34715 ⎘
Additional information regarding catalytic systems classified in; Complexes comprising metals of Group VIII as the central metal; Metals of the platinum group Rhodium
TRI-(ADAMANTYL)PHOSPHINES AND APPLICATIONS THEREOF
#2PROCESS FOR PREPARING, BY HYDROFORMYLATION, SHORT-CHAIN OLEFINS IN THE GAS PHASE
#3METHODS FOR PREPARING (2S,3R,4R)-4,5-DIHYDROXYISOLEUCINE DERIVATIVE AND INTERMEDIATES THEREOF
#4A NEW ROUTE FOR SYNTHESIZING AXIALLY CHIRAL CANNABINOIDS FROM COUMARINS
#5EGGSHELL TYPE CATALYST, AND PREPARATION METHOD AND APPLICATION THEREOF IN PROPYLENE HYDROFORMYLATION REACTION
#6CATALYTIC METHODS FOR CARBONYLATION OF ESTERS
#7CHIRAL SPIROCYCLIC COMPOUNDS AND METHODS OF PREPARATION AND USE THEREOF
#8SITE-SPECIFIC ISOTOPIC LABELING OF 1,4-DIENE SYSTEMS
#9SYNTHESIS OF (S)-6-HYDROXYTRYPTOPHAN AND DERIVATIVES THEREOF
#10PROCESS FOR PREPARING GAMMA,DELTA-UNSATURATED ALDEHYDES DERIVATIVES
#11COMPOUNDS, TRANSITION METAL COMPLEX HYDROFORMYLATION CATALYST PRECUROR COMPOSITIONS COMPRISING SUCH COMPOUNDS, AND HYDROFORMYLATION PROCESSES
#12PREPARATION OF ORGANOSILICON COMPOUNDS WITH CARBINOL FUNCTIONALITY
#13MICROPOROUS CATALYSTS FOR DIRECT SYNTHESIS OF BRANCHED ENALS WITH HIGH SELECTIVITY
#14SUPPORTED HYDROFORMYLATION CATALYST AND PREPARATION METHOD THEREOF, AND METHOD FOR SYNTHESIZING 4-ACETYLOXY-2-METHYL-2-BUTENAL
#15METHODS AND SYSTEMS FOR MODIFYING SELECTIVITY IN CATALYTIC REACTIONS
#16Branched Products
#17PROCESSES FOR THE PREPARATION OF PHENYLTETRAHYDROFURAN COMPOUNDS
#18METHOD FOR PRODUCING ALCOHOL
#19PROCESS FOR HYDROFORMYLATION OF DIISOBUTENE AND A C4 TO C7 OLEFIN
#20HYDROFORMYLATION PROCESS FOR PREPARING LINEAR AND BRANCHED ALDEHYDES
#21PROCESS FOR THE HYDROFORMYLATION OF DIISOBUTENE WITH PRECEDING DISTILLATION
#22PROCESS FOR PRODUCTION OF KETOCARBOXYLIC ACID VINYL ESTERS
#23METHOD FOR PREPARING TERT-BUTYL (S)-4-(1-(2,3-DIMETHYLPHENYL)ETHYL)-1H-IMIDAZOLE-1-CARBOXYLATE AND SALTS THEREOF AND ITS USE IN A METHOD FOR PREPARING (S)-4-(1-(2,3-DIMETHYLPHENYL)ETHYL)-1H-IMIDAZOLE AND SALTS THEREOF
#24HETEROBIDENTATE IMIDAZO[1,5-A]PYRIDINE AND IMIDAZO[1,5-A]QUINOLINE N-HETEROCYCLIC CARBENE (NHC) LIGANDS, CATALYST COMPLEXES THEREOF, AND METHODS USING SAME
#25CYCLIC SUPPORTED CATALYSTS
#26PROCESS FOR THE PREPARATION OF OPTICALLY PURE ENANTIOMERS OF CYCLIC IMINIUM SALTS AND THEIR USE AS CATALYSTS
#27Branched Alcohols
#28METHOD FOR PRODUCING ALDEHYDE, METHOD FOR PRODUCING ALCOHOL, AND CATALYST COMPOSITION
#29Branched Products
#30Mixture of two constitutionally isomeric bisphosphites
#31Diphosphites with substituents in the trans position
#32Diphosphites with a dicyclohexylphosphino radical
#33PROCESS FOR HYDROFORMYLATION WITH REMOVAL OF DISSOLVED HYDROGEN
#34PROCESS FOR THE PREPARATION OF POLYCYCLIC ALIPHATIC DIALDEHYDES
#35Branching Technology
#36Site-specific isotopic labeling of 1,4-diene systems
#37TRI-(ADAMANTYL)PHOSPHINES AND APPLICATIONS THEREOF
#38PROCESS FOR THE HYDROFORMYLATION OF OLEFINS IN HOMOGENEOUS PHASE
#39PROCESS FOR PREPARING 3-(CYCLOHEX-1-EN-1-YL)PROPANAL DERIVATIVES
#40Alcohols Production
#41PHOSPHOLANE-PHOSPHITE LIGANDS FOR ALKENE HYDROFORMYLATION CATALYSTS
#42CATALYST, REDOX-SWITCHABLE CATALYST SYSTEM, AND RELATED METHODS INVOLVING HYDROSILYLATION
#43Production of bio-based liquefied petroleum gas
#44Branched Compounds
#45METHODS OF ARENE ALKENYLATION
#46Branched Alcohols
#47Catalysts and methods for forming alkenyl substituted arenes
#48Alcohols Production
#49Tri-(adamantyl)phosphines and applications thereof
#50TRANSITION METAL COMPLEXES COMPRISING CARBENE LIGANDS SERVING AS EMITTERS FOR ORGANIC LIGHT-EMITTING DIODES (OLED'S)
#51METHOD OF PRODUCING HYDROGEN
#52LIGANDS FOR TRANSITION METAL CATALYSTS
#53Alcohols Production
#54Diphosphites having an open and a closed 2,4-methylated outer unit
#55Mixture of bisphosphites having an open and a closed outer unit and the use thereof as a catalyst mixture in hydroformylation
#56Methylcyclohexane as allyl alcohol hydroformylation solvent
#57CONTINUOUS PREPARATION METHOD FOR PENEM INTERMEDIATE MAP
#58Alcohols Production
#59Hydroformylation method
#60Processes for recovery of rhodium from a hydroformylation process
#61Use of an epoxide in order to reduce the formation of heavy ends in a hydroformylation process
#62Method for reducing heavy end formation and catalyst loss in a hydroformylation process
#63Branched products
#64Branched products
#65Process for hydroformylation of olefins to aldehydes
#66PROCESS TO PREPARE SOLUTION FROM HYDROFORMYLATION PROCESS FOR PRECIOUS METAL RECOVERY
#67Cyclic supported catalysts
#68Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol
#69Diphosphites having an open, 2,4-methylated outer unit
#70HYDROFORMYLATION CATALYST, PREPARATION METHOD THEREFOR AND USE THEREOF
#71Diphosphites based on cis-butene-1,4-diol
#726,6'-([1,1'-BIPHENYL]-2,3'-DIYLBIS(OXY))DIDIBENZO[D,F][1,3,2]DIOXAPHOSPHEPINES
#73Highly efficient process for the preparation of sitagliptin via rhodium catalyzed asymmetric hydrogenation
#74Process for preparing aldehydes and separation of the catalyst system by membrane separation
#75ORGANOMETALLIC COMPLEX CATALYST
#76Synthesis of (S)-6-Hydroxytryptophan and Derivatives Thereof
#77Branched alcohols
#78ORGANOMETALLIC COMPLEX CATALYST
#79Site-specific isotopic labeling of 1,4-diene systems
#80Composition comprising branched aldehydes
#81Alcohols production
#82Reactor for carrying out a gas-liquid two-phase high-pressure reaction with a foaming medium
#83Method for carrying out a gas/fluid two-phase high-pressure reaction
#84Process for hydroformylation of short-chain olefins in the gas phase
#85Method for producing acetic acid
#86Methods to rejuvenate a deactivated hydroformylation catalyst solution
#87Catalysts and methods for forming alkenyl and alkyl substituted arenes
#88Reactor for carrying out a reaction between two non-miscible fluids of different densities
#89Biphenyl tetradentate phosphite compound: preparation method and application thereof
#90Process for synthesizing fluorinated cyclic aliphatic compounds
#91Continuous preparation of an optically active carbonyl compound by asymmetric hydrogenation
#92Method of preparing metal complexes of formula Z-M, in particular carbene-metal complexes
#93Hydroformylation process
#94Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts
#95Tri-(adamantyl)phosphines and applications thereof
#96Composition including hydroformylation catalyst
#97Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes
#98Catalyst compositions and hydroformylation processes
#99Enantiopure terphenyls with two ortho-atropisomeric axes
#100METHODS OF CONTROLLING SURFACE TENSION
#101Hydroformylation system with vent reactor recycle to primary reactor
#102Catalyst composition for hydroformylation and method of preparing aldehyde using the same
#103Normal alpha olefin synthesis using dehydroformylation or dehydroxymethylation
#104Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
#105Hydroformylation process
#106Production of bio-based liquefied petroleum gas
#107Supported Metal Catalysts
#108Organometallic complex catalyst
#109Process for hydrocyanation of terminal alkynes
#110Dihydroxybiphenyl compound, bisphosphite compound, catalyst, production method of aldehydes, and production method of alcohol
#111Hydroformylation process for producing 1,6-hexanediol derivatives
#112Integrated methods for chemical synthesis
#113Catalysts for the transformation of carbon dioxide and glycerol to formic acid and lactic acid and methods of making the same
#114Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using a rhodium catalyst
#115METHOD FOR PREPARING ARYLALKOXYSILANES BY DEHYDROGENATIVE SILYLATION
#116HETEROGENEOUS CATALYSTS AND USES THEREOF
#117Site-specific isotopic labeling of 1,4-diene systems
#118Process for hydroformylating short-chain olefins using a heterogenized catalyst system without ionic liquid
#119Methods of treating a hydroformylation catalyst solution
#120Methods to rejuvenate a deactivated hydroformylation catalyst solution
#121Hydroformylation method and catalyst using rhodium-ruthenium dual metal and tetradentate phosphine ligand
#122Organometallic complex catalyst
#123Catalysts for chemical reactions in a water-surfactant mixture
#124Process for the preparation of hyperpolarized carboxylate compounds
#125BIMETALLIC CATALYTIC COMPOUNDS AND COMPOSITIONS COMPRISING PERMETHYLPENTALENE LIGANDS
#126Producing BDO via hydroformylation of allyl alcohol made from glycerin
#127Normal alpha olefin synthesis using dehydroformylation or dehydroxymethylation
#128Polymer-supported transition catalyst
#129Oxidative dehydroxymethylation of alcohols to produce olefins
#130Rhenium catalysts for glycerin to allyl alcohol conversion
#131Catalytic carbonylation catalysts and methods
#132Method for obtaining alcohols from aldehydes
#133Method for obtaining alcohols from aldehydes III
#134Method for obtaining alcohols from aldehydes II
#135Highly isoselective catalyst for alkene hydroformylation
#136Tetradentate ligand, and production method therefor, synthetic intermediate thereof, and transition metal complex thereof
#137Catalyst composition for hydroformylation and hydroformylation method using the same
#138Processes Using Multifunctional Catalysts
#139Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#140HETERGENOUS CATALYSIS FOR THE ACETIC ACID PRODUCTION BY METHANOL CARBONYLATION
#141METHOD FOR CATALYTIC PREPARATION OF HYDROMORPHONE, HYDROCODONE, AND OTHER OPIATES
#142Phosphine substituted ferrocenyl complex
#143Method of producing dialdehyde compound
#144PROCESS FOR THE PREPARATION OF CHIRAL 3-AMINO-PIPERIDINS, USEFUL INTERMEDIATES FOR THE PREPARATION OF TOFACITINIB
#145Metal complexes
#146Economical production of 2-propylheptanol
#147Process for producing aldehydes
#148Tri-(adamantyl)phosphines and applications thereof
#149Hydroformylation process for producing 1,6-disubstituted hexane derivatives
#150Method for hydroformylating cyclooctadiene using 4-([1,1′:3′,1″-terphenyl]-2′-yloxy)-S-dinaphtho[2,1-D:1′,2′-F][1,3,2]dioxaphosphepine
#151PROCESS FOR HYDROFORMYLATION OF PENTENOIC ESTERS
#152Method for hydroformylating cyclooctadiene using 2-(anthracen-9-yloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
#153Hydroformylation catalyst, composition including hydroformylation catalyst, and method of preparing aldehyde using hydroformylation catalyst
#154Catalyst composition containing phosphorous-based ligand and method for hydroformylation using same
#155Bisphosphites having 2,4-tert-butylphenyl units and use thereof as ligands in hydroformylation
#156Functionalized magnetic nanoparticle, a catalyst, a method for forming C—C bonds
#157Supported Metal Catalysts
#158PROCESS FOR PRODUCING HETEROCYCLIC COMPOUND
#159Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#160Catalysts and methods for forming alkenyl and alkyl substituted arenes
#161Method for catalytic preparation of hydromorphone, hydrocodone, and other opiates
#162Rh-CNheterogeneous catalyst for preparing acetic acid by carbonylation reaction
#163Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
#164Hydroformylation process
#165Rh/WxC heterogeneous catalyst for preparing acetic acid by carbonylation reaction
#166Allyl alcohol hydroformylation process
#167Bisphosphites having an unsymmetric outer biphenol unit
#168Hydrosilylation reaction catalyst
#169Stabilized organophosphorous compounds
#170Catalyst composition comprising phosphorus-based ligand and hydroformylation process using the same
#171Bidentate diphosphoramidites with a homopiperazine group as ligands for hydroformylation
#172Chiral ligand-based metal-organic frameworks for broad-scope asymmetric catalysis
#173BISPHOSPHITES HAVING 2,4-DIMETHYLPHENYL UNITS AND USE THEREOF AS LIGANDS IN HYDROFORMYLATION
#174Olefin hydroformylation methods for obtaining branched aldehydes
#175Integrated methods for chemical synthesis
#176Process for producing heterocyclic compound
#177Catalytic carbonylation catalysts and methods
#178N-substituted pyridiniophosphines, processes for their preparation and their use
#179BIS(PHOSPHINE)-CARBODICARBENE CATALYST COMPLEXES AND METHODS OF USING THE SAME
#180PHOSPHORAMIDITE DERIVATIVES IN THE HYDROFORMYLATION OF OLEFIN-CONTAINING MIXTURES
#181Direct stereospecific synthesis of unprotected aziridines from olefins
#182Monophosphite compounds having an ether group
#183Method for olefin hydroformylation reaction using solid heterogeneous catalyst
#184Solid heterogeneous catalyst for olefin hydroformylation reaction and production method and use thereof
#185Two-stage hydroformylation process with circulating gas and SILP technology
#186Process for the preparation of hyperpolarized carboxylate compounds
#187Hydroformylation process
#188Hydroformylation process
#189Catalyst used for dehydrogenation of formic acid, method for dehydrogenating formic acid, and method for producing hydrogen
#190SILP CATALYST FOR HYDROFORMYLATION OF OLEFINS WITH SYNTHESIS GAS
#191Supported composition and the use thereof in methods for the hydroformylation of unsaturated compounds
#192Bisphosphites having a central 2,3′-biphenol unit
#193CATALYST SYSTEMS FOR USE IN CONTINUOUS FLOW REACTORS AND METHODS OF MANUFACTURE AND USE THEREOF
#194Preparation of saturated ketone morphinan compounds by catalytic isomerisation
#195PHOSPHORAMIDITE DERIVATIVES IN THE HYDROFORMYLATION OF UNSATURATED COMPOUNDS
#196Bisphosphites having an unsymmetric outer biphenol unit
#197MONOPHOSPHITES COMPRISING A BENZOPINACOL
#198MONOPHOSPHITES COMPRISING AN ANTHROL
#199PHOSPHORAMIDITE DERIVATIVES IN THE HYDROFORMYLATION OF UNSATURATED COMPOUNDS
#200PROCESS FOR PREPARING BICYCLIC AMINE DERIVATIVES
#201Phosphine triply cross-linked by organic polymer, transition metal complex using said phosphine as a ligand, and catalyst
#202Hydrogenation and disproportionation catalysis
#203Ligand, metal complex containing ligand, and reaction using metal complex containing ligand
#204Cayalyst system
#205IMMOBILIZED CATALYTICALLY ACTIVE COMPOSITION FOR HYDROFORMYLATION OF OLEFIN-CONTAINING MIXTURES
#206Methods of using homogenous rhodium catalysts with N-heterocyclic carbene ligands for the hydroformylation of olefins and substituted olefins
#207Method for producing novel organometallic complex and amine compound
#208P-chirogenic organophosphorus compounds
#209Metallorganocatalysis for asymmetric transformations
#210Optimized separation technique for work-up of homogeneously catalysed hydroformylation mixtures
#211Hetereocyclic agent as catalytic stabilizing agent in a hydroformylation process
#212Process for catalytic preparation of aldehydes from olefins using monophosphite mixtures
#213Bidentate ligands for hydroformylation of ethylene
#214Hydroformylation process
#215Preparation method of aldehyde compound using a metal compound and a phosphorus compound
#216Unsymmetric bisphosphite
#217Mixture of bisphosphites and use thereof as a catalyst mixture in hydroformylation
#218Mixtures of constitutionally isomeric bisphosphites
#219Mixture of different asymmetrical bisophosphites and use thereof as a catalyst mixture in hydroformylation
#220Process For The Preparation Of Pyrido[2,1-a] Isoquinoline Derivatives By Catalytic Asymmetric Hydrogenation Of An Enamine
#221Metal complex and method for producing hydrogen peroxide
#222Stable long-term method for producing C5-aldehydes
#223Catalyst preparation process
#224Carbonylation catalyst and process using same
#225Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#226Catalyst compositions and their use for hydrogenation of nitrile rubber
#227Dehydrogenation catalyst for formic acid, method for producing hydrogen, and method for producing heavy-hydrogen gas or heavy-hydrogenated hydrogen
#228Hydrogenation of biomass-derived substrates
#229Rhodium catalyst and method for producing amine compound
#230Compositions for carboxylic acid production and methods for making and using same
#231Paracyclophane-based ligands, their preparation and use in catalysis
#232Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#233Bimetallic catalysts for COhydrogenation and Hgeneration from formic acid and/or salts thereof
#234Catalytic carbonylation catalysts and methods
#235Production method for 2-alkenylamine compound
#236Dirhodium catalyst compositions and synthetic processes related thereto
#237Apparatus for producing alcohols from olefins
#238Methods to store transition metal organophosphorous ligand based catalysts
#239Process for the preparation of urethanes
#240Use of supported ionic liquid phase (SILP) catalyst systems in the hydroformylation of olefin-containing mixtures to aldehyde mixtures with a high content of aldehydes unbranched in the 2 position
#241Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#242Heterogeneous rhodium metal catalysts
#243ORGANIC/INORGANIC HYBRID CATALYTIC MATERIALS, THEIR PREPARATION, USE IN SELECTIVE PROCESSES AND REACTORS CONTAINING THEM
#244Homogeneous process for the hydrogenation of carboxylic acids and derivatives thereof
#245Dehydrogenation of ammonia-borane by bifunctional catalysts
#246Hydroamination of Alkenes
#247Polymer support
#248Catalyst carrier, catalyst thereon and C-C coupling method use the same
#249Catalyst for asymmetric hydrogenation and method for manufacturing optically active carbonyl compound using the same
#250Process for recovering homogeneous metal hydride catalysts
#251Catalyst support material comprising polyazole salt, electrochemical catalyst, and the preparation of a gas diffusion electrode and a membrane-electrode assembly therefrom
#252Sulphonylated diphenylethylenediamines, method for their preparation and use in transfer hydrogenation catalysis
#253Catalyst composition for hydroformylation reaction and hydroformylation process using the same
#254Method for enriching a homogeneous catalyst from a process flow
#255Method for preparing a metal catalyst
#256Method for separation and partial return of rhodium and catalytically effective complex compounds thereof from process streams
#257Conductive organometallic framework
#258Process for the Preparation of Pyrido [2,1-a] Isoquinoline Derivatives by Catalytic Asymmetric Hydrogenation of an Enamine
#259Multireaction bifunctional polymeric catalyst
#260Apparatus for producing alcohols from olefins
#261Preparation of acetic acid and acetic anhydride
#262Electronically tuned ligands for asymmetric hydrogenation
#263Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same
#264Polymer-supported transition metal catalyst complexes and methods of use
#265Catalyst composition for hydroformylation and method for producing aldehyde using the same
#266METAL-CONTAINING ORGANOSILICA CATALYST; PROCESS OF PREPARATION AND USE THEREOF
#267TRAPPING, RECYCLING, AND OTHER TECHNIQUES INVOLVING CATALYSTS
#268Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same
#269Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers
#270Process for preparing Caldehyde mixtures with a high n-pentanal content
#271CATALYST FOR OXYGEN REDUCTION ELECTRODE AND OXYGEN REDUCTION ELECTRODE
#272Bidentate chiral ligands for use in catalytic asymmetric addition reactions
#273Chiral acyclic diaminocarbene ligands, precursors therefore and their use in organic synthesis reactions
#274Bidentate secondary phosphine oxide chiral ligands for use in asymmetric addition reactions
#275Method for the production of hydrogen from ammonia borane
#276Sulfonated organophosphine compounds and use thereof in hydroformylation processes
#277Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
#278Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
#279Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
#280PROCESS FOR THE PREPARATION OF (R)-2-PHENYL PROPIONIC ACID DERIVATIVES
#281Paracyclophane-based ligands, their preparation and use in catalysis
#282Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
#283Bent allenes, and their metal complexes
#284MULTIPLE-METAL COMPLEX-CONTAINING COMPOUND AND METAL COMPLEX, AND MANUFACTURE METHODS THEREFOR, AND EXHAUST GAS PURIFICATION CATALYST MANUFACTURE METHOD USING THE SAME
#285Coordination complex system comprising tautomeric ligands
#286CATALYST INK COMPRISING AN IONIC LIQUID AND ITS USE IN THE PRODUCTION OF ELECTRODES, CCMS, GDES AND MEAS
#287Phosphorus-containing catalyst composition and hydroformylation process using the same
#288Catalyst for asymmetric hydrogenation
#289Methods of preparing secondary carbinamine compounds with boronic acids
#290Metal entrapped compounds
#291Hydroformylation process
#292Alcohol Dehydration
#293Adsorption and release of nitric oxide in metal organic frameworks
#2942, 2′-bis (dialkylphosphino) biphenyl compound, production method thereof, and metal complex comprising the compound as ligand
#295Metal nanoparticle-based catalytic composition that contains a nitrogen-containing ligand in an ionic liquid, process for preparation, process for hydrogenation of an olefinic feedstock
#296Chiral phosphorous compounds
#297Catalytic conversion of amide compounds to methyl ether polymers and methyl ether ladder polymers
#298Bis(ferrocenylphosphino) ferrocene ligands used in asymmetric hydrogenation reactions
#299Amidine-carboxylic acid complex, briged polynuclear complex derived therefrom, production methods therefor, and use for preparing supported metal or metal oxide clusters
#300Multiple-metal complex-containing compound and metal complex, and manufacture methods therefor, and exhaust gas purification catalyst manufacture method using the same