Resistance to Stains:

In a set of experiments, fabric which has been cationized with 60 g/L or 75 g/L of Cationic Reagent A in continuous (cold pad batch) application and then dyed using reactive multifunctional dye at a concentration of 6 g/kg, is treated with different “stain resisting” materials. The dyeing was conducted by two different process: continuous dyeing followed by drying at 195° C. for 45 s; and exhaust dyeing for 5 min at room temperature followed by drying at 60° C. The antistaining additive used was Acrylic Polymer E at 30 g/L. There was also added or not, depending on the recipe, a silicon based softener at 2 g/L.

The pH of the fabric prior to the addition of the acrylic Polymer E was 9.28 (alkaline) and it was modified with acid to pHs 7 or 5, depending on the analysis, to check the interaction of the fabric pH and the acrylic polymer E efficacy in short lasting resistance to stain. The fabric pH modification was conducted by immersing the fabric in 7-9 ml/L of an aqueous solution of the organic acids compound to adjust the pH, measuring the extraction pH until this pH was 7 or 5.

The staining washes used reactive multifunctional dyes at 0.5% to 3.0% concentration and staining contamination simulated a home wash, being conducted for 30 min at 60° C.

The tables below present the obtained dE results for the studied cases in continuous dyeing:

TABLE 11
dE results for different fabric adjusted pHs. Fabric with 60 g/L
of cationic reagent A, continuous dyed and no finishing applied.

Continuous Dyeing

Fabric Adjusted pH

	No Finishing	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	3.87	3.54	3.01
	Sample 2	3.12	3.08	3.18
	Sample 3	2.22	2.01	2.68
	Sample 4	2.88	2.79	3.12
	Sample 5	3.93	3.24	3.60
	Sample 6	3.90	3.29	3.88
	Average	3.32	2.99	3.25
	Std Deviation Sample	0.70	0.54	0.43

Table 11 present the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, continuous dyed and no finishing applied after a single staining wash. No significant differences were noticed in terms of dE results for the fabric being treated with different pHs. So, it can be concluded that the fabric pH does not significantly interfere on the staining in a untreated fabric.

TABLE 12
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, continuous dyed and only
silicon based softener applied in finishing step

Continuous Dycing

Fabric Adjusted pH

	Softener only (pH 6.6)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.16	2.63	2.07
	Sample 2	2.76	2.58	2.45
	Average	2.46	2.61	2.26
	Std Deviation Sample	0.42	0.04	0.27
	Difference Avrg	−0.86	−0.39	−0.99
	% Difference Avrg	−26%	−13%	−30%

Table 12 present the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, continuous dyed and only silicon based softener applied at finishing step after a single staining wash. The finishing bath, with only the silicon based softener, has a standard pH as 6.6. No significant differences were noticed in terms of dE results for the fabric being treated with different pHs, but the staining is slightly better than untreated fabric presented at Table 11. It can be concluded that the used of silicon based softener has a few impact on a short lasting staining resistance, in comparison to a untreated fabric, but this impact is not significant in terms of avoiding stains.

TABLE 13
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, continuous dyed and both
silicon based softener and acrylic polymer E applied in
finishing step. The finishing bath (mixture between softener
and acrylic polymer E) with pH adjusted to 5.0

Continuous Dyeing

Fabric Adjusted pH

	Softener + AP E (pH 5.0)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.11	1.53	2.10
	Sample 2	1.37	1.63	1.65
	Sample 3	1.30	1.49	1.61
	Sample 4	1.72	1.71	1.70
	Sample 5	1.40	2.14	2.01
	Sample 6	1.65	2.27	2.05
	Average	1.59	1.80	1.85
	Std Deviation Sample	0.30	0.33	0.22
	Difference Avrg	−1.73	−1.20	−1.39
	% Difference Avrg	−52%	−40%	−43%

Table 13 present the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, continuous dyed and with both silicon based softener and acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (mixture between softener and acrylic polymer) had its pH adjusted to 5.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 11) and also lower than when only silicon based softener is added to the fabric (Table 12). Those results in Table 13 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, in comparison to the silicon based softener, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

TABLE 14
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, continuous dyed and both
silicon based softener and acrylic polymer E applied in
finishing step. The finishing bath (mixture between softener
and acrylic polymer E) with pH adjusted to 7.0

Continuous Dyeing

Fabric Adjusted pH

	Softener + AP E (pH 7.0)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.26	1.58	1.51
	Sample 2	1.45	1.59	1.25
	Sample 3	1.27	1.47	1.40
	Sample 4	1.52	1.73	1.54
	Sample 5	2.06	1.96	2.06
	Sample 6	1.96	2.11	1.78
	Average	1.75	1.74	1.59
	Std Deviation Sample	0.39	0.25	0.29
	Difference Avrg	−1.57	−1.25	−1.66
	% Difference Avrg	−47%	−42%	−51%

Table 14 present the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, continuous dyed and with both silicon based softener and acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (mixture between softener and acrylic polymer) had its pH adjusted to 7.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 11) and also lower than when only silicon based softener is added to the fabric (Table 12). Those results are similar to what is presented at Table 13. Table 14 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, in comparison to the silicon based softener, and that the pH does not interfere in the short lasting resistance to stain, according to what are presented at Table 7 and Table 13.

TABLE 15
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, continuous dyed and both
silicon based softener and acrylic polymer E applied in
finishing step. The finishing bath (mixture between softener
and acrylic polymer E) with pH adjusted to 8.5

Continuous Dyeing

Fabric Adjusted pH

	Softener + AP E (pH 8.5)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	1.39	1.81	2.02
	Sample 2	1.69	1.73	1.81
	Sample 3	1.56	1.28	1.50
	Sample 4	1.62	1.27	1.23
	Sample 5	1.71	1.35	1.11
	Sample 6	1.88	1.74	1.53
	Sample 7	2.06	2.02	2.21
	Sample 8	1.78	2.38	1.95
	Average	1.71	1.70	1.67
	Std Deviation Sample	0.20	0.39	0.39
	Difference Avrg	−1.61	−1.29	−1.57
	% Difference Avrg	−48%	−43%	−49%

Table 15 presents the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, continuous dyed and with both silicon based softener and acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (mixture between softener and acrylic polymer) had its pH adjusted to 8.5. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 11) and also lower than when only silicon based softener is added to the fabric (Table 12). Those results are similar to what are presented at Table 13 and Table 14. Table 15 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, in comparison to the silicon based softener, and that the pH does not interfere in the short lasting resistance to stain, according to what are presented at Table 7, Table 13 and Table 14.

Table 11 to Table 15 show that dyed cationic fabric tends to stain. Even the addition of a silicon based softener at the finishing step providing a small reduction in dE, in comparison to a unfinished fabric, the softener itself does not avoid stains. The short lasting stain resistance is provided by the use of an acrylic polymer which, in that case, is acrylic polymer E. As shown in Table 7, the short lasting stain resistance does not depend on the pH of the application or even the fabric.

The tables below present the obtained dE results for the studied cases in a 60 g/L cationic fabric exhaust dyed:

TABLE 16
dE results for different fabric adjusted pHs. Fabric with 60 g/L
of cationic reagent A, exhausted dyed and no finishing applied.

Exhaust Dyeing

Fabric Adjusted pH

	No Finishing	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.02	1.76	1.82
	Sample 2	3.07	4.57	2.28
	Average	2.55	3.17	2.05
	Std Deviation Sample	0.74	1.99	0.33

Table 16 presents the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, exhausted dyed and no finishing applied after a single staining wash. No significant differences were noticed in terms of dE results for the fabric being treated with different pHs. So, it can be concluded that the fabric pH does not significantly interfere on the staining in an untreated fabric.

TABLE 17
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 5.0

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 5.0)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.07	1.36	1.92
	Sample 2	1.94	4.41	2.68
	Average	2.01	2.89	2.30
	Std Deviation Sample	0.09	2.16	0.54
	Difference Avrg	−0.54	−0.28	0.25
	% Difference Avrg	−21%	−9%	12%

Table 17 presents the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 5.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 16). Those results in Table 17 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

TABLE 18
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 7.0

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 7.0)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	1.64	1.71	1.90
	Sample 2	1.69	1.99	2.12
	Average	1.67	1.85	2.01
	Std Deviation Sample	0.04	0.20	0.16
	Difference Avrg	−0.88	−1.32	−0.04
	% Difference Avrg	−35%	−42%	−2%

Table 18 presents the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 7.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 16). Those results in Table 18 show that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

TABLE 19
dE results for different fabric adjusted pHs. Fabric with
60 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 8.5

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 8.5)	5.00	7.00	9.28
	cationic 60 g/L	dE	dE	dE

	Sample 1	2.09	1.35	1.52
	Sample 2	2.14	0.59	1.75
	Average	2.12	0.97	1.64
	Std Deviation Sample	0.04	0.54	0.16
	Difference Avrg	−0.43	−2.20	−0.42
	% Difference Avrg	−17%	−69%	−20%

Table 19 presents the results for dE parameters for a fabric treated with 60 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 8.5. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 16). Those results in Table 19 show that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

Table 16 to Table 19 show that dyed cationic fabric tends to stain. The short lasting stain resistance is provided by the use of an acrylic polymer which, in that case, is acrylic polymer E. As shown in Table 7, the short lasting stain resistance does not depend on the pH of the application or even the fabric, even with slightly better results being obtained at neutral pHs.

The tables below present the obtained dE results for the studied cases in a 75 g/L cationic fabric exhaust dyed:

TABLE 20
dE results for different fabric adjusted pHs. Fabric with 75 g/L
of cationic reagent A, exhausted dyed with no finishing step

Exhaust Dyeing

Fabric Adjusted pH

	No Finishing	5.00	7.00	9.28
	cationic 75 g/L	dE	dE	dE

	Sample 1	1.94	1.82	1.98
	Sample 2	1.83	1.72	1.73
	Average	1.89	1.77	1.86
	Std Deviation Sample	0.08	0.07	0.18

Table 20 presents the results for dE parameters for a fabric treated with 75 g/L of cationic reagent A, exhausted dyed and no finishing applied after a single staining wash. No significant differences were noticed in terms of dE results for the fabric being treated with different pHs. So, it can be concluded that the fabric pH does not significantly interfere on the staining in an untreated fabric.

TABLE 21
dE results for different fabric adjusted pHs. Fabric with
75 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 5.0

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 5.0)	5.00	7.00	9.28
	cationic 75 g/L	dE	dE	dE

	Sample 1	1.75	1.55	1.97
	Sample 2	1.33	1.78	2.17
	Average	1.54	1.67	2.07
	Std Deviation Sample	0.30	0.16	0.14
	Difference Avrg	−0.35	−0.11	0.22
	% Difference Avrg	−18%	−6%	12%

Table 21 presents the results for dE parameters for a fabric treated with 75 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 5.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 20). Those results in Table 21 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

TABLE 22
dE results for different fabric adjusted pHs. Fabric with
75 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 7.0

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 7.0)	5.00	7.00	9.28
	cationic 75 g/L	dE	dE	dE

	Sample 1	1.52	1.52	1.82
	Sample 2	1.52	1.58	1.48
	Average	1.52	1.55	1.65
	Std Deviation Sample	0.00	0.04	0.24
	Difference Avrg	−0.37	−0.22	−0.21
	% Difference Avrg	−19%	−12%	−11%

Table 22 presents the results for dE parameters for a fabric treated with 75 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 7.0. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 20). Those results in Table 22 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

TABLE 23
dE results for different fabric adjusted pHs. Fabric with
75 g/L of cationic reagent A, exhausted dyed and only acrylic
polymer E applied in finishing step. The finishing bath
(with only acrylic polymer E) with pH adjusted to 8.5

Exhaust Dyeing

Fabric Adjusted pH

	AP E (pH 8.5)	5.00	7.00	9.28
	cationic 75 g/L	dE	dE	dE

	Sample 1	1.45	1.36	1.22
	Sample 2	1.67	1.24	1.84
	Average	1.56	1.30	1.53
	Std Deviation Sample	0.16	0.08	0.44
	Difference Avrg	−0.33	−0.47	−0.33
	% Difference Avrg	−17%	−27%	−18%

Table 23 presents the results for dE parameters for a fabric treated with 75 g/L of cationic reagent A, exhausted dyed and with only acrylic polymer E applied at finishing step after a single staining wash. The finishing bath (with only acrylic polymer E) had its pH adjusted to 8.5. The addition of acrylic polymer E at the finishing bath makes the dE results being lower than when no additive is added to the fabric (Table 20). Those results in

Table 23 shows that acrylic polymer E by itself is an additive necessary to the short lasting staining resistance of the fabric, and that the pH does not interfere in the short lasting resistance to stain, according to what is presented at Table 7.

Table 20 to

Table 23 show that dyed cationic fabric tends to stain. The short lasting stain resistance is provided by the use of an acrylic polymer which, in that case, is acrylic polymer E. As shown in Table 7, the short lasting stain resistance does not depend on the pH of the application or even the fabric.

Also, a comparison between Table 16 to Table 19 with Table 20 to

Table 23 suggests that more concentrated cationic cotton (60 vs. 75 g/L) will demand higher acrylic polymer concentrations to obtain similar protection against staining, because results from Table 20 to

Table 23 were lower than the results Table 16 to Table 19, while both studies used the same acrylic polymer E concentration (30 g/L).