DELIVERY SYSTEMS COMPRISING MALODOR REDUCTION COMPOSITIONS

Description

FIELD OF THE INVENTION

The present invention relates to delivery systems comprising malodor reduction compositions, methods of making such delivery systems and consumer products made with such delivery systems.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C₂-C₁₂ carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.

Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. As a result of such recognition, Applicants developed delivery systems comprising malodor reduction compositions that do not unduely interfere with the scent of the perfumed or unperfumed delivery system, perfumed or unperfumed products comprising such delivery systems and any perfumed or unperfumed situs that is treated with such products. Such delivery systems are disclosed herein.

SUMMARY OF THE INVENTION

The present invention relates to delivery systems comprising malodor reduction compositions, methods of making such delivery systems and consumer products made with such delivery systems. Such delivery systems do not unduely interfere with the scent of the perfumed or unperfumed delivery system, perfumed or unperfumed products comprising such delivery systems and any perfumed or unperfumed situs that is treated with such products.

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.

As used herein, the term “perfume” does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value “MORV” that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.

As used herein “cleaning and/or treatment products” means products comprising fluid laundry detergents, fabric enhancers, laundry and/or rinse additives, fluid dishwashing detergents, fluid hard surface cleaning and/or treatment compositions, fluid toilet bowl cleaners that may or may not be contained in a unit dose delivery product all for consumer, agricultural, industrial or institutional use.

As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.

As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.

As used herein, the terms “a” and “an” mean “at least one”.

As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.

Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.

It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical identifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3 and there for Tables 4, 5 and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.

Codes
A = Vapor Pressure >0.1 torr
B = Vapor Pressure is between 0.01 torr and 0.1 torr
C = Calculated logP <3
D = Calculated logP >3
E = Probability of Ingredient Color Instability = 0%
F = Probability of Ingredient Color Instability <71%
G = Odor Detection Threshold less than p.ol = 8
H = Odor Detection Threshold greater than p.ol = 8
I = Melamine formaldehyde PMC Headspace Response Ratio greater
than or equal to 10
J = Melamine formaldehyde PMC leakage less than or equal to 5%
K = Log of liquid dish neat product liquid-air partition coefficient
greater than or equal to −7
L = Log of liquid dish neat product liquid-air partition coefficient
greater than or equal to −5

TABLE 1
List of materials with at least one MORV from 1 to 5

		CAS	Comment
Number	Material Name	Number	Code

1	2-ethylhexyl (Z)-3-(4-methoxyphenyl)acrylate	5466-77-3	DEFHJ
2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-	131812-67-4	DFHJ
	tetrahydronaphthalen-2-yl)-1,3-dioxolane
3	1,1-dimethoxynon-2-yne	13257-44-8	ACEFHJK
4	para-Cymen-8-ol	1197-01-9	BCGIJK
7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
9	Methoxycyclododecane	2986-54-1	DEFHJK
10	1,1-dimethoxycyclododecane	950-33-4	DEFHJK
11	(Z)-tridec-2-enenitrile	22629-49-8	DEFHJK
13	Oxybenzone	131-57-7	DEFGJ
14	Oxyoctaline formate	65405-72-3	DFHJK
16	4-methyl-1-oxaspiro[5.5]undecan-4-ol	57094-40-3	CFGIJK
17	7-methyl-2H-benzo[b][1,4]dioxepin-3(4H)-one	28940-11-6	CGIK
18	1,8-dioxacycloheptadecan-9-one	1725-01-5	DGJ
21	4-(tert-pentyl)cyclohexan-1-one	16587-71-6	ADFGIJKL
22	o-Phenyl anisol	86-26-0	DEFHJK
23	3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-	823178-41-2	DEFHJK
	4H-indeno(4,5-d)-1,3-dioxole
25	7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane	62406-73-9	BDEFHIJK
28	Octyl 2-furoate	39251-88-2	DEFHJK
29	Octyl acetate	112-14-1	BDEFHJKL
30	octanal propylene glycol acetal	74094-61-4	BDEFHJKL
31	Octanal	124-13-0	ACHIKL
32	Octanal dimethyl acetal	10022-28-3	ACEFGJKL
33	Myrcene	123-35-3	ADEFGIKL
34	Myrcenol	543-39-5	BCEFGIKL
35	Myrcenyl acetate	1118-39-4	ADEFGJK
36	Myristaldehyde	124-25-4	DFHJK
37	Myristicine	607-91-0	CGJK
38	Myristyl nitrile	629-63-0	DEFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
42	Ocimenol	5986-38-9	BCHIJK
43	Ocimenol	28977-58-4	BCHIJK
47	Nopyl acetate	128-51-8	DEFHJK
48	Nootkatone	4674-50-4	DHJK
49	Nonyl alcohol	143-08-8	BDEFGIJKL
50	Nonaldehyde	124-19-6	ADHIKL
52	12-methyl-14-tetradec-9-enolide	223104-61-8	DFHJK
57	N-ethyl-p-menthane-3-carboxamide	39711-79-0	DEFGIJK
61	1-(3-methylbenzofuran-2-yl)ethan-1-one	23911-56-0	CEFHIK
62	2-methoxynaphthalene	93-04-9	BDEFHK
63	Nerolidol	7212-44-4	DEFHJK
64	Nerol	106-25-2	BCHIK
65	1-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane	31996-78-8	ACEFHIJKL
67	Methyl (E)-non-2-enoate	111-79-5	ADEFHJKL
68	10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-	89079-92-5	BDEFHIJK
	diene
69	2-(2-(4-methylcyclohex-3-en-1-	95962-14-4	DHJK
	yl)propyl)cyclopentan-1-one
70	Myrtenal	564-94-3	ACFHIJKL
71	(E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one	54992-90-4	BDEFHIJK
74	Myraldyl acetate	53889-39-7	DHJK
75	Musk tibetine	145-39-1	DHIJ
76	1,7-dioxacycloheptadecan-8-one	3391-83-1	DGJ
77	Musk ketone	81-14-1	DHJ
78	Musk ambrette	83-66-9	DHIJ
79	3-methylcyclopentadecan-1-one	541-91-3	DEFHJK
80	(E)-3-methylcyclopentadec-4-en-1-one	82356-51-2	DHJK
82	3-methyl-4-phenylbutan-2-ol	56836-93-2	BCEFHIK
83	1-(4-isopropylcyclohexyl)ethan-1-ol	63767-86-2	BDEFHIJK
85	Milk Lactone	72881-27-7	DEFHJK
91	Methyl octine carbonate	111-80-8	BDEFHKL
92	Methyl octyl acetaldehyde	19009-56-4	ADFHJKL
93	6,6-dimethoxy-2,5,5-trimethylhex-2-ene	67674-46-8	ACHJKL
98	Methyl phenylethyl carbinol	2344-70-9	BCEFHIK
100	Methyl stearate	112-61-8	DEFHJ
101	Methyl nonyl acetaldehyde dimethyl acetal	68141-17-3	BDEFHJK
102	Methyl nonyl ketone	112-12-9	BDFHJKL
103	Methyl nonyl acetaldehyde	110-41-8	BDFHJK
104	Methyl myristate	124-10-7	DEFHJK
105	Methyl linoleate	112-63-0	DEFHJ
106	Methyl lavender ketone	67633-95-8	CFHJK
108	Methyl isoeugenol	93-16-3	ACEFHK
109	Methyl hexadecanoate	112-39-0	DEFHJK
110	Methyl eugenol	93-15-2	ACEFHK
112	Methyl epijasmonate	1211-29-6	CHJK
113	Methyl dihydrojasmonate	24851-98-7	DFHJK
114	Methyl diphenyl ether	3586-14-9	DEFHJK
117	Methyl cinnamate	103-26-4	BCEFHK
119	Methyl chavicol	140-67-0	ADEFHK
120	Methyl beta-naphthyl ketone	93-08-3	CEFHK
122	Methyl 2-octynoate	111-12-6	ACEFHKL
123	Methyl alpha-cyclogeranate	28043-10-9	ACHIJKL
126	Methoxycitronellal	3613-30-7	ACFGIJK
128	Menthone 1,2-glycerol ketal (racemic)	67785-70-0	CEFHJ
130	Octahydro-1H-4,7-methanoindene-1-carbaldehyde	30772-79-3	BCFHIJKL
134	3-(3-(tert-butyl)phenyl)-2-methylpropanal	62518-65-4	BDHJK
135	(E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine	38462-23-6	DEFHJK
137	(E)-trideca-3,12-dienenitrile	134769-33-8	DEFHJK
140	2,2-dimethyl-3-(m-tolyl)propan-1-ol	103694-68-4	CEFHIJK
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
142	Maceal	67845-30-1	BDFHJK
143	4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-	31906-04-4	CHJ
	carbaldehyde
145	1-Limonene	5989-54-8	ADEFGIJKL
146	(Z)-3-hexen-1-yl-2-cyclopenten-1-one	53253-09-1	BDHK
148	Linalyl octanoate	10024-64-3	DEFHJ
149	Linalyl isobutyrate	78-35-3	BDHJK
152	Linalyl benzoate	126-64-7	DFHJ
153	Linalyl anthranilate	7149-26-0	DFHJ
155	Linalool oxide (furanoid)	60047-17-8	BCHIJK
156	linalool oxide	1365-19-1	CGIJK
158	(2Z,6E)-3,7-dimethylnona-2,6-dienenitrile	61792-11-8	BDEFHJK
159	3-(4-methylcyclohex-3-en-1-yl)butanal	6784-13-0	ACFHIJK
161	(2,5-dimethyl-1,3-dihydroinden-2-yl)methanol	285977-85-7	CEFHJK
162	3-(4-(tert-butyl)phenyl)-2-methylpropanal	80-54-6	BDHJK
167	(E)-1-(1-methoxypropoxy)hex-3-ene	97358-54-8	ACEFGJKL
168	Leaf acetal	88683-94-7	ACEFGJKL
170	1-Carveol	2102-58-1	BCHIJK
174	Lauryl alcohol	112-53-8	DEFGJK
175	Lauryl acetate	112-66-3	DEFHJK
176	Lauric acid	143-07-7	DEFHJ
177	Lactojasmone	7011-83-8	BDEFHIJKL
178	Lauraldehyde	112-54-9	BDFHJK
179	3,6-dimethylhexahydrobenzofuran-2(3H)-one	92015-65-1	BCEFHIJKL
182	4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-	36306-87-3	BDFHIJK
	1-one
183	Khusimol	16223-63-5	CEFHJK
184	5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-	117933-89-8	DEFHJ
	methyl-1,3-dioxane
185	(1-methyl-2((1,2,2-trimethylbicyclo[3.1.0]hexan-	198404-98-7	DEFHJK
	3-yl)methyl)cyclopropyl)methanol
186	2-propylheptanenitrile	208041-98-9	ADEFHIJKL
187	(E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran-2-one	32764-98-0	BCFHJKL
189	2-hexylcyclopentan-1-one	13074-65-2	BDFHJKL
190	2-methyl-4-phenyl-1,3-dioxolane	33941-99-0	BCEFGIK
192	2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene	71078-31-4	BDEFHIJK
193	Isopulegol	89-79-2	BCEFHIJKL
195	Isopropyl palmitate	142-91-6	DEFHJ
196	Isopropyl myristate	110-27-0	DEFHJK
197	Isopropyl dodecanoate	10233-13-3	DEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
208	Isomenthone	491-07-6	ADEFGIJKL
209	Isojasmone	95-41-0	BDFHJKL
210	Isomenthone	36977-92-1	ADEFGIJKL
211	Isohexenyl cyclohexenyl carboxaldehyde	37677-14-8	DFHJK
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-	54464-57-2	DHJK
	octahydronaphthalen-2-yl)ethan-1-one
218	Isocyclocitral	1335-66-6	ACFHIJKL
221	Isobutyl quinoline	65442-31-1	DEFHJK
227	Isobomylcyclohexanol	68877-29-2	DEFHJK
228	Isobomyl propionate	2756-56-1	BDEFHIJK
229	Isobomyl isobutyrate	85586-67-0	BDEFHIJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
231	Isobomyl acetate	125-12-2	ADEFHIJKL
233	Isobergamate	68683-20-5	DEFHJK
234	Isoamyl undecylenate	12262-03-2	DEFHJK
238	Isoamyl laurate	6309-51-9	DEFHJK
242	Isoambrettolide	28645-51-4	DGJ
243	Irisnitrile	29127-83-1	ADEFHKL
244	Indolene	68527-79-7	DEFHJ
246	Indol/Hydroxycitronellal Schiff base	67801-36-9	DEFHJ
247	4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine	18096-62-3	BCEFGJK
249	Hydroxy-citronellol	107-74-4	CEFGIJK
252	2-cyclododecylpropan-1-ol	118562-73-5	DEFHJK
253	Hydrocitronitrile	54089-83-7	CEFHJK
254	Hydrocinnamyl alcohol	122-97-4	BCEFHIK
256	Hydratropaldehyde dimethyl acetal	90-87-9	ACEFHJK
259	5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one	27538-09-6	CFGIK
260	2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal	173445-44-8	DHJK
261	3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal	173445-65-3	DHJK
263	Hexyl octanoate	1117-55-1	DEFHJK
267	Hexyl hexanoate	6378-65-0	DEFHJKL
269	Hexyl cinnamic aldehyde	101-86-0	DHJ
271	Hexyl benzoate	6789-88-4	DEFHJK
274	Hexenyl tiglate	84060-80-0	BDEFHJK
276	(E)-3,7-dimethylocta-2,6-dien-1-yl palmitate	3681-73-0	DEFHJ
277	Hexadecanolide	109-29-5	DEFGJK
278	2-butyl-4,4,6-trimethyl-1,3-dioxane	54546-26-8	ADEFHIJKL
280	Ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-	116126-82-0	BDEFHIJK
	5-ene-2-carboxylate
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl	5413-60-5	CEFGJK
	acetate
285	2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-	141773-73-1	DEFHJ
	methylpropyl propionate
286	Heliotropine diethyl acetal	40527-42-2	CEFGJ
288	Helional	1205-17-0	CHJK
289	(E)-oxacyclohexadec-13-en-2-one	111879-80-2	DGJK
290	Gyrane	24237-00-1	ADEFHIJKL
292	Guaiol	489-86-1	DEFHJK
293	1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one	68611-23-4	DHJK
294	Ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-	57934-97-1	BDEFHIJK
	carboxylate
295	Germacrene B	15423-57-1	DEFHJK
296	Germacrene D	23986-74-5	DEFHJK
300	Geranyl phenylacetate	102-22-7	DFHJ
301	Geranyl phenyl acetate	71648-43-6	DFHJ
303	Geranyl linalool	1113-21-9	DFHJ
307	Geranyl cyclopentanone	68133-79-9	DHJK
316	gamma-Undecalactone (racemic)	104-67-6	DEFHJKL
317	gamma-Terpinyl acetate	10235-63-9	BDHJK
318	gamma-Terpineol	586-81-2	BCGIJK
321	gamma-Nonalactone	104-61-0	BCEFHIKL
322	gamma-Muurolene	30021-74-0	DEFHJKL
323	gamma-(E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran-	63095-33-0	BCEFHKL
	2-one
324	gamma-Ionone	79-76-5	BDEFHIJK
325	gamma-Himachalene	53111-25-4	BDEFHJKL
328	gamma-Gurjunene	22567-17-5	DEFHJKL
329	gamma-Eudesmol	1209-71-8	DFHJK
330	gamma-Dodecalactone	2305-05-7	DEFHJK
331	gamma-Damascone	35087-49-1	BDEFHIJK
332	gamma-Decalactone	706-14-9	BDEFHIJKL
333	gamma-Cadinene	39029-41-9	DEFHJKL
334	1-(3,3-dimethylcyclohexyl)pent-4-en-1-one	56973-87-6	BDEFHJK
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
336	Furfuryl octanoate	39252-03-4	DEFHJK
338	Furfuryl hexanoate	39252-02-3	CEFHJK
339	Furfuryl heptanoate	39481-28-2	CEFHJK
342	2-methyldecanenitrile	69300-15-8	BDEFHJKL
343	8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-	76842-49-4	DEFHJK
	methanoinden-6-yl propionate
344	Ethyl (3aR,4S,7R,7aR)-octahydro-3aH-4,7-	80657-64-3	DEFHIJK
	methanoindene-3a-carboxylate
347	Diethyl cyclohexane-1,4-dicarboxylate	72903-27-6	CEFHJK
349	(6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-	63187-91-7	CEFHJ
	yl)methanol
350	2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol	63500-71-0	BCEFHIJK
352	Undec-10-enenitrile	53179-04-7	BDEFHJK
353	(Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-	69486-14-2	CEFGJK
	2-one
356	3-(2-ethylphenyl)-2,2-dimethylpropanal	67634-15-5	BDHJK
358	(E)-4,8-dimethyldeca-4,9-dienal	71077-31-1	BDFHJK
359	(E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-	501929-47-1	DEFHJK
	5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol
360	8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-	171102-41-3	DEFHJK
	methanoinden-6-yl acetate
361	3-(4-ethylphenyl)-2,2-dimethylpropanenitrile	134123-93-6	DEFHJK
362	2-heptylcyclopentan-1-one	137-03-1	DFHJKL
363	1-ethoxyethoxy Cyclododecane	389083-83-4	DEFHJK
364	3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-,	815580-59-7	ACHIJKL
	methyl ester
368	Farnesyl acetate	29548-30-9	DEFHJK
369	Farnesol	4602-84-0	DEFHJK
370	Oxacyclohexadecan-2-one	106-02-5	DEFGJK
371	1-cyclopentadec-4-en-1-one	14595-54-1	DEFGJK
372	1-cyclopentadec-4-en-1-one	35720-57-1	DEFGJK
373	2-methoxy-4-(4-methylenetetrahydro-2H-pyran-2-	128489-04-3	CGJ
	yl)phenol
374	Eugenyl acetate	93-28-7	CFHJK
375	Eugenol	97-53-0	CHIK
377	Ethylmethylphenylglycidate	77-83-8	CFHJK
378	Ethylene brassylate	105-95-3	DFGJ
381	Ethyl undecylenate	692-86-4	DEFHJK
385	Ethyl palmitate	628-97-7	DEFHJ
386	Ethyl nonanoate	123-29-5	BDEFHJKL
388	Ethyl myristate	124-06-1	DEFHJK
390	Ethyl linalool	10339-55-6	BCEFHJK
391	Ethyl laurate	106-33-2	DEFHJK
394	Ethyl hexyl ketone	925-78-0	ADFHIKL
397	Ethyl decanoate	110-38-3	BDEFHJK
398	Ethyl gamma-Safranate	35044-57-6	ADHIJK
407	Ethyl 3-phenylglycidate	121-39-1	CGJK
413	6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-	79893-63-3	BDEFHIJK
	diene
414	Elemol	639-99-6	DEFHJK
415	(2-(1-ethoxyethoxy)ethyl)benzene	2556-10-7	BCEFHJK
416	(E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-	67801-20-1	DHJK
	yl)pent-4-en-2-ol
417	d-xylose	58-86-6	CGIJ
418	(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-	30168-23-1	DFHJK
	5-ylidene)butanal
421	Dodecanal dimethyl acetal	14620-52-1	DEFHJK
424	d-Limonene	5989-27-5	ADEFGIJKL
425	Dipropylene Glycol	25265-71-8	CEFGIK
426	Dispirone	83863-64-3	BDEFHJK
428	Diphenyloxide	101-84-8	BDEFHK
429	Diphenylmethane	101-81-5	DEFGK
432	Dimethyl benzyl carbinyl butyrate	10094-34-5	DEFHJK
436	2,6-dimethyloct-7-en-4-one	1879-00-1	ADEFHIJKL
441	Octahydro-1H-4,7-methanoinden-5-yl acetate	64001-15-6	DEFHJKL
444	Dihydrocarveol acetate	20777-49-5	BDEFHIJK
445	Dihydrocarveol	619-01-2	BCEFHIJKL
449	Dihydro Linalool	18479-51-1	BCEFGIJKL
450	Dihydro Isojasmonate	37172-53-5	DHJK
453	Dibutyl sulfide	544-40-1	ADEFHIKL
457	Dibenzyl	103-29-7	DEFGJK
459	delta-Undecalactone	710-04-3	DEFHJKL
461	delta-Elemene	20307-84-0	BDEFHJK
462	delta-Guaiene	3691-11-0	DEFHJKL
463	delta-Dodecalactone	713-95-1	DEFHJK
464	delta-Decalactone	705-86-2	BDEFHIJKL
465	delta-Cadinene	483-76-1	DEFHJKL
466	delta-damascone	57378-68-4	ADHIJK
467	delta-Amorphene	189165-79-5	DEFHJKL
468	delta-3-Carene	13466-78-9	ADEFGIJKL
470	Decylenic alcohol	13019-22-2	BDEFHJK
471	Decyl propionate	5454-19-3	DEFHJK
473	Decanal diethyl acetal	34764-02-8	DEFHJK
474	Decahydro-beta-naphthol	825-51-4	BCEFGIK
475	1-cyclohexylethyl (E)-but-2-enoate	68039-69-0	BDFHJK
478	3-(4-isopropylphenyl)-2-methylpropanal	103-95-7	BDFHJK
479	Cyclotetradecane	295-17-0	DEFGJKL
480	Cyclopentadecanone	502-72-7	DEFGJK
482	Cyclohexyl salicylate	25485-88-5	DFGJ
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl	113889-23-9	DEFHJK
	butyrate
485	Cyclic ethylene dodecanedioate	54982-83-1	DFGJ
486	8,8-dimethyl-1,2,3,4,5,6,7,8-	68991-97-9	DHJK
	octahydronaphthalene-2-carbaldehyde
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl	67634-20-2	DEFHJK
	isobutyrate
488	Curzerene	17910-09-7	DHJK
491	Cumic alcohol	536-60-7	CHIJK
493	Coumarone	1646-26-0	BCEFHIK
497	2-(3-phenylpropyl)pyridine	2110-18-1	CEFHJK
498	Dodecanenitrile	2437-25-4	DEFHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
502	Citryl acetate	6819-19-8	DFHJK
503	Citrus Propanol	15760-18-6	CEFHIJK
505	Citronitrile	93893-89-1	CEFHJK
519	Citral propylene glycol acetal	10444-50-5	CEFHJK
520	Citral dimethyl acetal	7549-37-3	BCEFHJK
521	Citral diethyl acetal	7492-66-2	BDEFHJK
524	cis-Ocimene	3338-55-4	ADGIKL
527	cis-Limonene oxide	13837-75-7	ADEFGIJKL
529	Cis-iso-ambrettolide	36508-31-3	DGJ
530	cis-6-nonenol	35854-86-5	BCEFHIKL
531	cis-carveol	1197-06-4	BCHIJK
532	cis-4-Decen-1-al	21662-09-9	ADHKL
534	cis-3-hexenyl-cis-3-hexenoate	61444-38-0	BDEFHJK
537	cis-3-Hexenyl salicylate	65405-77-8	DEFGJ
541	Cis-3-hexenyl Benzoate	25152-85-6	DEFHJK
544	cis-3-Hexenyl 2-methylbutyrate	53398-85-9	ADEFHJKL
546	cis-3, cis-6-nonadienol	53046-97-2	ACEFHK
548	Cinnamyl propionate	103-56-0	DEFHJK
550	Cinnamyl isobutyrate	103-59-3	DEFHJK
551	Cinnamyl formate	104-65-4	BCEFHK
552	Cinnamyl cinnamate	122-69-0	DHJ
553	Cinnamyl acetate	103-54-8	BCEFHK
555	Cinnamic alcohol	104-54-1	BCEFHIK
558	Cetyl alcohol	36653-82-4	DEFHJ
559	(E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-	79-78-7	DHJK
	dien-3-one
560	2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-	65405-84-7	DFHJK
	yl)butanal
561	(3aR,5aR,9aR,9bR)-3a,6,6,9a-	3738-00-9	DEFHJK
	tetramethyldodecahydronaphtho[2,1-b]furan
562	1,6-dioxacycloheptadecan-7-one	6707-60-4	DGJ
563	1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-	13171-00-1	DEFHJK
	4-yl)ethan-1-one
565	Cedryl methyl ether	19870-74-7	ADEFHJK
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
568	(4Z,8Z)-1,5,9-trimethyl-13-	71735-79-0	DFHJK
	oxabicyclo[10.1.0]trideca-4,8-diene
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-	139539-66-5	DEFHJK
	oxabicyclo[3.2.1]octane
571	5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-	426218-78-2	DFHJ
	oxabicyclo[3.2.1]octane
572	1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-	33704-61-9	BDEFHIJK
	inden-4-one
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
577	Carvyl acetate	97-42-7	BDHIJK
578	Caprylnitrile	124-12-9	ACEFGIKL
580	Caprylic alcohol	111-87-5	ACEFGIKL
581	Caprylic acid	124-07-2	BCEFHIK
582	Capric acid	334-48-5	DEFHJK
584	Capraldehyde	112-31-2	ADHKL
586	3-(4-methoxyphenyl)-2-methylpropanal	5462-06-6	BCHJK
587	Camphorquinone	10373-78-1	ACEFGIJK
589	Camphene	79-92-5	ADEFGIJKL
591	Ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-	59151-19-8	DHJ
	carboxylate
592	Butylated hydroxytoluene	128-37-0	DEFGIJK
594	Butyl stearate	123-95-5	DEFHJ
595	Butyl butyryl lactate	7492-70-8	CEFGJK
599	Butyl 10-undecenoate	109-42-2	DEFHJK
600	2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-	72089-08-8	DEFHJK
	yl)butan-1-ol
601	3-(4-(tert-butyl)phenyl)propanal	18127-01-0	BDHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
604	Bornyl acetate	76-49-3	ADEFHIJKL
606	2-ethoxy-2,6,6-trimethyl-9-	68845-00-1	BDEFHJK
	methylenebicyclo[3.3.1]nonane
607	(ethoxymethoxy)cyclododecane	58567-11-6	DEFHJK
608	Bisabolene	495-62-5	DEFHJK
609	Bigarade oxide	72429-08-4	ADEFHJKL
610	beta-Vetivone	18444-79-6	DHJK
611	beta-Terpinyl acetate	10198-23-9	BDHJK
612	beta-Terpineol	138-87-4	BCGIJK
613	beta-Sinensal	60066-88-8	DHJK
614	beta-Sesquiphellandrene	20307-83-9	DEFHJK
615	beta-Selinene	17066-67-0	BDEFGJK
616	beta-Santalol	77-42-9	DEFHJK
618	beta-Pinene	127-91-3	ADEFGIJKL
620	beta-Naphthyl ethyl ether	93-18-5	BDEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
625	beta-Himachalene	1461-03-6	DEFHJKL
626	beta-Guaiene	88-84-6	DEFHJKL
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
628	beta-Farnesene	18794-84-8	DEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
632	beta-Cedrene	546-28-1	BDEFGJKL
633	beta-Caryophyllene	87-44-5	DEFHJKL
635	beta-Bisabolol	15352-77-9	DFHJK
636	Beta ionone epoxide	23267-57-4	BDEFHIJK
638	Bergaptene	484-20-8	CGJ
639	Benzyl-tert-butanol	103-05-9	CEFGJK
644	Benzyl laurate	140-25-0	DEFHJ
649	Benzyl dimethyl carbinol	100-86-7	BCEFGIK
650	Benzyl cinnamate	103-41-3	DHJ
653	Benzyl benzoate	120-51-4	DHJ
655	Benzophenone	119-61-9	DEFHK
658	7-isopentyl-2H-benzo[b][1,4]dioxepin-3(4H)-one	362467-67-2	DHJ
659	2′-isopropyl-1,7,7-	188199-50-0	DEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-2,4′-
	[1,3]dioxane
660	4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-	21690-43-7	DEFHJK
	carbonitrile
661	Aurantiol	89-43-0	DEFHJ
663	Anisyl phenylacetate	102-17-0	DFHJ
668	Methyl (E)-octa-4,7-dienoate	189440-77-5	ACEFHKL
671	Amyl Cinnamate	3487-99-8	DEFHJK
673	(3aR,5aS,9aS,9bR)-3a,6,6,9a-	6790-58-5	DEFHJK
	tetramethyldodecahydronaphtho[2,1-b]furan
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-	211299-54-6	DEFHJK
	4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole
675	2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-	71832-76-3	DEFHJK
	2-ol
676	2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-	41199-19-3	DEFHJK
	2-ol
677	1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol	139504-68-0	DEFHJK
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-	476332-65-7	ADEFHJK
	b]furan
680	2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-	647828-16-8	ADEFHJK
	b]furan
681	Amber acetate	37172-02-4	BDEFHJK
682	Alpinofix ®	811436-82-5	DEFHJ
683	alpha-Thujone	546-80-5	ADEFGIJKL
684	alpha-Vetivone	15764-04-2	DHJK
686	alpha-Terpinyl propionate	80-27-3	BDEFHJK
691	alpha-Sinensal	17909-77-2	DHJK
692	alpha-Selinene	473-13-2	BDEFHJK
693	alpha-Santalene	512-61-8	ADEFHJKL
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
697	alpha-neobutenone	56973-85-4	BDHJK
698	alpha-Muurolene	10208-80-7	DEFHJKL
700	alpha-methyl ionone	127-42-4	BDHJK
702	alpha-Limonene	138-86-3	ADEFGIJKL
704	alpha-Irone	79-69-6	BDHJK
706	alpha-Humulene	6753-98-6	DEFHJK
707	alpha-Himachalene	186538-22-7	BDEFHJK
708	alpha-Gurjunene	489-40-7	BDEFHJKL
709	alpha-Guaiene	3691-12-1	DEFHJKL
710	alpha-Farnesene	502-61-4	DEFHJK
711	alpha-Fenchene	471-84-1	ADEFGIJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
713	alpha-Curcumene	4176-17-4	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
715	alpha-Cedrene epoxide	13567-39-0	ADEFHJK
716	alpha-Cadinol	481-34-5	DEFHJK
717	alpha-Cadinene	24406-05-1	DEFHJKL
718	alpha-Bisabolol	515-69-5	DFHJK
719	alpha-bisabolene	17627-44-0	DEFHJK
720	alpha-Bergamotene	17699-05-7	BDEFHJKL
721	alpha-Amylcinnamyl alcohol	101-85-9	DEFHJ
722	alpha-Amylcinnamyl acetate	7493-78-9	DEFHJ
723	alpha-Amylcinnamaldehyde diethyl acetal	60763-41-9	DEFHJ
724	alpha-Amylcinnamaldehyde	122-40-7	DHJK
725	alpha-Amorphene	23515-88-0	DEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
727	1-methyl-4-(4-methyl-3-penten-1-yl)-3-Cyclohexene-	52475-86-2	DFHJK
	1-carboxaldehyde
730	1-Phenyl-2-pentanol	705-73-7	CEFHK
731	1-Phenyl-3-methyl-3-pentanol	10415-87-9	CEFHJK
733	2,3,4-trimethoxy-benzaldehyde	2103-57-3	BCGI
735	2,4,5-trimethoxy-benzaldehyde	4460-86-0	BCG
736	2,4,6-trimethoxybenzaldehyde	830-79-5	BCGI
738	2,4-Nonadienal	6750-03-4	ACHKL
741	2,6,10-Trimethylundecanal	105-88-4	BDFGJK
742	alpha,4-Dimethyl benzenepropanal	41496-43-9	ACHJK
746	Allyl cyclohexyl propionate	2705-87-5	BDEFHJK
748	Allyl amyl glycolate	67634-00-8	BCEFGJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
752	Aldehyde C-11	143-14-6	ADHJK
754	Methyl (E)-2-(((3,5-dimethylcyclohex-3-en-1-	94022-83-0	DEFHJ
	yl)methylene)amino)benzoate
757	2,6,10-trimethylundec-9-enal	141-13-9	BDFHJK
758	Acetoxymethyl-isolongifolene (isomers)	59056-62-1	BDEFHJK
763	Acetate C9	143-13-5	BDEFHJKL
764	Acetarolle ®	744266-61-3	DFHJK
766	Acetaldehyde phenylethyl propyl acetal	7493-57-4	CEFHJK
767	Acetaldehyde dipropyl acetal	105-82-8	ACEFGIKL
768	Acetaldehyde benzyl 2-methoxyethyl acetal	7492-39-9	BCEFHJK
769	(Z)-2-(4-methylbenzylidene)heptanal	84697-09-6	DHJ
770	9-decenal	39770-05-3	ADHKL
771	8-Hexadecenolide	123-69-3	DGJ
772	7-Methoxycoumarin	531-59-9	CHK
774	7-epi-alpha-Selinene	123123-37-5	BDEFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-hexamethyltetralin	1506-02-1	DEFHJ
778	6-Isopropylquinoline	135-79-5	CEFHJK
781	6,6-dimethyl-2-norpinene-2-propionaldehyde	33885-51-7	BCFHJK
782	6,10,14-trimethyl-2-Pentadecanone	502-69-2	DEFHJK
786	5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran	13679-86-2	ACGIJKL
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
791	4-Terpinenol	562-74-3	BCHIJK
792	4-Pentenophenone	3240-29-7	BCEFHIK
800	4-Carvomenthenol	28219-82-1	BCHIJK
802	4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran	494-90-6	BCEFHIJKL
803	4-(p-Methoxyphenyl)-2-butanone	104-20-1	BCEFHJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
805	3-Propylidenephthalide	17369-59-4	CEFHK
806	3-Nonylacrolein	20407-84-5	BDFHJK
807	3-Methyl-5-phenyl-1-pentanal	55066-49-4	BDFHJK
814	3-Hexenyl isovalerate	10032-11-8	ADEFHJKL
821	3,6-Dimethyl-3-octanyl acetate	60763-42-0	ADEFHIJKL
824	3,4,5-trimethoxybenzaldehyde	86-81-7	BCGIK
826	3-(p-Isopropylphenyl)propionaldehyde	7775-00-0	BDFHJK
827	2-Undecenenitrile	22629-48-7	BDEFHJK
828	2-Undecenal	2463-77-6	ADHJK
829	2-trans-6-trans-Nonadienal	17587-33-6	ACHKL
831	2-Phenylethyl butyrate	103-52-6	DEFHJK
833	2-Phenyl-3-(2-furyl)prop-2-enal	57568-60-2	CHJ
834	2-Phenoxyethanol	122-99-6	BCEFGIK
837	2-Nonen-1-al	2463-53-8	ADHKL
839	2-Nonanol	628-99-9	BDEFGIKL
840	2-Nonanone	821-55-6	ADFHIKL
849	2-Isobutyl quinoline	93-19-6	CEFHJK
850	2-Hexylidene cyclopentanone	17373-89-6	DFHJKL
852	2-Heptyl tetrahydrofuran	2435-16-7	BDEFHJKL
856	2-Decenal	3913-71-1	ADHKL
864	2,6-Nonadienal	26370-28-5	ACHKL
865	2,6-Nonadien-1-ol	7786-44-9	ACEFHK
866	2,6-dimethyl-octanal	7779-07-9	ADFGIJKL
868	1-Decanol	112-30-1	BDEFGJK
869	1-Hepten-1-ol, 1-acetate	35468-97-4	ACEFHKL
870	10-Undecen-1-ol	112-43-6	DEFHJK
871	10-Undecenal	112-45-8	ADHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
873	1,8-Thiocineol	68391-28-6	ADEFHIJKL
876	1,3,5-undecatriene	16356-11-9	ADEFHJKL
877	1,2-Dihydrolinalool	2270-57-7	BCEFGIJKL
878	1,3,3-trimethyl-2-norbornanyl acetate	13851-11-1	ADEFHIJKL
879	1,1,2,3,3-Pentamethylindan	1203-17-4	ADHIJKL
881	(Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate	3239-37-0	DEFHJK
884	(Z)-3-Dodecenal	68141-15-1	BCFHJK
885	(S)-gamma-Undecalactone	74568-05-1	DEFHJKL
886	(R)-gamma-Undecalactone	74568-06-2	DEFHJKL
890	(E)-6,10-dimethylundeca-5,9-dien-2-yl acetate	3239-35-8	DEFHJK
892	(2Z)-3-methyl-5-phenyl-2-Pentenenitrile	53243-59-7	DEFHJK
893	(2S,5S,6S)-2,6,10,10-tetramethyl-1-	65620-50-0	DFHIJK
	oxaspiro[4_5]decan-6-ol
894	(2E)-3-methyl-5-phenyl-2-pentenenitrile	53243-60-0	CEFHJK
897	(+)-Dihydrocarveol	22567-21-1	BCEFHIJKL
905	Menthone	89-80-5	ADEFGIJKL
908	(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-	185068-69-3	CHJK
	yl)but-2-en-1-ol
912	2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-	68901-32-6	DEFHJK
	1,3-dioxolane
913	gamma-methyl ionone	7388-22-9	BDHIJK
914	3-(3-isopropylphenyl)butanal	125109-85-5	BDHJK
916	3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene	40910-49-4	BDEFHJK
919	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl	17511-60-3	CEFHJK
	propionate
920	Bulnesol	22451-73-6	DEFHJK
922	Benzyl phenylacetate	102-16-9	DHJ
923	Benzoin	119-53-9	CEFHJ
924	(E)-1,2,4-trimethoxy-5-(prop-1-en-1-yl)benzene	2883-98-9	BCFGJK
925	alpha,alpha,6,6-tetramethyl bicyclo[3.1.1]hept-2-	33885-52-8	BDFHJK
	ene-propanal
926	7-epi-sesquithujene	159407-35-9	DEFHJKL
927	5-Acetyl-1,1,2,3,3,6-hexamethylindan	15323-35-0	DEFHJK
928	3-Methylphenethyl alcohol	1875-89-4	BCEFHIK
929	3,6-Nonadien-1-ol	76649-25-7	ACEFHK
930	2-Tridecenal	7774-82-5	BDFHJK
933	Patchouli alcohol	5986-55-0	DEFHIJK
937	p-Cresyl isobutyrate	103-93-5	BDHJK
939	p-Cresyl n-hexanoate	68141-11-7	DEFHJK
941	5-hexyl-4-methyldihydrofuran-2(3H)-one	67663-01-8	BDEFHIJKL
942	Ethyl (2Z,4E)-deca-2,4-dienoate	3025-30-7	BDEFHJK
943	Pelargene	68039-40-7	DEFHJK
945	2-cyclohexylidene-2-phenylacetonitrile	10461-98-0	DFHJK
946	Perillaldehyde	2111-75-3	ACHIJK
947	Perillyl acetate	15111-96-3	DFHJK
948	Perillyl alcohol	536-59-4	CHIJK
950	(2-isopropoxyethyl)benzene	68039-47-4	ACEFHJKL
951	Ethyl (2Z,4E)-deca-2,4-dienoate	313973-37-4	BDEFHJK
953	(2-(cyclohexyloxy)ethyl)benzene	80858-47-5	DEFHJK
954	Phenethyl 2-methylbutyrate	24817-51-4	DEFHJK
955	Phenethyl alcohol	60-12-8	BCEFGIK
959	Phenethyl phenylacetate	102-20-5	DHJ
962	Phenoxanol	55066-48-3	DEFHJK
965	Phenyl benzoate	93-99-2	DFHJK
967	Phenyl ethyl benzoate	94-47-3	DHJ
969	Phenylacetaldehyde ethyleneglycol acetal	101-49-5	BCEFGIK
973	2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-	30897-75-7	ACFHIJKL
	yl)acetaldehyde
974	Pinocarveol	5947-36-4	BCEFGIJKL
976	Piperonyl acetone	55418-52-5	CEFGJ
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl	68039-44-1	DEFHJK
	pivalate
980	(4aR,8aS)-7-methyloctahydro-1,4-	41724-19-0	CEFGJKL
	methanonaphthalen-6(2H)-one
982	p-Menth-3-en-1-ol	586-82-3	BCGIJK
985	(E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-	107898-54-4	DHJK
	1-yl)pent-4-en-2-ol
988	1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-	52474-60-9	DFHJK
	ene-1-carbaldehyde
993	Propylene glycol	57-55-6	ACEFGIKL
998	p-Tolyl phenylacetate	101-94-0	DFHJ
1000	Ethyl 2,4,7-decatrienoate	78417-28-4	BDEFHJK
1003	2-benzyl-4,4,6-trimethyl-1,3-dioxane	67633-94-7	DEFHJK
1006	2,4-dimethyl-4-phenyltetrahydrofuran	82461-14-1	BDEFHJK
1007	(2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-	41816-03-9	DEFHJK
	hexahydro-1′H-spiro[oxirane-2,2′-
	[1,4]methanonaphthalene]
1008	(Z)-6-ethylideneoctahydro-2H-5,8-methanochromene	93939-86-7	BCEFHJKL
1009	2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-	236391-76-7	DFHJ
	oxoethyl propionate
1010	Methyl 2,2-dimethyl-6-methylenecyclohexane-1-	81752-87-6	ADHIJKL
	carboxylate
1012	2-methyl-5-phenylpentan-1-ol	25634-93-9	DEFHJK
1016	4-methyl-2-phenyl-3,6-dihydro-2H-pyran	60335-71-9	BCEFGJK
1020	Sabinol	471-16-9	BCEFHIJKL
1021	Safrole	94-59-7	BCEFHK
1022	2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one	502847-01-0	DHIJK
1023	3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-	65113-99-7	DEFHJK
	yl)pentan-2-ol
1024	(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-	28219-61-6	DEFHJK
	yl)but-2-en-1-ol
1025	(E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-	28219-60-5	CHJK
	1-yl)but-2-en-1-ol
1026	5-methoxyoctahydro-1H-4,7-methanoindene-2-	86803-90-9	CHJK
	carbaldehyde
1027	5-methoxyoctahydro-1H-4,7-methanoindene-2-	193425-86-4	CHJK
	carbaldehyde
1028	Sclareol	515-03-7	DEFHJ
1029	Sclareol oxide	5153-92-4	DEFHJK
1031	Selina-3,7(11)-diene	6813-21-4	DEFHJKL
1032	2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-	477218-42-1	DEFHJ
	methylpropyl cyclopropanecarboxylate
1033	3-(4-isobutylphenyl)-2-methylpropanal	6658-48-6	DHJK
1035	Spathulenol	6750-60-3	DEFHJK
1036	Spirambrene	533925-08-5	BCEFHJK
1037	Spirodecane	6413-26-9	BCEFGIJKL
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one	224031-70-3	DGJK
1042	2-(4-methylthiazol-5-yl)ethan-1-ol	137-00-8	CGIKL
1043	2-(heptan-3-yl)-1,3-dioxolane	4359-47-1	ACEFHIJKL
1045	(Z)-dodec-4-enal	21944-98-9	BDFHJK
1046	tau-Cadinol	5937-11-1	DEFHJK
1047	tau-Muurolol	19912-62-0	DEFHJK
1053	Tetrahydrojasmone	13074-63-0	BDFHIJKL
1057	2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene	36431-72-8	BDFHIJKL
1059	Thiomenthone	38462-22-5	BDEFHIJKL
1060	Thujopsene	470-40-6	BDEFGJKL
1062	Thymol methyl ether	1076-56-8	ADHIJKL
1063	1-(2,2,6-trimethylcyclohexyl)hexan-3-ol	70788-30-6	DEFHJK
1064	trans,trans-2,4-Nonadienal	5910-87-2	ACHKL
1065	trans,trans-Farnesol	106-28-5	DEFHJK
1066	trans-2,cis-6-Nonadienal	557-48-2	ACHKL
1067	trans-2-Decenal	3913-81-3	ADHKL
1070	trans-2-Nonen-1-al	18829-56-6	ADHKL
1072	trans-3, cis-6-nonadienol	56805-23-3	ACEFHK
1073	trans-4-Decen-1-al	65405-70-1	ADHKL
1075	trans-ambrettolide	51155-12-5	DGJ
1077	trans-beta-ocimene	13877-91-3	ADGIKL
1078	trans-beta-Ocimene	3779-61-1	ADGIKL
1082	trans-Geraniol	106-24-1	BCHIK
1083	trans-Hedione	2570-03-8	DFHJK
1085	7-(1,1-Dimethylethyl)-2H-1,5-benzodioxepin-3(4H)-	195251-91-3	CEFHJ
	one
1089	Tricyclone	68433-81-8	DEFHJK
1090	Tridecyl alcohol	112-70-9	DEFGJK
1091	Triethyl citrate	77-93-0	CEFGJ
1093	Methyl 2-((l-hydroxy-3-phenylbutyl)amino)benzoate	144761-91-1	DFHJ
1095	1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-	28371-99-5	DHJK
	trien-1-yl)ethan-1-one
1097	Decahydro-2,6,6,7,8,8-hexamethyl-2h-	338735-71-0	BDEFHJK
	indeno(4,5-b)furan
1099	13-methyl oxacyclopentadec-10-en-2-one	365411-50-3	DEFHJK
1102	Undecanal	112-44-7	BDHJK
1104	(E)-4-methyldec-3-en-5-ol	81782-77-6	BDEFHIJK
1105	Valencene	4630-07-3	BDEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1111	Vanillin isobutyrate	20665-85-4	CHJ
1113	Vaniwhite ®	5533-03-9	CGIK
1116	(Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-	68555-62-4	BDFHJK
	yl)but-2-enal
1117	Methyl 2,4-dihydroxy-3,6-dimethylbenzoate	4707-47-5	CGIJ
1120	1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-	27135-90-6	ACEFHJKL
	methanoindene
1121	Methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-	91-51-0	DFHJ
	methylpropylidene)amino)benzoate
1125	(Z)-hex-3-en-1-yl isobutyrate	41519-23-7	ADEFHJKL
1126	Vertacetal	5182-36-5	BCFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-	32388-55-9	DHJK
	hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one
1131	Methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-	68738-99-8	DEFHJ
	yl)methylene)amino)benzoate
1135	Vetiverol	89-88-3	CEFHIJK
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]	68480-11-5	DEFGJKL
1138	(2Z,6E)-nona-2,6-dienenitrile	67019-89-0	ACEFHKL
1139	(Z)-cyclooct-4-en-1-yl methyl carbonate	87731-18-8	BCHJKL
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-	552-02-3	DEFHJK
	tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-	127459-79-4	DHJ
	tetrahydronaphthalene-2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-	133636-82-5	DEFHJK
	trimethylspiro[bicyclo[3.1.1]heptane-3,1′-
	cyclohexan]-2′-en-4′-one
1144	1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-	154171-76-3	DEFHJK
	spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]
1145	1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-	154171-77-4	DEFHJK
	spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene] K
1146	4-(4-hydroxy-3-methoxyphenyl)butan-2-one	122-48-5	CEFGJ
1147	(1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-	41929-05-9	DEFHJKL
	hexahydronaphthalene
1148	4,5-epoxy-4,11,11-trimethyl-8-	1139-30-6	DEFHJK
	methylenebicyclo(7.2.0)undecane
1149	1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-	23787-90-8	DEFHIJK
	2,4alpha-methanophthalen-8(5H)-one

TABLE 2
List of materials with at least one MORV greater than 5 to 10

Number	Material Name	CAS Number	Comment Code

2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-	131812-67-4	DFHJ
	tetrahydronaphthalen-2-yl)-1,3-dioxolane
23	3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-	823178-41-2	DEFHJK
	heptamethyl-4H-indeno(4,5-d)-1,3-dioxole
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
185	(1-methyl-2-((1,2,2-	198404-98-7	DEFHJK
	trimethylbicyclo[3.1.0]hexan-
	3-yl)methyl)cyclopropyl)methanol
227	Isobornylcyclohexanol	68877-29-2	DEFHJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
246	Indol/Hydroxycitronellal	67801-36-9	DEFHJ
	Schiff base
248	Hydroxymethyl isolongifolene	59056-64-3	DEFHJK
343	8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-	76842-49-4	DEFHJK
	4,7-methanoinden-6-yl propionate
359	(E)-4-((3aR,4R,7R,7aR)-	501929-47-1	DEFHJK
	1,3a,4,6,7,7a-hexahydro-
	5H-4,7-methanoinden-5-ylidene)-
	3-methylbutan-2-ol
565	Cedryl methyl ether	19870-74-7	BDEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
659	2'-isopropyl-1,7,7-	869292-93-3	BDEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-
	2,4'-[1,3]dioxane]
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-	211299-54-6	DEFHJK
	hexamethyloctahydro-
	4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-	476332-65-7	DEFHJK
	2H-indeno[4,5-b]furan
715	alpha-Cedrene epoxide	13567-39-0	BDEFHJK
758	Acetoxymethyl-isolongifolene	59056-62-1	DEFHJK
	(isomers)
1028	Sclareol	515-03-7	DEFHJ
1097	Decahydro-2,6,6,7,8,8-	338735-71-0	DEFHJK
	hexamethyl-2h-indeno(4,5-b)furan

TABLE 3
List of materials with at least one MORV from 0.5 to less than 1

Number	Material Name	CAS Number	Comment Code

12	1-ethoxy-4-(tert-pentyl)cyclohexane	181258-89-9	ADEFHJK
19	(3Z)-1-(2-buten-1-yloxy)-3-hexene	888744-18-1	ADEFHJKL
20	4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene	14576-08-0	ADHIJKL
24	O-Methyl linalool	60763-44-2	ADHIJKL
26	o-Methoxycinnamaldehyde	1504-74-1	ACHK
27	Octanal, 3,7-dimethyl-	25795-46-4	ADGIJKL
53	3,3-Dimethyl-5(2,2,3-Trimethyl-3-	329925-33-9	CEFHJ
	Cyclopenten-1yl)-4-Penten-2-ol
54	n-Hexyl salicylate	6259-76-3	DEFHJ
55	n-Hexyl 2-butenoate	19089-92-0	ADEFHJKL
59	Neryl Formate	2142-94-1	BCEFHJK
72	Methyl-beta-ionone	127-43-5	DHJK
73	Myroxide	28977-57-3	ADGIJKL
81	(E)-3,7-dimethylocta-4,6-dien-3-ol	18479-54-4	BCEFGIJK
84	(Z)-hex-3-en-1-ylcyclopropanecarboxylate	188570-78-7	BCEFHIKL
96	Methyl phenyl carbinyl propionate	120-45-6	BCHJK
97	Methyl phenylacetate	101-41-7	ACEFHIKL
107	2-methyl-6-oxaspiro[4.5]decan-7-one	91069-37-3	BCEFGIKL
111	Methyl geraniate	2349-14-6	BCHJKL
115	2-ethoxy-4-(methoxymethyl)phenol	5595-79-9	CFGK
116	Methyl cyclopentylideneacetate	40203-73-4	ACEFHIKL
125	Methoxymelonal	62439-41-2	ACGIJK
133	((1s,4s)-4-isopropylcyclohexyl)methanol	13828-37-0	BDEFHIJK
147	Linalyl propionate	144-39-8	BDFHJK
150	Linalyl formate	115-99-1	ACFHJK
151	Linalyl butyrate	78-36-4	BDEFHJK
154	Linalyl acetate	115-95-7	BDHJK
157	Linalool	78-70-6	BCEFGIJK
163	(Z)-hex-3-en-1-yl methyl carbonate	67633-96-9	ACEFGKL
166	Lepidine	491-35-0	BCEFHIKL
169	L-Carvone	6485-40-1	ACGIJKL
181	Khusinil	75490-39-0	DHJK
191	Isoraldeine	1335-46-2	BDHIJK
194	Isopropylvinylcarbinol	4798-45-2	ACGIKL
198	Isopropyl 2-methylbutyrate	66576-71-4	ACEFGIJKL
201	Isopentyrate	80118-06-5	ADEFGIJKL
204	Isononyl acetate	40379-24-6	BDEFHJKL
205	Isononanol	27458-94-2	BDEFGIKL
213	Isoeugenyl acetate	93-29-8	CFHJK
214	Isoeugenol	97-54-1	CEFHIK
232	Isoborneol	124-76-5	ACEFHIJKL
237	Isoamyl octanoate	2035-99-6	DEFHJK
239	Isoamyl isobutyrate	2050-01-3	ACEFGIJKL
255	Hydrocinnamic acid	501-52-0	CEFHIK
258	Hydratopic alcohol	1123-85-9	BCEFHIK
264	Hexyl propanoate	2445-76-3	ADEFHIKL
270	Hexyl butyrate	2639-63-6	BDEFHJKL
273	Hexyl 2-methylbutanoate	10032-15-2	BDEFHJKL
275	Hexyl 2-furoate	39251-86-0	DEFHJK
282	Heptyl alcohol	111-70-6	ACEFGIKL
283	Heptyl acetate	112-06-1	ADEFHKL
284	Heptaldehyde	111-71-7	ACHIKL
287	Heliotropin	120-57-0	BCGIK
302	Geranyl nitrile	5146-66-7	BCEFHKL
306	Geranyl formate	105-86-2	BCEFHJK
308	Geranyl caprylate	51532-26-4	DEFHJ
310	Geranyl benzoate	94-48-4	DFHJ
312	Geranial	141-27-5	ACHIKL
314	N,2-dimethyl-N-phenylbutanamide	84434-18-4	BCEFHJK
319	gamma-Terpinene	99-85-4	ADEFGIJKL
346	2-(sec-butyl)cyclohexan-1-one	14765-30-1	ADFHIKL
354	3-(2-ethylphenyl)-2,2-dimethylpropanal	67634-14-4	BDHJK
355	2-(tert-butyl)cyclohexyl ethyl carbonate	67801-64-3	BDFHJK
365	2-(tert-butyl)cyclohexyl ethyl carbonate	81925-81-7	ACFHIKL
366	Fenchyl alcohol	1632-73-1	ACGIJKL
376	Eucalyptol	470-82-6	ADEFGIJKL
379	Ethyl vanillin acetate	72207-94-4	CHJ
387	Ethyl octanoate	106-32-1	BDEFHJKL
400	Ethyl cinnamate	103-36-6	BCEFHK
412	Ethyl 2-(cyclohexyl)propionate	2511-00-4	BDFHIJKL
419	d-p-8(9)-Menthen-2-one	5524-05-0	ACGIJKL
420	4-methyl-2-phenyltetrahydro-2H-pyran	94201-73-7	BDEFHJK
437	Dihydromyrcenol	18479-58-8	ADEFGIJK
438	Dihydrojasmone	1128-08-1	BCFHIJKL
439	Dihydroisophorone	873-94-9	ACEFGIJKL
440	Dihydroeugenol	2785-87-7	CEFHIJK
442	Dihydrocoumarin	119-84-6	BCGIKL
443	Dihydrocarvone	7764-50-3	ACGIJKL
447	Dihydro-alpha-terpinyl acetate	80-25-1	BDEFHIJKL
448	Dihydro-alpha-ionone	31499-72-6	BDHIJK
454	Dibenzyl ether	103-50-4	DEFHJK
455	Dibutyl o-phthalate	84-74-2	DEFHJ
469	2-pentylcyclopentan-1-one	4819-67-4	BDFHIKL
472	Decyl anthranilate	18189-07-6	DEFHJ
477	Methyl (1s,4s)-1,4-dimethylcyclohexane-	23059-38-3	ADEFHIJKL
	1-carboxylate
481	Cyclohexylethyl acetate	21722-83-8	BDEFHJKL
492	Creosol	93-51-6	BCHIK
495	Cosmene	460-01-5	ADEFGIKL
496	4-cyclohexyl-2-methylbutan-2-ol	83926-73-2	BDEFGIJK
504	2-benzyl-2-methylbut-3-enenitrile	97384-48-0	BDHJK
509	Citronellyl nitrile	51566-62-2	BCEFGIKL
510	Citronellyl phenylacetate	139-70-8	DFHJ
512	Citronellyl formate	105-85-1	BCEFGJKL
515	Citronellyl benzoate	10482-77-6	DFHJ
517	Citronellol	106-22-9	BCHIJKL
518	Citronellal	106-23-0	ACHIJKL
522	Citral	5392-40-5	ACHIKL
525	cis-Pinane	6876-13-7	ADEFGIJKL
526	(Z)-3-methyl-2-(pent-2-en-1-yl)	488-10-8	BCHIJKL
	cyclopent-2-en-1-one
528	cis-iso-Eugenol	5912-86-7	CEFHIK
535	cis-3-Hexenyl valerate	35852-46-1	BDEFHJKL
536	cis-3-Hexenyl tiglate	67883-79-8	BDEFHJK
538	cis-3-Hexenyl propionate	33467-74-2	ACEFHIKL
540	cis-3-Hexenyl butyrate	16491-36-4	ADEFHJKL
542	cis-3-Hexen-1-ol	928-96-1	ACEFHIKL
547	cis-2-Hexenol	928-94-9	ACEFHIKL
549	Cinnamyl nitrile	4360-47-8	ACEFGIK
554	Cinnamic aldehyde	104-55-2	ACHIK
556	Cinnamyl nitrile	1885-38-7	ACEFGIK
557	Chloroxylenol	88-04-0	BCHIJK
575	Carvacrol	499-75-2	DHIJK
576	Carvone	99-49-0	ACGIJKL
579	Carbitol	111-90-0	BCEFGIK
583	Caproyl alcohol	111-27-3	ACEFGIKL
585	2-(2,2,3-trimethylcyclopent-3-	15373-31-6	ACGIJKL
	en-1-yl)acetonitrile
588	Camphor	76-22-2	ACEFGIJKL
602	(E)-2-methyl-4-(2,6,6-trimethylcyclohex-	3155-71-3	DHJK
	1-en-1-yl)but-2-enal
605	Borneol	507-70-0	ACEFHIJKL
617	beta-Pinene epoxide	6931-54-0	ACEFGIJKL
619	beta-Phellandrene	555-10-2	ADEFGIJKL
640	Benzylacetone	2550-26-7	ACEFGIK
641	Benzyl salicylate	118-58-1	DFGJ
645	Benzyl isovalerate	103-38-8	BDEFHJK
647	Benzyl isobutyrate	103-28-6	BCHJK
651	Benzyl butyrate	103-37-7	BCEFHJK
652	Benzyl alcohol	100-51-6	ACEFGIKL
662	1-(3,3-dimethylcyclohexyl)ethyl formate	25225-08-5	ADEFHIJKL
664	Anisyl acetate	104-21-2	BCEFGK
665	Anisyl formate	122-91-8	BCEFGK
667	Anethole	104-46-1	ACEFHK
672	Amyl benzoate	2049-96-9	DEFHJK
687	alpha-Terpinyl acetate	80-26-2	BDHJK
699	alpha-methyl-cyclohexanepropanol	10528-67-3	BDEFHIK
701	alpha-methyl cinnamaldehyde	101-39-3	ACHIK
703	alpha-Isomethylionone	127-51-5	BDHIJK
740	2,5-Dimethyl-4-methoxy-3(2H)-furanone	4077-47-8	ACEFGIJKL
743	Allyl phenoxyacetate	7493-74-5	BCGK
744	Allyl Phenethyl ether	14289-65-7	ACEFHK
745	Allyl heptanoate	142-19-8	ADEFHJKL
755	N-ethyl-N-(m-tolyl)propionamide	179911-08-1	CEFHJK
760	3-hydroxybutan-2-one	513-86-0	ACEFGIKL
761	Acetoanisole	100-06-1	BCEFHIK
777	6-Methylquinoline	91-62-3	BCEFHIKL
779	6,8-Diethyl-2-nonanol	70214-77-6	BDEFGIJKL
784	5-Methyl-3-heptanone	541-85-5	ACFGIKL
789	4-Vinylphenol	2628-17-3	BCHIK
796	4-hydroxy-3-methoxy-cinnamaldehyde	458-36-6	CH
797	4-Ethylguaiacol	2785-89-9	CEFHIK
799	4-Damascol	4927-36-0	BDFHJK
808	3-methyl-4-phenylpyrazole	13788-84-6	CEFHK
810	3-Methyl-1,2-cyclopentanedione	765-70-8	ACEFGIKL
811	3-Methoxy-5-methylphenol	3209-13-0	BCHIK
812	3-Methoxy-3-Methyl Butanol	56539-66-3	ACGIKL
817	3-Hexenol	544-12-7	ACEFHIKL
819	3,7-dimethyl-2-methylene-6-octenal	22418-66-2	ADFHIJK
820	3,7-dimethyl-1-octanol	106-21-8	BDEFGIJKL
832	2-Phenylethyl acetate	103-45-7	BCEFHK
835	2-Phenethyl propionate	122-70-3	BCEFHJK
836	2-Pentylcyclopentan-1-ol	84560-00-9	DEFHIKL
838	2-nonanone propylene glycol acetal	165191-91-3	BDEFHJK
845	2-Methoxy-3-(1-methylpropyl)pyrazine	24168-70-5	BCEFGIK
846	2-isopropyl-N,2,3-trimethylbutyramide	51115-67-4	ACEFGIJK
847	2-Isopropyl-5-methyl-2-hexenal	35158-25-9	ADFGIJKL
848	2-Isopropyl-4-methylthiazole	15679-13-7	ACHIJKL
851	2-Hexen-1-ol	2305-21-7	ACEFHIKL
858	2-Butoxyethanol	111-76-2	ACEFGIKL
875	1,4-Cineole	470-67-7	ADGIJKL
880	1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-	43052-87-5	BDHIJK
	2-buten-1-one
882	(Z)-3-hepten-1-yl acetate	1576-78-9	ACEFHKL
883	(S)-(1R,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-	1196-01-6	ACEFGIJKL
	3-en-2-one
888	(R)-(−)-Linalool	126-91-0	BCEFGIJK
889	(1)-Citronellal	5949-05-3	ACHIJKL
891	(d)-Citronellal	2385-77-5	ACHIJKL
899	(+)-Citronellol	1117-61-9	BCHIJKL
900	(−)-Citronellol	7540-51-4	BCHIJKL
901	(+)-alpha-Pinene	7785-70-8	ADEFGIJKL
902	(+)-Carvone	2244-16-8	ACGIJKL
903	(−)-alpha-Pinene	7785-26-4	ADEFGIJKL
904	Methyl 2-methylbutyrate	868-57-5	ACEFGIKL
909	Hexyl tiglate	16930-96-4	BDEFHJKL
918	Allyl 2-(cyclohexyloxy)acetate	68901-15-5	CHJK
921	1,5-dimethylbicyclo[3.2.1]octan-8-one oxime	75147-23-8	CFHIJK
931	alpha-acetoxystyrene	2206-94-2	ACEFHIK
940	p-Cymene	99-87-6	ADGIJKL
956	Phenethyl formate	104-62-1	ACEFHK
958	Phenethyl isobutyrate	103-48-0	DHJK
960	Phenethyl tiglate	55719-85-2	DHJK
971	Phenylethyl methacrylate	3683-12-3	DHJK
977	p-Isopropylphenylacetaldehyde	4395-92-0	BDFHK
981	1,2-dimethyl-3-(prop-1-en-2-yl)cyclopentan-1-ol	72402-00-7	BCEFGIJKL
983	p-Methoxyphenylacetone	122-84-9	BCEFHK
986	(2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one	358331-95-0	ADHIJKL
987	p-Propyl anisole	104-45-0	ADEFHKL
994	p-t-butyl phenyl acetaldehyde	109347-45-7	BDHJK
995	p-tert-Amyl cyclohexanol	5349-51-9	BDEFHIJK
1001	Racemic alpha-Pinene	80-56-8	ADEFGIJKL
1002	4-(4-hydroxyphenyl)butan-2-one	5471-51-2	CEFGIK
1004	Rhodinol	141-25-3	BCHIJKL
1005	Ethyl (2,3,6-trimethylcyclohexyl)carbonate	93981-50-1	BDEFHJKL
1011	1-(3,3-dimethylcyclohexyl)ethyl acetate	25225-10-9	ADHIJKL
1017	S)-(+)-Linalool	126-90-9	BCEFGIJK
1018	Sabinene	3387-41-5	ADEFGIJKL
1019	Sabinene hydrate	546-79-2	ADEFGIJKL
1030	Propyl (S)-2-(tert-pentyloxy)propanoate	319002-92-1	BDEFHJK
1039	Spirolide	699-61-6	BCGIKL
1040	(Z)-5-methylheptan-3-one oxime	22457-23-4	BCEFGIJKL
1041	1-phenylethyl acetate	93-92-5	ACEFHIK
1051	Tetrahydrogeranial	5988-91-0	ADGIJKL
1052	Tetrahydroionol	4361-23-3	BDEFHIJK
1054	Tetrahydrolinalool	78-69-3	BDEFGIJKL
1055	Tetrahydrolinalyl acetate	20780-48-7	ADEFHJKL
1058	Ethyl (1R,6S)-2,2,6-trimethylcyclohexane-	22471-55-2	ADEFHIJKL
	1-carboxylate
1061	Thymol	89-83-8	BDHIJK
1069	trans-2-Hexenol	928-95-0	ACEFHIKL
1071	trans-2-tert-Butylcyclohexanol	5448-22-6	ACGIJKL
1074	trans-alpha-Damascone	24720-09-0	BDHIJK
1076	trans-Anethole	4180-23-8	ACEFHK
1079	trans-Cinnamic acid	140-10-3	CEFHK
1081	trans-Dihydrocarvone	5948-04-9	ACGIJKL
1084	trans-Isoeugenol	5932-68-3	CEFHIK
1088	Trichloromethyl phenyl	90-17-5	BDEFGJ
	carbinyl acetate
1098	2-mercapto-2-methylpentan-1-ol	258823-39-1	ACEFHIJKL
1110	Vanillin acetate	881-68-5	CH
1112	Vanitrope	94-86-0	CEFHK
1115	2,2,5-trimethyl-5-pentylcyclopentan-1-one	65443-14-3	BDFGIJKL
1118	Veratraldehyde	120-14-9	BCGIK
1119	(1R,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-	18309-32-5	ACEFGIJKL
	3-en-2-one
1122	Verdol	13491-79-7	ACGIJKL
1127	4-(tert-butyl)cyclohexyl acetate	10411-92-4	BDEFHJK
1128	4-(tert-butyl)cyclohexyl acetate	32210-23-4	BDEFHJK
1133	Vethymine	7193-87-5	CEFGK
1134	4-methyl-4-phenylpentan-2-yl acetate	68083-58-9	BDFHJK
1141	(Z)-1-((2-methylallyl)oxy)hex-3-ene	292605-05-1	ADEFHKL

TABLE 4
List of materials with ALL MORVs from 1 to 5

Number	Material Name	CAS Number	Comment Code

7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
14	Oxyoctaline formate	65405-72-3	DFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
48	Nootkatone	4674-50-4	DHJK
183	Khusimol	16223-63-5	CEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-	54464-57-2	DHJK
	octahydronaphthalen-2-yl)ethan-1-one
229	Isobornyl isobutyrate	85586-67-0	BDEFHIJK
260	2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal	173445-44-8	DHJK
261	3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal	173445-65-3	DHJK
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate	5413-60-5	CEFGJK
329	gamma-Eudesmol	1209-71-8	DFHJK
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
353	(Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one	69486-14-2	CEFGJK
360	8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-	171102-41-3	DEFHJK
	methanoinden-6-yl acetate
441	Octahydro-1H-4,7-methanoinden-5-yl acetate	64001-15-6	DEFHJKL
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-	113889-23-9	DEFHJK
	6-yl butyrate
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-	67634-20-2	DEFHJK
	5-yl isobutyrate
488	Curzerene	17910-09-7	DHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-	139539-66-5	DEFHJK
	6-oxabicyclo[3.2.1]octane
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
616	beta-Santalol	77-42-9	DEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
632	beta-Cedrene	546-28-1	BDEFGJKL
663	Anisyl phenylacetate	102-17-0	DFHJ
680	2,2,6,6,7,8,8-heptamethyldecahydro-	647828-16-8	ADEFHJK
	2H-indeno[4,5-b]furan
684	alpha-Vetivone	15764-04-2	DHJK
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
708	alpha-Gurjunene	489-40-7	BDEFHJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
764	Acetarolle ®	744266-61-3	DFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-hexamethyltetralin	1506-02-1	DEFHJ
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
919	3a,4,5,6,7,7a-hexahydro-	17511-60-3	CEFHJK
	1H-4,7-methanoinden-6-yl propionate
927	5-Acetyl-1,1,2,3,3,6-hexamethylindan	15323-35-0	DEFHJK
933	Patchouli alcohol	5986-55-0	DEFHIJK
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate	68039-44-1	DEFHJK
1007	(2R,4a'R,8a'R)-3,7'-dimethyl-3',4',4a',5',8',8a'-hexahydro-	41816-03-9	DEFHJK
	1'H-spiro[oxirane-2,2'-[1,4]methanonaphthalene]
1022	2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one	502847-01-0	DHIJK
1024	(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol	28219-61-6	DEFHJK
1027	5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde	193425-86-4	CHJK
1029	Sclareol oxide	5153-92-4	DEFHJK
1035	Spathulenol	6750-60-3	DEFHJK
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one	224031-70-3	DGJK
1060	Thujopsene	470-40-6	BDEFGJKL
1089	Tricyclone	68433-81-8	DEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-	32388-55-9	DHJK
	1H-3a,7-methanoazulen-5-yl)ethan-1-one
1131	Methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-	68738-99-8	DEFHJ
	yl)methylene)amino)benzoate
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene]	68480-11-5	DEFGJKL
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-	552-02-3	DEFHJK
	1H-cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-	127459-79-4	DHJ
	2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-	133636-82-5	DEFHJK
	3,1'-cyclohexan]-2'-en-4'-one
1144	1',1',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[1,3]dioxolane-	154171-76-3	DEFHJK
	2,8'-[2,4a]methanonaphthalene]
1145	1',1',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[1,3]dioxolane-	154171-77-4	DEFHJK
	2,8'-[2,4a]methanonaphthalene] K
1148	4,5-epoxy-4,11,11-trimethyl-8-	1139-30-6	DEFHJK
	methylenebicyclo(7.2.0)undecane
1149	1,3,4,6,7,8alpha-hexahydro-1,1,5,5-	23787-90-8	DEFHIJK
	tetramethyl-2H-2,4alpha-
	methanophthalen-8(5H)-one

TABLE 5
List of materials with ALL MORVs greater than 5 to 10

	Number	Material Name	CAS Number	Comment Code
	248	Hydroxymethyl	59056-64-3	BDEFHJK
		isolongifolene

TABLE 6
List of materials with ALL MORVs from 0.5 to less than 1

Number	Material Name	CAS Number	Comment Code
472	Decyl anthranilate	18189-07-6	DEFHJ
526	(Z)-3-methyl-2-(pent-	488-10-8	BCHIJKL
	2-en-1-yl)cyclopent-
	2-en-1-one

The materials in Tables 1-6 can be supplied by one or more of the following: Firmenich Inc. of Plainsboro N.J. USA; International Flavor and Fragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA; Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad, Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.

Actual MORV values for each material listed in Tables 1-6 above are as follows:

	MORV value for	MORV Value	MORV Value	MORV value for
Material No.	Equation a.)	for Equation b.)	for Equation c.)	Equation d.)

1	0.548223914	0.876283261	1.22018588	−0.41901144
2	1.520311929	3.493450446	2.70657265	5.11342862
3	2.267801995	−0.81712657	0.43218875	1.595983683
4	−0.591063369	−0.48283571	0.16199804	1.210497701
7	1.437444636	2.131822996	3.81633465	1.318339345
9	2.151445882	−0.46189495	0.56090469	1.206360803
10	2.5733592	−0.58780849	1.39751471	1.258361951
11	3.052627325	1.008519135	−0.30475953	0.076323462
12	0.683776599	−0.01157903	0.82853231	0.326169402
13	1.549643217	1.809183231	0.70864531	2.22799611
14	2.82111224	2.339505033	1.240818	2.502429355
16	−0.31551128	−0.06816599	−0.04371934	2.76742389
17	−1.334904153	−0.5773313	1.75644798	1.898455724
18	−1.34154226	−2.63596666	0.06885109	1.001431671
19	0.15532384	0.09866097	0.64214585	−0.33330779
20	0.640261783	0.693213268	0.54637273	−0.97556029
21	0.936895364	−0.01521118	1.1697513	−0.63510809
22	1.158981042	1.115900089	−0.25859776	1.318200884
23	3.702361074	1.399942641	5.23954766	7.089933671
24	0.773874141	0.146848137	−1.05705847	−0.36193173
25	−1.016103969	−1.18967936	0.78064625	2.944710012
25	−1.016103969	−1.18967936	0.78064625	2.944710012
26	0.615085491	−0.00096877	−0.35697252	−0.18121401
27	0.70261974	−0.22197386	0.19710806	−2.37196477
28	1.366472597	−0.42546942	−0.59394241	−0.01417395
29	1.096043453	−1.02972898	−1.42167356	−0.63817943
30	1.143415203	−0.85945441	−0.41416913	2.499807942
31	1.138642907	−0.19595476	−0.54547769	−0.98828898
32	1.914414495	−0.64487788	0.63212987	1.166699371
33	0.314847366	1.848003955	−1.3905032	−0.62848261
34	−0.113542761	0.981530917	0.32824239	1.126524277
35	0.472382903	1.494882467	−0.07201236	−0.64589543
36	3.158513795	1.084094934	−0.00328981	−0.17786385
37	−1.055631982	2.240172964	0.92596118	2.105391988
38	3.158513795	0.592820874	−0.49326241	0.212867212
39	1.083800659	2.069727985	2.48170879	3.205630609
42	−0.103134861	0.267726008	−0.65350189	1.125952363
43	0.323961628	1.469295081	−0.52991193	0.797908251
47	1.703678841	1.348737095	2.00634162	−0.16505407
48	2.370955056	2.783472865	2.68240273	1.221864405
49	1.670680003	−0.41866107	−0.9173849	1.181929544
50	1.670680003	0.076369374	−0.49915943	−0.85392575
52	0.464485039	0.057512869	1.31230219	−0.11170276
53	0.626671823	−0.46954947	−0.33383736	0.277079201
54	0.666149043	0.009549925	−0.36226343	0.197224432
55	0.723473579	−1.50916383	−0.3848989	−0.71458778
57	0.381273227	1.192994109	1.65593321	−1.65739236
59	0.561360663	−0.17793966	−1.63250554	−0.7564969
61	0.146473611	−0.01535544	−0.16339658	1.738656146
62	1.20162032	−0.3576095	−0.10695443	1.322155191
63	1.084291915	2.258720158	−1.01245416	1.688283974
64	0.744770665	0.155243763	−1.8029919	1.023503542
65	0.972835178	2.797151284	1.53453579	0.857051645
67	2.069410561	0.021831924	0.37855159	−0.67235457
68	0.527636614	0.590831983	1.02843762	2.208655795
69	2.133965691	2.088998449	2.05751412	−0.9433713
70	0.327378959	0.996844599	1.23648533	−1.25138371
71	1.40093669	0.778222691	0.70401172	−0.24075444
72	0.617697349	−0.29503359	0.52404847	0.816184656
73	0.617792473	0.888976061	−0.45289639	0.615659244
74	1.437359024	1.548292147	0.10314807	−0.48982286
75	−1.970885622	3.398008325	4.08025266	−0.89948156
76	−1.32746934	−2.65365233	0.10272816	1.001614125
77	−2.541686116	3.295534192	3.75284227	0.404837808
78	−2.110794	2.109874746	3.13350902	−0.3880285
79	1.641162056	−0.28533994	1.53676145	0.652696023
80	1.594400214	0.283682865	2.23140233	1.111682021
81	0.176566806	−2.0786518	−2.13986952	0.981126964
82	0.980373758	−0.28813159	0.19404501	1.252564677
83	0.941833098	0.317310013	1.17606727	0.72992237
84	0.774237336	−0.27140727	0.72461427	−1.56415746
85	2.092976965	0.810644229	0.82999192	−0.62861806
91	2.061595915	−0.79930338	−0.18285395	−0.66898499
92	2.068748434	−0.24299896	0.07214682	−1.11758276
93	−0.08984279	−1.06025959	−0.05068694	1.560050105
96	0.927758203	−0.44129515	0.89190422	0.744284978
97	0.658667572	−0.68771072	0.46051026	−0.53120883
98	0.853222693	−0.2037738	−0.21414441	1.119784962
100	1.654535066	0.995056228	2.35139085	0.543654824
101	2.173663649	−0.11491477	1.48285148	1.698527571
102	2.066679492	−0.16785146	−0.84780149	0.12159477
103	2.335152618	−0.02866585	0.16993375	−0.98254522
104	2.760588276	0.459513599	1.35310241	0.000336976
105	1.654535066	3.654489674	3.13033965	0.544225478
106	1.750588169	−0.55853348	0.50257773	1.630011313
107	0.896789863	0.73615897	0.53011623	−0.54697747
108	0.532375207	0.826537134	1.21040312	0.690230716
109	2.407655187	0.742651426	1.80322099	0.271832856
110	0.54830833	2.916795026	1.40126098	0.690230716
111	0.939597126	−0.3750368	−1.23479972	−0.89366351
112	1.398518854	1.265740274	4.19618377	−0.12762692
113	1.415726941	0.086297006	3.43559555	−0.12964168
115	−1.557729423	−0.44113526	0.86330536	0.590708892
116	0.193562268	−1.58091165	0.83247813	−0.70978039
117	1.353510875	−0.59062398	−0.31776345	−0.3050158
119	0.830052725	2.28725579	0.38409695	0.219336109
120	1.261997955	−0.22622961	−1.04772194	2.028504137
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819	0.805916178	0.96701754	−0.8811308	−1.23858491
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821	1.099377934	−0.55297074	−0.58846144	−1.64325365
824	−0.183625049	1.183962609	1.63494269	0.25504959
826	1.678825829	1.234136613	1.45948258	0.224375571
827	2.592229701	0.621958527	−0.52522117	−0.19676404
828	2.592229701	0.57915141	−0.51767373	−0.58077497
829	1.670680003	1.284791367	0.14864516	−0.84985664
831	1.116827432	−0.75462162	0.39137278	−0.04171761
832	0.516805788	−0.98195801	−1.03806082	−0.25383454
833	1.490368312	0.080687244	−0.97130296	0.833722265
834	−0.369014518	−1.35841128	−1.27372214	1.351157886
835	0.914072736	−0.8695664	0.36889122	−0.08606658
836	0.998848923	−0.42464651	−0.23731009	0.395895785
837	1.670680003	0.070165381	−0.64700996	−0.85055617
838	0.810918992	−0.75696962	−0.21854084	0.836677293
839	1.066219316	−0.66764691	−0.49983634	0.669914
840	1.078821776	−0.72511699	−1.00012288	−0.15789319
845	−0.163950017	−0.21616766	0.65276069	−0.52575739
846	0.665621985	−3.16625248	0.34329102	−1.44312939
847	−0.233400992	−1.15488444	0.83051343	−1.85751897
848	−0.631135606	0.037691556	0.57903451	−0.9926
849	1.707541313	0.010345383	0.48581606	1.513341091
850	1.447075297	0.022864201	0.99130501	0.473154634
851	−0.24632881	−0.23975349	−0.01449288	0.574861147
852	1.176028423	−0.85747031	−0.72464089	0.30542841
856	2.237616041	0.345329597	−0.60597063	−0.71581056
858	−1.47960224	−2.5770536	−1.03619781	0.847300104
864	1.670680003	1.284791101	0.14864516	−0.84985664
865	1.670680003	1.916382859	0.6998144	1.124089601
866	1.024819853	−0.7521596	0.35073152	−2.14193241
868	2.237616041	−0.17986241	−0.86317199	1.325805381
869	1.747776963	−0.25802105	−1.11614995	−0.77093434
870	2.592229701	2.030913569	−0.50618719	1.463926567
871	2.592229701	2.510587108	−0.07540594	−0.58371481
872	1.800767509	1.372656013	2.09551175	2.849728342
873	1.849432484	4.556065495	−0.39732139	−0.67726477
875	0.201768224	0.618509503	−0.39732139	−0.67726477
876	2.237616041	1.553468488	−0.72864242	−0.33330779
877	0.323968221	−1.00428076	−1.65151616	1.031096548
878	0.783570663	2.023288951	−0.03975252	0.474038265
879	1.187592149	1.464239711	0.67009263	1.103774764
880	−0.192632911	0.142411101	0.79310676	0.125548041
881	1.071875228	0.911734331	−1.50008456	0.185176261
882	0.798806784	−0.1516478	−0.64900063	−0.77199025
883	−0.671908804	−0.65984824	0.5238174	−0.85314111
884	2.863652137	1.896850773	0.06443558	−0.44689505
885	2.314558863	−0.25458637	0.22080129	−0.04142716
886	2.314558863	−0.25458637	0.22080129	−0.04142716
888	0.131224024	0.21510779	−1.70996346	0.964902175
889	0.742030255	0.281479436	−1.4156326	−1.91369695
890	1.071875228	0.911734331	−1.50008456	0.185176261
891	0.742030255	0.281479436	−1.4156326	−1.91369695
892	1.749446006	0.076054765	−0.59137073	0.291488011
893	0.869958847	0.843158237	0.61532515	3.158279932
894	1.749446006	0.076054765	−0.59137073	0.291488011
897	−0.047486491	1.045012945	−0.25220201	−0.31982826
899	0.784181146	−0.20530019	−1.89414748	0.152726109
900	0.784181146	−0.20530019	−1.89414748	0.152726109
901	−0.440378333	0.918089245	0.03050609	−1.62235977
902	−0.2346025	0.890438419	−0.13206526	−0.83961838
903	−0.440378333	0.918089245	0.03050609	−1.62235977
904	−1.320466583	−2.49763118	0.9787365	−1.85867969
905	−0.386224123	−0.24799559	1.19406353	−1.61243489
908	1.878331515	1.287303121	0.11530502	1.132065786
909	0.614968453	−1.61827184	−0.80789799	−0.66927285
912	0.530707518	0.774109528	3.0396125	4.394775258
913	0.337020095	1.531840025	0.10544973	0.347450471
914	0.774589061	1.224705331	1.87994281	−0.11684579
916	−0.363201351	0.35600238	−1.20673542	2.056973054
918	0.153047955	0.702054562	0.76757802	0.096096862
919	2.891894151	2.295157633	3.54101626	1.984030826
920	1.292959895	0.808281618	2.92956952	2.204248324
921	−0.465333775	0.862817284	0.1439546	0.64701735
922	1.54265003	0.291977233	0.79089158	0.801314068
923	1.340862559	0.503169303	0.53213093	3.164832031
924	0.158497146	1.507280765	2.25315926	1.173977914
925	1.23162703	1.671882685	3.1838372	−0.22917041
926	2.608734063	3.080604939	−0.69726361	−0.36219702
927	1.879182741	3.409153142	2.48473663	3.409954437
928	−0.093106169	0.019939108	0.15932154	1.229749745
929	1.670680003	1.94609957	0.19633838	1.14825764
930	3.052627325	0.956834107	−0.29721209	−0.31007607
931	0.367631287	0.501274945	−1.31074554	−0.39331005
933	3.702965303	3.03402795	4.33630831	4.238503729
937	0.570011387	0.097928934	1.03350455	−0.13392581
939	1.801474588	0.770314085	0.70188154	0.22333959
940	−0.412950838	−0.1781887	0.50649275	−0.57215449
941	1.691004766	−0.42331992	0.66279648	0.0318465
942	1.451782586	−0.565439	−0.32447381	−0.43378383
943	1.188491672	0.120632811	0.20106994	3.078484746
945	1.214814941	0.806987609	0.47605587	1.372949466
946	0.561732094	1.21448402	0.35542793	−1.03704442
947	0.956565856	1.505997176	0.88115653	−0.60583691
948	0.592575441	1.383482681	0.93567635	1.058669028
950	0.343657562	−0.85471906	−0.21125904	1.184648122
951	1.236659334	3.828926809	1.57729777	−0.31942874
953	1.836389049	0.755753735	−0.36014522	1.262853393
953	1.836389049	0.755753735	−0.36014522	1.262853393
954	1.001653875	−0.85635082	0.89224781	−0.39245818
955	−0.122918652	−0.846489	−0.63367729	1.182912962
956	0.589766639	−0.9783487	−0.67638264	−0.38772225
958	0.715082397	−0.90020686	0.86817768	0.030652004
959	1.609198886	0.500797943	0.795571	0.908389449
960	0.952787327	−0.90555475	−0.17381408	0.06786323
962	1.836429446	0.208275147	−0.14300625	1.067462181
965	1.9158432	0.35211823	−1.02174589	0.625657932
967	1.383869627	0.274520494	−0.11659267	0.840327437
969	−0.445579934	−1.68867059	−0.5241276	2.233793943
971	0.736419048	0.409875189	−0.63140848	0.034514594
973	1.073465817	2.18418874	2.01361447	−0.93754437
974	0.130904221	1.882440008	1.85101055	0.112524893
976	−0.236681385	−0.09745533	0.1779313	2.08923366
977	0.904402612	0.936956925	0.87731788	0.102346515
978	2.201759817	2.123549573	3.7881607	2.358768953
980	1.784266982	1.845281076	3.42873622	−0.31098233
981	−0.225023329	0.087962898	−0.29053012	0.514272787
982	−0.231175318	−0.0159671	1.27391892	1.090487158
983	0.889215441	0.24321159	0.06877629	0.816247177
985	1.864634345	0.133647536	1.29803755	1.951226654
986	0.511450274	−2.33512445	−0.56246315	−0.42184152
987	0.847260813	0.368638185	0.4114346	0.219336109
988	1.596170102	1.592158381	0.30052357	0.283467897
993	−3.549941097	−2.6847861	−0.17502622	1.41034664
994	0.445802042	0.899738574	0.61059602	0.323194673
995	0.949498724	0.357111159	0.28371155	−0.14156488
998	2.197271885	1.578871826	0.90563334	1.056619658
998	2.197271885	1.578871826	0.90563334	1.056619658
1000	1.456120673	0.626173572	0.07683183	−0.43324035
1001	−0.440378333	0.918089245	0.03050609	−1.62235977
1002	0.819929066	0.459101825	−0.09227583	0.324342063
1003	1.64412453	−0.09343399	0.70197344	3.710273595
1004	0.796928207	0.459954079	−0.88538616	0.152000937
1005	0.044923203	−0.19994963	0.60082875	0.258347835
1006	−0.320452673	−0.33232662	−0.52315783	1.406273663
1007	4.040291133	3.474551355	3.57146797	3.565985043
1008	0.764519082	0.917635102	2.88258762	2.319622474
1009	−0.071112206	0.539362906	2.98048732	0.580423329
1010	−0.689737481	0.547928768	1.98805626	−0.76653376
1011	0.343668917	0.931501008	−0.05483722	0.395369857
1012	1.926713131	0.124849138	−0.09654906	1.126499382
1016	0.124247716	0.193102712	0.39003599	1.737670628
1017	0.131224136	0.21510779	−1.70996346	0.964902175
1018	0.499624069	0.962843507	0.77617619	−1.15296947
1019	0.813491983	0.322635656	0.02800396	0.599500927
1020	0.715468114	1.015469049	1.45994989	0.352548581
1021	−1.176339404	1.539767848	−0.14427147	1.389902738
1022	1.364966718	1.690570939	2.05914194	2.364375484
1023	2.154641091	0.800066339	0.85365652	0.965810338
1024	2.302280068	1.252164308	1.73414439	1.549538352
1025	1.878331515	1.287303121	0.11530502	1.132065786
1026	2.97722987	2.096441965	3.87172868	0.550274831
1027	2.474381478	1.950326182	3.81861867	1.366897355
1028	1.778414353	3.114931059	4.47690731	6.054314034
1029	3.672910795	2.760483725	3.26915034	3.042677588
1030	−0.604959715	−2.13584086	0.8687855	0.024144016
1031	2.012732245	2.293857161	0.54405555	1.261882121
1032	−1.086688867	0.953083194	2.92177054	0.876865185
1033	1.617520676	1.008017006	2.21183536	−0.1288484
1035	2.506372295	3.419954592	4.58206882	4.134341651
1036	−0.675805062	−0.15357004	0.94597719	3.966016669
1037	−0.275092569	−0.67687665	−0.52763797	1.489972106
1038	2.753559643	3.81185814	2.71344734	2.243351472
1039	0.65087433	0.026885305	−0.0153558	0.011870127
1040	0.141526548	−1.65455278	0.50170705	−1.90794
1041	0.458680435	−0.69730218	−0.48806249	0.586073092
1042	−0.513264812	−0.22001961	0.36339519	1.03208599
1043	−1.497887014	−1.76116109	−0.76634926	1.137002742
1045	2.863652137	1.96790869	0.43661485	−0.44756897
1046	0.981194248	1.73892162	2.21166953	2.738129365
1047	0.981194248	1.73892162	2.21166953	2.738129365
1051	0.70261974	−0.22197386	0.19710806	−2.37196477
1052	0.662126832	0.741436531	0.61672724	0.289359903
1053	0.87463644	−0.19717783	1.2664131	−0.4187507
1054	0.284558077	−1.46754925	−0.03124571	0.587227244
1055	0.885837831	−0.91907796	−0.45817355	−1.1936897
1057	0.790964847	1.387925398	−0.18370692	1.302393792
1058	−1.052897931	−0.85226912	0.90324527	−1.09684959
1059	−0.871565421	−0.17856476	1.51267137	−1.52734367
1060	3.311161199	3.074783921	2.10199297	1.822541682
1061	−0.655128061	0.497032417	0.92381279	−0.56348341
1062	−0.443129049	0.96200606	1.51641349	−0.22974864
1063	1.385675542	0.738759296	1.1677069	0.501211562
1064	1.670680003	−0.20756775	−0.73755051	−0.84924056
1065	1.43532227	1.656262941	−1.09448841	1.674272267
1066	1.670680003	1.284791101	0.14864516	−0.84985664
1067	2.237616041	0.345329863	−0.60597063	−0.71581056
1069	−0.24632881	−0.23975349	−0.01449288	0.574861147
1070	1.670680003	0.070165381	−0.64700996	−0.85055617
1071	−1.02687397	−0.36244273	0.13010074	0.535909448
1072	1.670680003	1.94609957	0.19633838	1.14825764
1073	2.237616041	1.438074134	0.31117554	−0.71786492
1074	−0.192632911	0.142411101	0.79310676	0.125548041
1075	0.909356011	0.368597887	1.03689838	1.001198751
1076	0.812238101	0.195908668	0.21564664	0.219336109
1077	0.325255266	1.131242708	−2.79377204	−0.62848261
1078	0.325255266	1.131242708	−2.79377204	−0.62848261
1079	0.85330799	−0.6855194	−0.90046979	−0.46415796
1081	−0.131519393	0.731836014	0.81604919	−1.29993979
1082	0.744770665	0.155243763	−1.8029919	1.023503542
1083	1.415726941	0.086297223	3.43559555	−0.12964168
1084	0.161304111	0.66712144	0.58401752	0.373809692
1085	−0.72863532	−0.2873027	2.21251376	3.003873022
1088	−1.1773616	−0.23258175	0.40529195	0.994988969
1089	2.769817302	1.661618789	3.97585272	1.059236597
1090	3.052627325	0.420821685	−0.57080756	1.751222205
1091	−3.379896722	−3.71174986	2.53586709	0.644702886
1093	0.72304265	1.667011476	2.53982093	2.7903213
1095	0.744219765	1.372184572	0.15852396	1.126053442
1097	4.407270402	2.670641491	5.02636153	5.361271976
1098	−1.85804837	−2.59071226	−0.46522239	0.655734646
1099	0.745797788	−0.20547378	4.27836342	4.646390386
1102	2.068748434	−0.24299896	0.07214682	−1.11758276
1104	1.018876287	0.025163067	−0.1106021	0.838914654
1105	2.387326861	3.865456674	2.2251199	0.728667998
1107	2.352582059	2.595496601	3.20492728	2.844590737
1110	0.302703712	0.599942142	−0.25637571	−0.03195517
1111	0.750930333	0.656784751	1.68326413	0.329846578
1112	−0.205527848	0.287622624	−0.00340777	0.59203719
1115	0.999825037	0.662221152	0.43571192	0.342558518
1116	0.873381263	1.544324176	0.13703728	−0.38172701
1117	−0.682983903	1.798204302	2.42110319	−0.39173951
1118	0.069769623	0.496895599	0.67857133	−0.14954441
1119	−0.671908804	−0.65984824	0.5238174	−0.85314111
1120	0.953790113	1.106552668	3.00006904	1.585038764
1121	−1.184630973	2.476138312	4.80971952	2.450646806
1122	−1.02687397	−0.36244273	0.13010074	0.535909448
1125	0.387315524	−0.36101406	1.14153708	−0.75303953
1126	1.021783831	−0.0070257	−0.14327539	3.954381426
1127	0.990592079	0.305612583	0.14155512	−0.29526854
1128	0.990592079	0.305612583	0.14155512	−0.29526854
1129	3.18966648	3.284362987	4.49398568	3.950809104
1131	1.650621055	1.545704806	2.37535081	1.259373143
1133	−1.519747805	−0.60804324	0.02746106	0.590708892
1134	0.815942067	−0.16126019	−0.54117238	0.613093526
1135	0.626973385	1.998305877	2.61706075	1.570404253
1136	2.812199484	1.353198146	2.05618426	1.869204406
1137	2.208307057	1.387136198	3.21521374	2.069795393
1138	1.670680003	1.316442078	0.14822999	−0.46985154
1139	1.408517438	0.890457374	1.24524408	0.685687797
1140	2.765860952	2.525539595	4.12464228	3.833744077
1141	−0.484394663	0.677713073	−0.22783646	−0.37267608
1142	2.54335679	4.298105601	3.36234238	2.684404542
1143	4.204367611	3.062126931	3.4234313	2.072899554
1144	2.479165229	3.226545885	4.65897152	4.952127235
1145	2.479158921	3.226545885	4.65897152	4.952127235
1146	0.774334025	1.075800774	1.06893156	1.011113116
1147	0.844648531	1.21935371	2.59138595	0.805938034
1148	2.906236436	1.550674121	3.56959167	2.832126896
1149	2.837627443	3.707154326	4.53384262	2.625871865

Delivery Systems and Methods

Non-limiting examples of suitable delivery systems, methods of making delivery systems and the uses of such delivery systems are disclosed in USPA 2007/0275866 A1. Such delivery systems include:

• Polymer Assisted Delivery (PAD): This delivery technology uses polymeric materials to deliver materials. Classical coacervation, water soluble or partly soluble to insoluble charged or neutral polymers, liquid crystals, hot melts, hydrogels, perfumed plastics, microcapsules, nano- and micro-latexes, polymeric film formers, and polymeric absorbents, polymeric adsorbents, etc. are some examples. PAD includes but is not limited to:
  • Matrix Systems: The fragrance is dissolved or dispersed in a polymer matrix or particle. Perfumes, for example, may be 1) dispersed into the polymer prior to formulating into the product or 2) added separately from the polymer during or after formulation of the product. Diffusion of perfume from the polymer is a common trigger that allows or increases the rate of perfume release from a polymeric matrix system that is deposited or applied to the desired surface (situs), although many other triggers are known that may control perfume release. Absorption and/or adsorption into or onto polymeric particles, films, solutions, and the like are aspects of this technology. Nano- or micro-particles composed of organic materials (e.g., latexes) are examples. Suitable particles include a wide range of materials including, but not limited to polyacetal, polyacrylate, polyacrylic, polyacrylonitrile, polyamide, polyaryletherketone, polybutadiene, polybutylene, polybutylene terephthalate, polychloroprene, polyethylene, polyethylene terephthalate, polycyclohexylene dimethylene terephthalate, polycarbonate, polychloroprene, polyhydroxyalkanoate, polyketone, polyester, polyetherimide, polyethersulfone, polyethylenechlorinates, polyimide, polyisoprene, polylactic acid, polymethylpentene, polyphenylene oxide, polyphenylene sulfide, polyphthalamide, polypropylene, polystyrene, polysulfone, polyvinyl acetate, polyvinyl chloride, as well as polymers or copolymers based on acrylonitrile-butadiene, cellulose acetate, ethylene-vinyl acetate, ethylene vinyl alcohol, styrene-butadiene, vinyl acetate-ethylene, and mixtures thereof.
  • “Standard” systems refer to those that are “pre-loaded” with the intent of keeping the pre-loaded perfume associated with the polymer until the moment or moments of perfume release. Such polymers may also suppress the neat product odor and provide a bloom and/or longevity benefit depending on the rate of perfume release. One challenge with such systems is to achieve the ideal balance between 1) in-product stability (keeping perfume inside carrier until you need it) and 2) timely release (during use or from dry situs). Achieving such stability is particularly important during in-product storage and product aging. This challenge is particularly apparent for aqueous-based, surfactant-containing products, such as heavy duty liquid laundry detergents. Many “Standard” matrix systems available effectively become “Equilibrium” systems when formulated into aqueous-based products. One may select an “Equilibrium” system or a Reservoir system, which has acceptable in-product diffusion stability and available triggers for release (e.g., friction). “Equilibrium” systems are those in which the perfume and polymer may be added separately to the product, and the equilibrium interaction between perfume and polymer leads to a benefit at one or more consumer touch points (versus a free perfume control that has no polymer-assisted delivery technology). The polymer may also be pre-loaded with perfume; however, part or all of the perfume may diffuse during in-product storage reaching an equilibrium that includes having desired perfume raw materials (PRMs) associated with the polymer. The polymer then carries the perfume to the surface, and releases it typically via perfume diffusion. The use of such equilibrium system polymers has the potential to decrease the odor intensity of the neat product (usually more so in the case of pre-loaded standard systems). Deposition of such polymers may serve to “flatten” the release profile and provide increased longevity. As indicated above, such longevity would be achieved by suppressing the initial intensity and may enable the formulator to use more high impact or low odor detection threshold (ODT) or low Kovats Index (KI) PRMs to achieve FMOT benefits without initial intensity that is too strong or distorted. It is important that perfume release occurs within the time frame of the application to impact the desired consumer touch point or touch points. Matrix systems also include hot melt adhesives and perfume plastics. In addition, hydrophobically modified polysaccharides may be formulated into the perfumed product to increase perfume deposition and/or modify perfume release. All such matrix systems, including for example polysaccarides and nanolatexes may be combined with other PDTs, including other PAD systems such as PAD reservoir systems in the form of a perfume microcapsule (PMC).
  • Silicones are also examples of polymers that may be used as PDT, and can provide perfume benefits in a manner similar to the polymer-assisted delivery “matrix system”. Such a PDT is referred to as silicone-assisted delivery (SAD). One may pre-load silicones with perfume, or use them as an equilibrium system as described for PAD. Examples of silicones include polydimethylsiloxane and polyalkyldimethylsiloxanes. Other examples include those with amine functionality, which may be used to provide benefits associated with amine-assisted delivery (AAD) and/or polymer-assisted delivery (PAD) and/or amine-reaction products (ARP).
• Reservoir Systems: Reservoir systems are also known as a core-shell type technology, or one in which the material that will be delivered is surrounded by a release controlling membrane, which may serve as a protective shell. The material inside the microcapsule is referred to as the core, internal phase, or fill, whereas the wall is sometimes called a shell, coating, or membrane. Microparticles or pressure sensitive capsules or microcapsules are examples of this technology. Microcapsules of the current invention are formed by a variety of procedures that include, but are not limited to, coating, extrusion, spray-drying, interfacial, in-situ and matrix polymerization. The possible shell materials vary widely in their stability toward water. Among the most stable are polyoxymethyleneurea (PMU)-based materials, which may hold certain PRMs for even long periods of time in aqueous solution (or product). Such systems include but are not limited to urea-formaldehyde and/or melamine-formaldehyde. Gelatin-based microcapsules may be prepared so that they dissolve quickly or slowly in water, depending for example on the degree of cross-linking. Many other capsule wall materials are available and vary in the degree of perfume diffusion stability observed. Without wishing to be bound by theory, the rate of release of perfume from a capsule, for example, once deposited on a surface is typically in reverse order of in-product perfume diffusion stability. As such, urea-formaldehyde and melamine-formaldehyde microcapsules for example, typically require a release mechanism other than, or in addition to, diffusion for release, such as mechanical force (e.g., friction, pressure, shear stress) that serves to break the capsule and increase the rate of perfume (fragrance) release. Other triggers include melting, dissolution, hydrolysis or other chemical reaction, electromagnetic radiation, and the like. The use of pre-loaded microcapsules requires the proper ratio of in-product stability and in-use and/or on-surface (on-situs) release, as well as proper selection of PRMs. Microcapsules that are based on urea-formaldehyde and/or melamine-formaldehyde are relatively stable, especially in near neutral aqueous-based solutions. These materials may require a friction trigger which may not be applicable to all product applications. Other microcapsule materials (e.g., gelatin) may be unstable in aqueous-based products and may even provide reduced benefit (versus free perfume control) when in-product aged. Scratch and sniff technologies are yet another example of PAD.
• Molecule-Assisted Delivery (MAD): Non-polymer materials or molecules may also serve to improve the delivery of materials. Without wishing to be bound by theory, perfume may non-covalently interact with organic materials, resulting in altered deposition and/or release. Non-limiting examples of such organic materials include but are not limited to hydrophobic materials such as organic oils, waxes, mineral oils, petrolatum, fatty acids or esters, sugars, surfactants, liposomes and even other perfume raw material (perfume oils), as well as natural oils, including body and/or other soils. Perfume fixatives are yet another example. In one aspect, non-polymeric materials or molecules have a Log P greater than about 2.
• Cyclodextrin (CD): This technology approach uses a cyclic oligosaccharide or cyclodextrin to improve the delivery of materials. Typically a perfume and cyclodextrin (CD) complex is formed. Such complexes may be preformed, formed in-situ, or formed on or in the situs. Without wishing to be bound by theory, loss of water may serve to shift the equilibrium toward the CD-Perfume complex, especially if other adjunct ingredients (e.g., surfactant) are not present at high concentration to compete with the perfume for the cyclodextrin cavity. A bloom benefit may be achieved if water exposure or an increase in moisture content occurs at a later time point. In addition, cyclodextrin allows the perfume formulator increased flexibility in selection of PRMs. Cyclodextrin may be pre-loaded with perfume or added separately from perfume to obtain the desired perfume stability, deposition or release benefit.

Starch Encapsulated Accord (SEA): The use of a starch encapsulated accord (SEA) technology allows one to modify the properties of the material that will be delivered, for example, by converting a liquid perfume into a solid by adding ingredients such as starch. The benefit includes increased perfume retention during product storage, especially under non-aqueous conditions. Upon exposure to moisture, a perfume bloom may be triggered. Benefits at other moments of truth may also be achieved because the starch allows the product formulator to select PRMs or PRM concentrations that normally cannot be used without the presence of SEA. Another technology example includes the use of other organic and inorganic materials, such as silica to convert perfume from liquid to solid.

• Zeolite & Inorganic Carrier (ZIC): This technology relates to the use of porous zeolites or other inorganic materials to deliver materials. By way of example, perfume-loaded zeolite may be used with or without adjunct ingredients used for example to coat the perfume-loaded zeolite (PLZ) to change its perfume release properties during product storage or during use or from the dry situs. Silica is another form of ZIC. Another example of a suitable inorganic carrier includes inorganic tubules, where the perfume or other active material is contained within the lumen of the nano- or micro-tubules. Preferably, the perfume-loaded inorganic tubule (or Perfume-Loaded Tubule or PLT) is a mineral nano- or micro-tubule, such as halloysite or mixtures of halloysite with other inorganic materials, including other clays. The PLT technology may also comprise additional ingredients on the inside and/or outside of the tubule for the purpose of improving in-product diffusion stability, deposition on the desired situs or for controlling the release rate of the loaded perfume. Monomeric and/or polymeric materials, including starch encapsulation, may be used to coat, plug, cap, or otherwise encapsulate the PLT.

A delivery system comprising, based on total delivery system weight, a sum total of from about 0.00025% to about 30%, preferably from about 0.0025% to about 10%, more preferably from about 0.005% to about 5%, most preferably from about 0.01% to about 4% of a benefit agent that comprises one or more malodor reduction materials, preferably 1 to about 20 malodor reduction materials, more preferably 1 to about 15 malodor reduction materials, most preferably 1 to about 10 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001; and optionally an additional benefit agent, is disclosed.

In one aspect of said delivery system each of said malodor reduction materials may have an MORV of 1 or greater, 2 or greater, 3 or greater, 4 or greater, 5 or greater, 6 or greater, 7 or greater, 8 or greater, 9 or greater, preferably for each of such ranges, the upper limit is about 10. In one aspect of said delivery system, said malodor reduction materials have a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably 0 and/or a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index.

In one aspect of said delivery system, said one or more malodor reduction materials is selected from the group consisting of about 0.01 to about 80% malodor reduction composition, preferably from about 0.1 to 70% malodor reduction composition, more preferably from about 0.5 to 60% malodor reduction composition, most preferably from about 1.0 to 40% malodor reduction composition.

In one aspect of said delivery system, said delivery system is selected from the group consisting of:

a) a Polymer Assisted Delivery (PAD) system comprising, based on total benefit agent weight, from about 0.1 to about 50% Malodor reducing composition

b) a Molecule-Assisted Delivery (MAD) system, comprising, based on total benefit agent weight, from about 0.1 to about 75% Malodor reducing composition.

c) a Cyclodextrin (CD) system comprising, based on total benefit agent weight, from about 0.1 to about 20% Malodor reducing composition.

d) a Starch Encapsulated Accord (SEA) system comprising, based on total benefit agent weight, from about 0.1 to about 80% Malodor reducing composition.

e) a Zeolite & Inorganic Carrier (ZIC) system comprising, based on total benefit agent weight, from about 0.1 to about 30% Malodor reducing composition.

In one aspect of said delivery system, said Polymer Assisted Delivery (PAD) system comprises a Polymer Assisted Delivery (PAD) Reservoir system.

In one aspect of said delivery system, said Polymer Assisted Delivery (PAD) Reservoir system is a perfume delivery particle that comprises a shell material and a core material, said shell material encapsulating said core material, said core material comprising a malodor reduction material according to claims 1 and said shell comprising a material selected from the group consisting of polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyacrylates; aminoplasts, in one aspect said aminoplast comprises a polyureas, polyurethane, and/or polyureaurethane, in one aspect said polyurea comprises polyoxymethyleneurea and/or melamine formaldehyde; polyvinylamine, polyvinyl formamide, polyolefins; polyvinyl alcohol, polysaccharides, in one aspect alginate and/or chitosan; gelatin; shellac; epoxy resins; vinyl polymers; water insoluble inorganics; silicone; and mixtures thereof, preferably said perfume delivery particle have a volume weighted mean particle size from about, from about 5 microns to about 45 microns more preferably from about 8 microns to about 25 microns, or alternatively a volume weighted mean particle size from about, from about 25 microns to about 60 microns, more preferably from about 25 microns to about 60 microns.

In one aspect of said delivery system, said shell comprises melamine formaldehyde and/or cross linked melamine formaldehyde.

In one aspect of said delivery system, said shell is coated by a water-soluble cationic polymer selected from the group that consists of polysaccharides, cationically modified starch and cationically modified guar, polysiloxanes, dimethyldiallylammonium polyhalogenides, copolymers of dimethyldiallylammonium polychloride and vinyl pyrrolidone, acrylamides, imidazoles, imidazolinium halogenides and imidazolium halogenides and polyvinyl amine and its copolymers with N-vinyl formamide

In one aspect of said delivery system, said coating that coats said shell, comprises a cationic polymer and an anionic polymer.

In one aspect of said delivery system, said cationic polymer comprises hydroxyl ethyl cellulose; and said anionic polymer comprises carboxyl methyl cellulose.

In one aspect of said delivery system, said reduction materials are selected from the group consisting of Table 1 materials and mixtures thereof; preferably said material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 735, 733, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097, Table 3 materials 12, 19, 20, 24, 26, 27, 53, 54, 59, 72, 73, 81, 84, 96, 97, 107, 111, 115, 116, 125, 133, 147, 150, 151, 154, 157, 163, 166, 169, 181, 191, 194, 198, 201, 204, 205, 213, 214, 232, 237, 239, 255, 258, 264, 270, 273, 275, 282, 283, 284, 287, 302, 306, 308, 310, 312, 314, 319, 346, 354, 355, 365, 366, 376, 379, 387, 400, 412, 419, 420, 437, 438, 439, 440, 442, 443, 447, 448, 454, 455, 469, 472, 477, 481, 492, 495, 496, 504, 509, 510, 512, 515, 517, 518, 522, 525, 526, 528, 535, 536, 538, 540, 542, 547, 549, 554, 556, 557, 575, 576, 579, 583, 585, 588, 602, 605, 617, 619, 640, 641, 645, 647, 651, 652, 662, 664, 665, 667, 672, 687, 699, 701, 703, 740, 743, 744, 745, 755, 760, 761, 777, 779, 784, 789, 796, 797, 799, 808, 810, 811, 812, 817, 819, 820, 832, 835, 836, 838, 845, 846, 847, 848, 851, 858, 875, 880, 882, 883, 888, 889, 891, 899, 900, 901, 902, 903, 904, 909, 918, 921, 931, 940, 956, 958, 960, 971, 977, 981, 983, 986, 987, 994, 995, 1001, 1002, 1004, 1005, 1011, 1017, 1018, 1019, 1030, 1039, 1040, 1041, 1051, 1052, 1054, 1055, 1058, 1061, 1069, 1071, 1074, 1076, 1079, 1081, 1084, 1088, 1098, 1110, 1112, 1115, 1118, 1119, 1122, 1127, 1128, 1133, 1134, 1141 and mixtures thereof; preferably said malodor reduction materials are selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 733, 735, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097 and mixtures thereof, more preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7, 14, 39, 48, 183, 199, 206, 212, 215, 229, 260, 261, 281, 329, 335, 353, 360, 441, 484, 487, 488, 501, 566, 567, 569, 570, 573, 574, 603, 616, 621, 624, 627, 632, 663, 680, 684, 694, 696, 708, 712, 714, 726, 750, 764, 775, 776, 788, 804, 872, 919, 927, 933, 978, 1007, 1022, 1024, 1027, 1029, 1035, 1038, 1060, 1089, 1107, 1129, 1131, 1136, 1137, 1140, 1142, 1143, 1144, 1145, 1148, 1149, Table 5 material 248 and mixtures thereof, most preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 261, 680, 788, 1129, 1148, 1149 and mixtures thereof.

In one aspect of said delivery system, said delivery system is a perfume delivery particle that comprises a shell material and a core material, said shell material encapsulating said core material, said core material comprising a malodor reduction material selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 18, 21, 22, 23, 25, 28, 29, 30, 32, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 52, 57, 63, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 83, 85, 92, 93, 100, 101, 102, 103, 104, 105, 106, 109, 112, 113, 114, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 189, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 244, 246, 247, 249, 252, 253, 256, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 322, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 377, 378, 381, 385, 386, 388, 390, 391, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 426, 432, 436, 441, 444, 445, 449, 450, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 497, 498, 501, 502, 503, 505, 519, 520, 521, 527, 529, 531, 534, 537, 541, 544, 548, 550, 552, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 582, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 650, 653, 658, 659, 660, 661, 663, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 731, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 766, 768, 769, 771, 774, 775, 776, 778, 781, 782, 786, 788, 791, 800, 802, 803, 804, 806, 807, 814, 821, 826, 827, 828, 831, 833, 849, 850, 852, 866, 868, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 959, 962, 965, 967, 973, 974, 976, 978, 980, 982, 985, 988, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1065, 1075, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149; Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097; Table 3 materials 1, 9, 12, 13, 19, 20, 21, 24, 25, 27, 32, 34, 37, 38, 43, 53, 54, 55, 59, 65, 68, 70, 71, 72, 73, 79, 81, 83, 85, 96, 100, 105, 106, 109, 111, 114, 125, 126, 133, 134, 135, 137, 140, 142, 143, 147, 148, 150, 151, 152, 153, 154, 157, 159, 162, 167, 169, 178, 181, 189, 191, 192, 195, 197, 198, 201, 204, 211, 213, 228, 231, 232, 233, 234, 237, 238, 239, 242, 246, 252, 256, 270, 273, 275, 277, 285, 286, 288, 289, 290, 292, 293, 295, 300, 301, 306, 308, 310, 314, 319, 322, 325, 331, 333, 334, 336, 338, 339, 344, 354, 355, 356, 358, 361, 362, 363, 366, 370, 371, 372, 374, 376, 377, 378, 379, 381, 385, 387, 388, 390, 407, 412, 413, 417, 418, 419, 420, 432, 437, 438, 439, 440, 443, 444, 447, 448, 454, 455, 457, 461, 465, 467, 472, 477, 478, 479, 480, 481, 482, 485, 491, 496, 497, 502, 503, 504, 510, 512, 515, 517, 518, 525, 526, 529, 535, 536, 537, 540, 541, 544, 550, 557, 558, 559, 560, 561, 568, 571, 572, 575, 576, 585, 588, 589, 592, 594, 599, 600, 602, 604, 605, 609, 617, 619, 620, 625, 626, 633, 636, 638, 641, 644, 645, 647, 650, 651, 653, 662, 672, 673, 675, 676, 681, 683, 686, 687, 693, 697, 698, 700, 703, 704, 706, 707, 716, 717, 718, 722, 725, 740, 742, 745, 746, 755, 757, 769, 771, 779, 782, 799, 803, 806, 807, 819, 820, 827, 828, 833, 835, 838, 846, 847, 848, 850, 875, 878, 879, 880, 881, 883, 888, 889, 890, 891, 893, 899, 900, 901, 902, 903, 909, 912, 914, 918, 920, 921, 922, 923, 930, 937, 939, 940, 941, 945, 946, 947, 948, 953, 954, 958, 959, 960, 965, 967, 971, 981, 986, 994, 995, 998, 1000, 1001, 1003, 1004, 1005, 1008, 1009, 1010, 1011, 1017, 1018, 1019, 1020, 1023, 1026, 1030, 1031, 1032, 1036, 1040, 1046, 1047, 1051, 1052, 1053, 1054, 1055, 1057, 1058, 1061, 1062, 1063, 1071, 1074, 1075, 1081, 1088, 1091, 1093, 1095, 1098, 1099, 1102, 1104, 1105, 1111, 1115, 1116, 1119, 1120, 1122, 1127, 1128, 1134, 1135, 1139, 1146, 1147 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 18, 21, 22, 23, 25, 28, 29, 30, 32, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 52, 57, 63, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 83, 85, 92, 93, 100, 101, 102, 103, 104, 105, 106, 109, 112, 113, 114, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 189, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 244, 246, 247, 249, 252, 253, 256, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 322, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 377, 378, 381, 385, 386, 388, 390, 391, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 426, 432, 436, 441, 444, 445, 449, 450, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 497, 498, 501, 502, 503, 505, 519, 520, 521, 527, 529, 531, 534, 537, 541, 544, 548, 550, 552, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 582, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 650, 653, 658, 659, 660, 661, 663, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 731, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 766, 768, 769, 771, 774, 775, 776, 778, 781, 782, 786, 788, 791, 800, 802, 803, 804, 806, 807, 814, 821, 826, 827, 828, 831, 833, 849, 850, 852, 866, 868, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 959, 962, 965, 967, 973, 974, 976, 978, 980, 982, 985, 988, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1065, 1075, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149; Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097, and mixtures thereof, most preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7, 14, 39, 48, 183, 199, 206, 212, 215, 229, 260, 261, 281, 329, 335, 353, 360, 441, 484, 487, 488, 501, 566, 567, 569, 570, 573, 574, 603, 616, 621, 624, 627, 632, 663, 680, 684, 694, 696, 708, 712, 714, 726, 750, 775, 776, 788, 804, 872, 919, 927, 933, 978, 1007, 1022, 1024, 1027, 1029, 1035, 1038, 1060, 1089, 1107, 1129, 1131, 1136, 1137, 1140, 1142, 1143, 1144, 1145, 1148, 1149, Table 5 material 248 and mixtures thereof. These are materials that are stable in perfume microcapsules and do not leak so they will deposit and be available to counteract the malodor.

A delivery system according to any of claims 6 through 9, wherein said core comprises one or more malodor reduction materials having a vapor pressure of greater than 0.01 torr, preferably, greater than 0.01 torr to 10 torr, preferably said one or more malodor materials are selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 32; 34; 35; 42; 49; 65; 67; 70; 92; 93; 101; 102; 103; 114; 123; 126; 130; 142; 145; 149; 155; 159; 167; 168; 170; 178; 186; 189; 192; 193; 208; 209; 210; 218; 228; 229; 231; 256; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 386; 397; 398; 415; 421; 424; 436; 441; 444; 445; 449; 461; 466; 468; 471; 473; 475; 491; 519; 520; 527; 531; 534; 544; 565; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 659; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 742; 748; 750; 752; 763; 766; 768; 774; 778; 781; 786; 791; 800; 802; 806; 814; 821; 826; 827; 828; 850; 852; 866; 868; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 937; 946; 947; 950; 973; 974; 982; 1006; 1008; 1010; 1016; 1020; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1102; 1104; 1105; 1120; 1125; 1137; 1144; 1145, Table 2 materials 565: 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 65; 70; 73; 81; 96; 111; 114; 125; 126; 133; 142; 147; 150; 154; 157; 159; 167; 169; 178; 189; 192; 198; 201; 204; 228; 231; 232; 237; 239; 256; 270; 273; 290; 306; 319; 322; 325; 333; 338; 344; 354; 358; 362; 366; 376; 387; 412; 419; 420; 437; 438; 439; 443; 444; 447; 448; 461; 477; 481; 491; 496; 512; 517; 518; 525; 535; 536; 540; 544; 557; 575; 576; 585; 588; 589; 604; 605; 609; 617; 619; 633; 645; 647; 651; 662; 683; 686; 687; 693; 698; 717; 725; 740; 742; 745; 779; 806; 819; 820; 827; 828; 835; 838; 846; 847; 848; 850; 875; 878; 879; 883; 888; 889; 891; 899; 900; 901; 902; 903; 909; 914; 937; 940; 946; 947; 981; 986; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1071; 1081; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 32; 34; 35; 42; 49; 65; 67; 70; 92; 93; 101; 102; 103; 114; 123; 126; 130; 142; 145; 149; 155; 159; 167; 168; 170; 178; 186; 189; 192; 193; 208; 209; 210; 218; 228; 229; 231; 256; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 386; 397; 398; 415; 421; 424; 436; 441; 444; 445; 449; 461; 466; 468; 471; 473; 475; 491; 519; 520; 527; 531; 534; 544; 565; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 659; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 742; 748; 750; 752; 763; 766; 768; 774; 778; 781; 786; 791; 800; 802; 806; 814; 821; 826; 827; 828; 850; 852; 866; 868; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 937; 946; 947; 950; 973; 974; 982; 1006; 1008; 1010; 1016; 1020; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1102; 1104; 1105; 1120; 1125; 1137; 1144; 1145 and Table 2 materials 565: 631; 659; 715 and mixtures thereof, preferably said malodor reduction material is selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, Table 5 material 526 and mixtures thereof. These are materials that are stable in perfume particles as they do not leak and will volatilize more quickly into the air because they are lower VP when the delivery system releases them thus being able to block the perception of the malodor better on the substrate the delivery system is near to or in contact with.

A consumer product comprising delivery system disclosed by Applicants herein and a consumer product ingredient is disclosed.

A method of treating and/or cleaning a situs, said method comprising

• • a) optionally washing, rinsing and/or drying said situs;
  • b) contacting said situs with a delivery system according to claims 1-12 and/or a consumer product according to claim 13; and
  • c) optionally washing, rinsing and/or drying said situs is disclosed.

A situs treated with a delivery system disclosed herein and/or a consumer product disclosed herein is disclosed.

Process of Making Encapsulates

In one aspect, a process that may comprise:

• • a.) preparing a first solution that may comprise, based on total solution weight from about 20% to about 90%, from about 40% to about 80%, or even from about 60% to about 80% water, of a first emulsifier and a first resin, the ratio of said first emulsifier and said first resin being from about 0.1:0 to about 10:0, from about 0.1:1 to about 10:1, from about 0.5:1 to about 3:1, or even from about 0.8:1 to about 1.1:1;
  • b.) preparing a second solution that may comprise based on total solution weight from about 20% to about 95% water, of a second emulsifier and a second resin, the ratio of said second emulsifier and said second resin being from about 0:1 to about 3:1, from about 0.04:1 to about 0.2:1, or even from about 0.05:1 to about 0.15:1;
  • c.) combining a core material that may comprise a perfume disclosed in the present specification and said first solution to form a first composition;
  • d.) emulsifying said first composition;
  • e.) combining said first composition and said second solution to form a second composition and optionally combining any processing aids and said second composition—said first composition and said second solution may be combined in any order but in one aspect said second solution is added to said first composition or said second solution and said first composition are combined simultaneously;
  • f.) mixing said second composition for at least 15 minutes, at least 1 hour or even from about 4 hours to about 100 hours at a temperature of from about 25° C. to about 100° C., from about 45° C. to about 90° C., or even from about 50° C. to about 80° C. heat and optionally combining any processing aids to said second composition;
  • g.) optionally combining any scavenger material, structurant, and/or anti-agglomeration agent with said second composition during step f.) or thereafter—such materials may be combined in any order but in one aspect the scavenger material is combined first, any structurant second, and then anti-agglomeration agent is combined; and
  • h.) optionally spray drying said second composition is disclosed.

In one or more aspects of the process, said first and second resins may comprise the reaction product of an aldehyde and an amine, suitable aldehydes include, formaldehyde. Suitable amines include melamine, urea, benzoguanamine, glycoluril, and mixtures thereof. Suitable melamines include, methylol melamine, methylated methylol melamine, imino melamine and mixtures thereof. Suitable ureas include, dimethylol urea, methylated dimethylol urea, urea-resorcinol, and mixtures thereof.

In one or more aspects of the process, said first and second emulsifiers may comprise a moiety selected from the group consisting of carboxy, hydroxyl, thiol, amine, amide and combinations thereof. In one aspect, said emulsifier may have a pKa of less than 5, preferably greater than 0 but less than 5. Emulsifiers include acrylic acid-alkyl acrylate copolymer, poly(acrylic acid), polyoxyalkylene sorbitan fatty esters, polyalkylene co-carboxy anhydrides, polyalkylene co-maleic anhydrides, poly(methyl vinyl ether-co-maleic anhydride), poly(propylene-co-maleic anhydride), poly(butadiene co-maleic anhydride), and poly(vinyl acetate-co-maleic anhydride), polyvinyl alcohols, polyalkylene glycols, polyoxyalkylene glycols, and mixtures thereof.

In one or more aspects of the process, the pH of the first and second solutions may be controlled such that the pH of said first and second solution is from about 3.0 to 7.0.

In one or more aspects of the process, during step f.), from about 0% to about 10%, from about 1% to about 5% or even from about 2% to about 4%, based on total second composition weight, of a salt comprising an anion and cation, said anion being selected from the group consisting of chloride, sulfate, phosphate, nitrate, polyphosphate, citrate, maleate, fumarate and mixtures thereof; and said cation being selected from the group consisting of a Periodic Group IA element, Periodic Group IIA element, ammonium cation and mixtures thereof, preferably sodium sulfate, may be combined with said second composition.

In one or more aspects of the process, any of the aforementioned processing parameters may be combined.

Supplemental teachings of making suitable encapsulates as well as suitable shell materials are described in U.S. Pat. No. 6,869,923 B1 and US Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263 A1. Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco (New Jersey, U.S.A.).

Compositions

In one aspect, a composition that may comprise any aspect of the perfume delivery systems and/or perfumes disclosed in the present specification is disclosed.

In one aspect, said composition may be a consumer product.

In one aspect, such composition may be a consumer product that may comprise, based on total composition weight, from about 0.001% to about 50%, from about 0.01% to about 10%, or even from about 0.1% to about 5%, of a perfume disclosed in the present specification—from about 0.001% to about 90%, from about 0.01% to about 50%, or even from about 0.1% to about 10%, of said perfume, based on said perfume's weight, may be provided by a perfume delivery system according to the present specification.

In one aspect, said composition may comprise an encapsulate wherein said encapsulate's density may be such that the density ratio of said encapsulate to one or more fluids of the composition's fluids may be from about 0.9:1 to about 1.1:1; from about 0.98:1 to about 1.02:1; from about 0.99:1 to about 1.01:1 or even 1:1.

In one aspect, any of the aforementioned compositions may comprise a cleaning and/or treatment ingredient.

In one aspect, any of the aforementioned compositions' encapsulates may be a perfume microcapsule.

In one aspect, any of the aforementioned compositions may comprise one or more cleaning and/or treatment agents selected from the adjunct ingredients listed in the present specification.

While the precise level of encapsulate that is employed depends on the type and end use of the consumer product, in one aspect a consumer product may comprise, based on total composition weight, at least about 0.01%, from about 0.01% to about 80%, or even from about 0.02% to about 10% wt% of a encapsulate disclosed herein.

In one aspect, a consumer product that is compact is disclosed.

In one aspect, a consumer products including liquid detergents having a water content, based on total consumer product formulation weight, of from about 0% to about 15%, from about 0.01% to about 15%,from about 0.5% to about 10% or even from about 1% to about 8% water are disclosed.

In one aspect, the consumer product is a cleaning and/or treatment composition or fabric care composition that may comprise an encapsulate disclosed in the present specification and at least one cleaning and/or treatment composition or fabric care adjunct ingredient.

In one aspect, a cleaning composition may comprise, from about 0.005% to about 5% weight % of such encapsulate based on total cleaning composition weight of such encapsulate. In one aspect, a fabric treatment composition may comprise, based on total fabric treatment composition weight from about 0.005% to about 20% of such encapsulate.

Aspects of the invention include the use of the encapsulates of the present invention in detergent compositions (e.g., TIDE™), hard surface cleaners (e.g., MR CLEAN™), automatic dishwashing liquids (e.g., CASCADE™), dishwashing liquids (e.g., DAWN™), and floor cleaners (e.g., SWIFFER™). The cleaning compositions disclosed herein may be formulated such that, during use in aqueous cleaning operations, the wash water will have a pH of between about 6.5 and about 12, or between about 7.5 and 10.5. Liquid dishwashing product formulations typically have a pH between about 6.8 and about 9.0. Cleaning products are typically formulated to have a pH of from about 2 to about 11. Techniques for controlling pH at recommended usage levels include the use of buffers, alkalis, acids, etc., and are well known to those skilled in the art.

Fabric treatment compositions disclosed herein typically comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quats, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty oils, polymer latexes and mixtures thereof.

Formaldehyde Scavenger

In one aspect, the perfume delivery system disclosed herein may be combined with a formaldehyde scavenger. In one aspect, such perfume delivery system may comprise the encapsulates of the present invention. Suitable formaldehyde scavengers include materials selected from the group consisting of sodium bisulfite, melamine, urea, ethylene urea, cysteine, cysteamine, lysine, glycine, serine, carnosine, histidine, glutathione, 3,4-diaminobenzoic acid, allantoin, glycouril, anthranilic acid, methyl anthranilate, methyl 4-aminobenzoate, ethyl acetoacetate, acetoacetamide, malonamide, ascorbic acid, 1,3-dihydroxyacetone dimer, biuret, oxamide, benzoguanamine, pyroglutamic acid, pyrogallol, methyl gallate, ethyl gallate, propyl gallate, triethanol amine, succinamide, thiabendazole, benzotriazol, triazole, indoline, sulfanilic acid, oxamide, sorbitol, glucose, cellulose, poly(vinyl alcohol), partially hydrolyzed poly(vinylformamide), poly(vinyl amine), poly(ethylene imine), poly(oxyalkyleneamine), poly(vinyl alcohol)-co-poly(vinyl amine), poly(4-aminostyrene), poly(l-lysine), chitosan, hexane diol, ethylenediamine-N,N′-bisacetoacetamide, N-(2-ethylhexyl)acetoacetamide, 2-benzoylacetoacetamide, N-(3-phenylpropyl)acetoacetamide, lilial®, helional, melonal, triplal®, 5,5-dimethyl-1,3-cyclohexanedione, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,2-dimethyl-1,3-dioxan-4,6-dione, 2-pentanone, dibutyl amine, triethylenetetramine, ammonium hydroxide, benzylamine, hydroxycitronellol, cyclohexanone, 2-butanone, pentane dione, dehydroacetic acid, or a mixture thereof. These formaldehyde scavengers may be obtained from Sigma/Aldrich/Fluka of St. Louis, Mo. U.S.A. or PolySciences, Inc. of Warrington, Pa., U.S.A.

Such formaldehyde scavengers are typically combined with a slurry containing said benefit agent containing delivery particle, at a level, based on total slurry weight, of from about 2 wt. % to about 18 wt. %, from about 3.5 wt. % to about 14 wt. % or even from about 5 wt. % to about 13 wt. %.

In one aspect, such formaldehyde scavengers may be combined with a product containing a benefit agent containing delivery particle, said scavengers being combined with said product at a level, based on total product weight, of from about 0.005% to about 0.8%, alternatively from about 0.03% to about 0.5%, alternatively from about 0.065% to about 0.25% of the product formulation.

Consumer Product Ingredients

While not essential for each consumer product embodiment of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant consumer products and may be desirably incorporated in certain embodiments of the invention, for example to assist or enhance performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the operation for which it is to be used. Such adjunct are in addition to the perfumes and/or perfume delivery systems previously disclosed herein. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfume and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments.

As stated, the adjunct ingredients are not essential for each consumer product embodiment of the present invention. Thus, certain embodiments of Applicants' compositions do not contain one or more of the following adjuncts materials: bleach activators, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfumes and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below:

Surfactants—The compositions according to the present invention can comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic surfactants and/or ampholytic and/or zwitterionic and/or semi-polar nonionic surfactants. The surfactant is typically present at a level of from about 0.1%, from about 1%, or even from about 5% by weight of the cleaning compositions to about 99.9%, to about 80%, to about 35%, or even to about 30% by weight of the cleaning compositions.

Builders—The compositions of the present invention can comprise one or more detergent builders or builder systems. When present, the compositions will typically comprise at least about 1% builder, or from about 5% or 10% to about 80%, 50%, or even 30% by weight, of said builder. Builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth and alkali metal carbonates, aluminosilicate builders, polycarboxylate compounds, ether hydroxypolycarboxylates, copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, and carboxymethyl-oxysuccinic acid, the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids such as ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well as polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and soluble salts thereof.

Chelating Agents—The compositions herein may also optionally contain one or more copper, iron and/or manganese chelating agents. If utilized, chelating agents will generally comprise from about 0.1% by weight of the compositions herein to about 15%, or even from about 3.0% to about 15% by weight of the compositions herein.

Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. When present in the compositions herein, the dye transfer inhibiting agents are present at levels from about 0.0001%, from about 0.01%, from about 0.05% by weight of the cleaning compositions to about 10%, about 2%, or even about 1% by weight of the cleaning compositions.

Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials are the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid may comprise at least two carboxyl radicals separated from each other by not more than two carbon atoms.

Enzymes—The compositions can comprise one or more detergent enzymes which provide cleaning performance and/or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, 13-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is a cocktail of conventional applicable enzymes like protease, lipase, cutinase and/or cellulase in conjunction with amylase.

Enzyme Stabilizers—Enzymes for use in compositions, for example, detergents can be stabilized by various techniques. The enzymes employed herein can be stabilized by the presence of water-soluble sources of calcium and/or magnesium ions in the finished compositions that provide such ions to the enzymes.

Catalytic Metal Complexes—Applicants' compositions may include catalytic metal complexes. One type of metal-containing bleach catalyst is a catalyst system comprising a transition metal cation of defined bleach catalytic activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, such as zinc or aluminum cations, and a sequestrate having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra (methyl-enephosphonic acid) and water-soluble salts thereof.

If desired, the compositions herein can be catalyzed by means of a manganese compound. Such compounds and levels of use are well known in the art.

Compositions herein may also suitably include a transition metal complex of a macropolycyclic rigid ligand—abbreviated as “MRL”. As a practical matter, and not by way of limitation, the compositions and cleaning processes herein can be adjusted to provide on the order of at least one part per hundred million of the benefit agent MRL species in the aqueous washing medium, and may provide from about 0.005 ppm to about 25 ppm, from about 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm, of the MRL in the wash liquor.

Preferred transition-metals in the instant transition-metal bleach catalyst include manganese, iron and chromium. Preferred MRL's herein are a special type of ultra-rigid ligand that is cross-bridged such as 5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane.

Rheology Modifier

The liquid compositions of the present invention may comprise a rheology modifier. The rheology modifier may be selected from the group consisting of non-polymeric crystalline, hydroxy-functional materials, polymeric rheology modifiers which impart shear thinning characteristics to the aqueous liquid matrix of the composition. In one aspect, such rheology modifiers impart to the aqueous liquid composition a high shear viscosity, at 20 sec⁻¹ shear rate and at 21° C., of from 1 to 7000 mPa.s and a viscosity at low shear (0.5 sec⁻¹ shear rate at 21° C.) of greater than 1000 mPa.s, or even 1000 mPa.s to 200,000 mPa.s. In one aspect, for cleaning and treatment compositions, such rheology modifiers impart to the aqueous liquid composition a high shear viscosity, at 20 sec⁻¹ and at 21° C., of from 50 to 3000 mPa.s and a viscosity at low shear (0.5 sec⁻¹ shear rate at 21° C.) of greater than 1000 mPa.s, or even 1000 mPa.s to 200,000 mPa.s. Viscosity according to the present invention is measured using an AR 2000 rheometer from TA instruments using a plate steel spindle having a plate diameter of 40 mm and a gap size of 500 μm. The high shear viscosity at 20 sec⁻¹ and low shear viscosity at 0.5sec⁻¹ can be obtained from a logarithmic shear rate sweep from 0.1 sec⁻¹ to 25 sec⁻¹ in 3 minutes time at 21° C. Crystalline hydroxyl functional materials are rheology modifiers which form thread-like structuring systems throughout the matrix of the composition upon in situ crystallization in the matrix. Polymeric rheology modifiers are preferably selected from polyacrylates, polymeric gums, other non-gum polysaccharides, and combinations of these polymeric materials.

Generally the rheology modifier will comprise from 0.01% to 1% by weight, preferably from 0.05% to 0.75% by weight, more preferably from 0.1% to 0.5% by weight, of the compositions herein.

Structuring agents which are especially useful in the compositions of the present invention may comprise non-polymeric (except for conventional alkoxylation), crystalline hydroxy-functional materials which can form thread-like structuring systems throughout the liquid matrix when they are crystallized within the matrix in situ. Such materials can be generally characterized as crystalline, hydroxyl-containing fatty acids, fatty esters or fatty waxes. In one aspect, rheology modifiers include crystalline, hydroxyl-containing rheology modifiers include castor oil and its derivatives. In one aspect, rheology modifiers include hydrogenated castor oil derivatives such as hydrogenated castor oil and hydrogenated castor wax. Commercially available, castor oil-based, crystalline, hydroxyl-containing rheology modifiers include THIXCIN™ from Rheox, Inc. (now Elementis).

Other types of rheology modifiers, besides the non-polymeric, crystalline, hydroxyl-containing rheology modifiers described heretofore, may be utilized in the liquid detergent compositions herein. Polymeric materials which provide shear-thinning characteristics to the aqueous liquid matrix may also be employed.

Suitable polymeric rheology modifiers include those of the polyacrylate, polysaccharide or polysaccharide derivative type. Polysaccharide derivatives typically used as rheology modifiers comprise polymeric gum materials. Such gums include pectine, alginate, arabinogalactan (gum Arabic), carrageenan, gellan gum, xanthan gum and guar gum.

If polymeric rheology modifiers are employed herein, a preferred material of this type is gellan gum. Gellan gum is a heteropolysaccharide prepared by fermentation of Pseudomonaselodea ATCC 31461. Gellan gum is commercially marketed by CP Kelco U.S., Inc. under the KELCOGEL tradename.

A further alternative and suitable rheology modifier include a combination of a solvent and a polycarboxylate polymer. More specifically the solvent may be an alkylene glycol. In one aspect, the solvent may comprise dipropylene glycol. In one aspect, the polycarboxylate polymer may comprise a polyacrylate, polymethacrylate or mixtures thereof. In one aspect, solvent may be present, based on total composition weight, at a level of from 0.5% to 15%, or from 2% to 9% of the composition. In one aspect, polycarboxylate polymer may be present, based on total composition weight, at a level of from 0.1% to 10%, or from 2% to 5%. In one aspect, the solvent component may comprise mixture of dipropylene glycol and 1,2-propanediol. In one aspect, the ratio of dipropylene glycol to 1,2-propanediol may be 3:1 to 1:3, or even 1:1. In one aspect, the polyacrylate may comprise a copolymer of unsaturated mono- or di-carbonic acid and C₁-C₃₀ alkyl ester of the (meth) acrylic acid. In another aspect, the rheology modifier may comprise a polyacrylate of unsaturated mono- or di-carbonic acid and C₁-C₃₀ alkyl ester of the (meth) acrylic acid. Such copolymers are available from Noveon Inc. under the tradename Carbopol Aqua 30®.

In the absence of rheology modifier and in order to impart the desired shear thinning characteristics to the liquid composition, the liquid composition can be internally structured through surfactant phase chemistry or gel phases.

Processes of Making and Using Consumer Products

The embodiments of consumer products of the present invention can be formulated into any suitable form and prepared by any process chosen by the formulator, non-limiting examples of which are described in U.S. Pat. No. 5,879,584; which is incorporated herein by reference.

In one aspect, the perfumes and/or delivery systems comprising same that are disclosed herein may be incorporated into solid particles, particularly polymeric based particles. Preferably said perfume delivery system is a microcapsule that comprises said perfume one or more of said perfumes. Examples of such polymeric particles may include particles comprising polyethylene glycol, starches and polysaccharides, polyvinyl alcohol, celluloses. Such particles may additionally comprise additional components such as other benefit agents, inorganic fillers such as carbonate, silicate, clay, metal oxides. Particularly useful particles include particles based on polyethylene glycol.

Method of Use

Compositions, such as consumer products, containing the encapsulate disclosed herein can be used to clean or treat a situs inter alia a surface or fabric. Typically at least a portion of the situs is contacted with an embodiment of Applicants' composition, in neat form or diluted in a liquor, for example, a wash liquor and then the situs may be optionally washed and/or rinsed. In one aspect, a situs is optionally washed and/or rinsed, contacted with an encapsulate according to the present invention or composition comprising said encapsulate and then optionally washed and/or rinsed. For purposes of the present invention, washing includes but is not limited to, scrubbing, and mechanical agitation. The situs may comprise most any material, for example a fabric, fabric capable of being laundered or treated in normal consumer use conditions. Liquors that may comprise the disclosed compositions may have a pH of from about 3 to about 11.5. Such compositions are typically employed at concentrations of from about 500 ppm to about 15,000 ppm in solution. When the wash solvent is water, the water temperature typically ranges from about 5 ° C. to about 90 ° C. and, when the situs comprises a fabric, the water to fabric ratio is typically from about 1:1 to about 30:1.

Test Methods

Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and indentified, by analytical methods that include GC-MS and/or NMR.

Test For Volume Weighted Mean Particle Size

Particle size is measured using an Accusizer 780A, made by Particle Sizing Systems, Santa Barbara Calif. The instrument is calibrated from 0 to 300μ using Duke particle size standards. Samples for particle size evaluation are prepared by diluting about 1 g emulsion, if the volume weighted mean particle size of the emulsion is to be determined, or 1 g of capsule slurry, if the finished capsule volume weighted mean particle size is to be determined, in about 5 g of de-ionized water and further diluting about 1 g of this solution in about 25 g of water.

About 1 g of the most dilute sample is added to the Accusizer and the testing initiated, using the autodilution feature. The Accusizer should be reading in excess of 9200 counts/second. If the counts are less than 9200 additional sample should be added. The accusizer will dilute the test sample until 9200 counts/second and initiate the evaluation. After 2 minutes of testing the Accusizer will display the results, including volume-weighted median size.

The broadness index can be calculated by determining the particle size at which 95% of the cumulative particle volume is exceeded (95% size), the particle size at which 5% of the cumulative particle volume is exceeded (5% size), and the median volume-weighted particle size (50% size—50% of the particle volume both above and below this size). Broadness Index (5)=((95% size)−(5% size)/50% size).

Test Method for Determining Saturation Vapour Pressure (VP)

The saturation Vapour Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at 25 ° C. expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.

Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (log P

The value of the log of the Octanol/Water Partition Coefficient (log P) is computed for each PRM in the perfume mixture being tested. The log P of an individual PRM is calculated using the Consensus log P Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless log P value. The ACD/Labs' Consensus log P Computational Model is part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.

For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service (“CAS”), a division of the American Chemical Society, Columbus, Ohio, U.S.A. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.

A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), is used to duplicate the 2-dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.

For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a “.smi” or “.txt” file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: Cl═CC═CC═Cl benzene.

The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water Partition Coefficient (log P); Odour Detection Threshold (ODT); Malodour Reduction Value (MORV); and/or Universal Malodour Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.

• • Computing Molecular Structure Descriptors using winMolconn:
  • 1) Assemble the molecular structure for one or more perfume ingredients in the form of a MACCS Structure-Data File, also called an SDF file, or as a SMILES file.
  • 2) Using version 1.0.1.3 of the winMolconn program, running on an appropriate computer, compute the full complement of molecular descriptors that are available from the program, using the SDF or SMILES file described above as input.
    • a. The output of winMolconn is in the form of an ASCII text file, typically space delimited, containing the structure identifiers in the first column and respective molecular descriptors in the remaining columns for each structure in the input file.
  • 3) Parse the text file into columns using a spreadsheet software program or some other appropriate technique. The molecular descriptor labels are found on the first row of the resulting table.
  • 4) Find and extract the descriptor columns, identified by the molecular descriptor label, corresponding to the inputs required for each model.
    • a. Note that the winMolconn molecular descriptor labels are case-sensitive.
      MORV and Universal MORV calculation
• 1.) Input Molecular Descriptor values as determined via the method above into the following four equations:

MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)   a)

MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129x(idcbar)   b)

MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403x(idc)−0.23286×(nd2).   c)

MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)   d)

• Equation a) relates a material's effectiveness in reducing the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)
• Equation b) relates a material's effectiveness in reducing the malodor trimethylamine (amine based malodors)
• Equation c) relates a material's effectiveness in reducing the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)
• Equation d) relates a material's effectiveness in reducing the malodor skatole (indole based malodors)
• 2.) For purpose of the present application, a material's MORV is the highest MORV value from equations 1.)a) through 1.)d).
• 3.) If all MORVvalues from equations 1.)a) through 1.)d) above are greater than 0.5, the subject material has a Universal MORV.

Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker Index (BI) for a Malodor Reduction Compound

Blocker materials suitable for use in consumer products of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.

Method for Assigning the FFI to Test Samples

The first step in the method for assigning an FFI to the test samples on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution.

Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the FFI Reference Swatches

Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μL of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FFI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.

At least four perfumers/expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert panel is asked to rank order swatches according to a scale between 0 and 3.

The panel must demonstrate statistical differences between the swatches as seen in Table 7.

TABLE 7
Results FFI of reference swatches
from six perfumers/expert graders.

Expert Grader

Std

FFI	Swatch	1	2	3	4	5	6	Ave	Dev.

0	Control: stripped	0	0	0.5	0	0	0	0.08	0.2
	swatch NIL
	ethyl vanillin
1	Stripped swatch with	0.5	0.5	0.5	1.5	0.5	1.0	0.75	0.4
	13 μL 25 ppm
	ethyl vanillin
2	Stripped swatch with	2.0	1.5	1.5	2.0	2.0	2.0	1.8	0.2
	13 μL 120 ppm
	ethyl vanillin
3	Stripped swatch with	3.0	2.0	3.0	3.0	3.0	3.0	2.8	0.4
	13 μL 1000 ppm
	ethyl vanillin

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.

TABLE 8
This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.

Expert Grader

Std

FFI	Swatch	1	3	4	5	6	Ave	Dev.

0	Control: stripped	0	0.5	0	0	0	0.08	0.2
	swatch NIL
	ethyl vanillin
1	Stripped swatch with	0.5	0.5	1.5	0.5	1.0	0.80	0.4
	13 μL 25 ppm
	ethyl vanillin
2	Stripped swatch with	2.0	1.5	2.0	2.0	2.0	1.9	0.2
	13 μL 120 ppm
	ethyl vanillin
3	Stripped swatch with	3.0	3.0	3.0	3.0	3.0	3.0	0.0
	13 μL 1000 ppm
	ethyl vanillin

The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch.

TABLE 9
Swatch treatments comprising the Fragrance
Fidelity Index (FFI) reference scale

Swatch treatment	Conc. of ethyl vanillin	FFI
Clean fabric swatch w/ 13 μL ethyl vanillin	1000 ppm ethyl vanillin	3
Clean fabric swatch w/ 13 μL ethyl vanillin	120 ppm ethyl vanillin	2
Clean fabric swatch w/ 13 μL ethyl vanillin	25 ppm ethyl vanillin	1
Clean fabric swatch NIL ethyl vanillin	NIL ethyl vanillin	0

Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μL of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hrs of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.

Assigning the FFI to the Test Material

At least two perfumers/expert graders are used to assign an FFI grade to a test sample. The perfumer/expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FFI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.

Method for Assigning the BI to Test Sample

The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the BI Reference Swatches

Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acid solution to one clean swatch, 5 μL of the 0.08% isovaleric acid solution to the next swatch and 20 μL of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.

At least four perfumers/expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10.

TABLE 10
Results from six perfumers/expert graders to create the BI scale.

Expert Grader

Std

BI	Swatch	1	2	3	4	5	Ave	Dev.

0	Control: stripped swatch	0	0	0	0	0	0	0
	NIL isovaleric acid
1	Stripped swatch with 2 μL	0.5	2.0	1.0	1.0	0.5	1.0	0.5
	0.08% isovaleric acid
2	Stripped swatch with 5 μL	2.0	2.5	2.0	2.0	2.0	2.1	0.2
	0.08% isovaleric acid
3	Stripped swatch with 20 μL	3.0	3.0	3.0	3.0	2.5	2.8	0.2
	0.08% isovaleric acid

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.

TABLE 11
This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.

Expert Grader

Std

BI	Swatch	1	3	4	5	Ave	Dev.

0	Control: stripped swatch	0	0	0	0	0	0
	NIL isovaleric acid
1	Stripped swatch with 2 μL	0.5	1.0	1.0	0.5	0.8	0.3
	0.08% isovaleric acid
2	Stripped swatch with 5 μL	2.0	2.0	2.0	2.0	2.0	0
	0.08% isovaleric acid
3	Stripped swatch with 20 μL	3.0	3.0	3.0	2.5	2.9	0.2
	0.08% isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 BIs on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.

TABLE 12
Swatch treatments comprising the Blocker
Index (BI) reference scale.

	Swatch/treatment	Wt of isovaleric acid	BI
	Clean fabric swatch w/ 20 μL	16 mg isovaleric acid	3
	0.08% isovaleric acid
	Clean fabric swatch w/ 5 μL	4 mg isovaleric acid	2
	0.08% isovaleric acid
	Clean fabric swatch w/ 2 μL	1.6 mg isovaleric acid	1
	0.08% isovaleric acid
	Clean fabric swatch NIL	NIL isovaleric acid	0
	isovaleric acid

Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid+test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid+test material swatches and the BI reference swatches should be made within 2 hrs of each other. The isovaleric acid+test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1 and about 100 ppm to determine the BI.

Assigning the BI to the Test Material

At least two perfumers/expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid+test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the isovaleric acid+test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid+test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.

Malodor Reduction Compounds with FFI and BI Grades Based on the Aforementioned

Table
Ref #	CAS#	log P	Name	Conc	FFI	BI

281	54830-99-8	3.11	3a,4,5,6,7,7a-hexahydro-4,7-	10 ppm	0	2.0
			methano-1H-indenyl acetate	50 ppm	0.5	2.0
677	139504-68-0	3.75	1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol	10 ppm	0	2.3
				50 ppm	1.8	2.0
962	55066-48-3	3.17	3-methyl-5-phenylpentan-1-ol	10 ppm	0	2.3
				50 ppm	0.5	1.7
261	173445-65-3	3.29	3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal	10 ppm	0	1.8
				50 ppm	1.3	1.3
1139	87731-18-8	2.11	(Z)-cyclooct-4-en-1-yl methyl carbonate	10 ppm	0	2.0
				50 ppm	1.0	2.7
	4430-31-3	1.43	3,4,4a,5,6,7,8,8a-octahydrochromen-2-one	10 ppm	0	2.0
				50 ppm	0	2.0
204	40379-24-6	3.89	7-methyloctyl acetate	10 ppm	0	2.0
				50 ppm	0	2.7
1005	93981-50-1	5.59	ethyl (2,3,6-trimethylcyclohexyl)carbonate	50 ppm	0.5	2.6
391	106-33-2	5.73	Ethyl laurate	50 ppm	0.3	2.2
1148	1139-30-6	4.06	Caryophyllene Oxide	50 ppm	0.5	2.3
524	13877-91-3	4.31	3 ,7-Dimethyl-1,3,6-Octatriene(cis-β ocimene 70%)	50 ppm	0	2.8
	3338-55-4
1149	23787-90-8	4	1,3,4,6,7,8alpha-hexahydro-	10 ppm	0	1.5
			1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-	50 ppm	0.8	2.3
			8(5H)-one
	112-42-5	4.62	Undecanol	50 ppm	0.8	2.3
174	112-53-8	5.17	1-dodecanol	50 ppm	0.5	2.3
	98-52-2	2.78	4-tert-butyl cyclohexane	10 ppm	0	2.0
				50 ppm	0.3	2.0
109	112-39-0	6.41	Methyl palmitate	10 ppm		2.0

Malodor control compounds with improved performance at lower levels.

Below are some non-limiting examples of preferred behavior by which the malodor control compound gives improved malodor control at lower concentration. These nonlimiting data provide additional compelling data that malodor is being blocked, not masked.

Table
Ref #	CAS#	Name	Conc	FFI	BI

N/A	68912-13-0	8,8-dimethyl-3a,4,5,6,7,7a-	10 ppm	0	1.5
		hexahydro-1H-4,7-	50 ppm	0	2.2
		methanoinden-6-yl propionate
N/A	NA	4,8-dimethyl-1-(methylethyl)-	10 ppm		2.0
		7-oxybiciclo[4.3.0]nonane	50 ppm	0.3	2.2

Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor control compound could fail to demonstrate odor blocking (BI>2.5) at a higher concentration it should be retested at a lower concentration to determine if it passes.

Table
Ref #	CAS #	Name	Conc	FFI	BI

N/A	173445-65-3	1H-Indene-5-propanal, 2,3-	10 ppm	0	1.5
		dihydro-3 ,3-dimethyl-	50 ppm	0.5	2.7

EXAMPLE 1

Compositions Comprising Malodor Reduction Compounds

In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction compounds.

	% wt Active

Component	CAS#	A	B	C	D	E
2,2,8,8-tetramethyl-octahydro-1H-	29461-14-1	35-45	15-25	5-20	10-30	15-25
2,4a-methanonapthalene-10-one
1H-Indene-ar-propanal, 2,3-	300371-33-9	10-20	1-30	NIL	5-10	1-5
dihydro-1,1-dimethyl-
Hexadecanoic acid, (2E)-3,7-	3681-73-0	35-45	10-25	NIL	30-40	35-50
dimethyl-2,6-octadien-1-yl ester
1-Pentanol-3-methyl-5-phenyl	55066-48-3	10-20	10-25	2-10	5-17	10
4,7-Methano-1H-inden-5-ol,	171102-41-3	0-5	10-25	NIL	1-6	1-5
3a,4,5,6,7,7a-hexahydro-, 5-acetate
4,8-dimethyl-1-(methylethyl)-7-	N/A	0-5	NIL	NIL	NIL	1-5
oxybiciclo [4.3.0]nonane
(3Z)-3,7-dimethylocta-1,3,6-triene	3338-55-4	NIL	NIL	10-20	2-5	NIL
1H-Indene-5-propanal, 2,3-	173445-65-3	NIL	NIL	NIL	7.5-16	1-15
dihydro-3,3-dimethyl-
3,4,4a,5,6,7,8,8a-	4430-31-3	NIL	NIL	NIL	3-7	1-15
octahydrochromen-2-one
1-(2-tert-	139504-68-0	NIL	NIL	NIL	0.25-1.5	NIL
butylcyclohexyl)oxybutan-2-ol
ethyl (2,3,6-trimethylcyclohexyl)	93981-50-1	NIL	NIL	15-30	NIL	2
carbonate
benzyl 2-hydroxypropanoate	2051-96-9	NIL	NIL	2-5	NIL	NIL
(3,5-dimethylcyclohex-3-en-1-	67634-16-6	NIL	NIL	5-30	NIL	NIL
yl)methanol
2-Dodecanol	10203-28-8	NIL	0.25-1	NIL	0.5-3	NIL

EXAMPLE 2

Compositions Comprising Malodor Reduction Compounds

	% wt Active

Ingredient	CAS #	A	B	C	B	D	E

(E)-1-(2,6,6-trimethyl-1-	127-42-4	4	8	2	8	3	2
cyclohex-2-enyl)pent-1-en-3-
one
ethyl dodecanoate	106-33-2	NIL	1	NIL	3	NIL	NIL
3a,4,5,6,7,7a-hexahydro-1H-	68912-13-0	8	30	1	4	1	3.5
4,7-methanoind3en-1-yl
propanoate
[1R-(1R*,4R*,6R*,10S*)]-	1139-30-6	NIL	0.3	2	0.5	NIL	0.5
4,12,12-trimethyl-9-
methylene-5-
oxatricyclo[8.2.0.04,6]dodecane
(8E)-cyclohexadec-8-en-1-one	3100-36-5	NIL	5	NIL	7	NIL	NIL
3,5,5-trimethylhexyl acetate	58430-94-7	25	15	50	35	60	56
ethyl (2,3,6-	93981-50-1	NIL	1	NIL	5	NIL	NIL
trimethylcyclohexyl)
carbonate
2,4-dimethyl-4,4a,5,9b-	27606-09-3	25	10	15	15	16	15
tetrahydroindeno[1,2-
d][1,3]dioxine
2,2,7,7-	23787-90-8	8	9	5	7	5	5
tetramethyltricyclo[6.2.1.01,6]
undecan-5-one
(3,5-dimethylcyclohex-3-en-	67634-16-6	NIL	0.7	NIL	0.5	NIL	NIL
1-yl)methanol
3-(7,7-dimethyl-4-	33885-52-8	30	20	25	15	15	18
bicyclo[3.1.1]hept-3-enyl)-
2,2-dimethylpropanal
Total		100	100	100	100	100	100

EXAMPLE 3

Malodor Reduction Composition

		% wt Active

Ingredient	CAS #	A	B	C

5-Cyclohexadecen-1-One	37609-25-9	15.0	2.00	2.00
decahydro-2,2,7,7,8,9,9-heptamethylindeno(4,3a-b)furan	476332-65-7	0.005	0.01	0.01
2,3-Dihydro-5,6-dimethoxy-2-(4-piperidinylmethylene)-	33704-61-9	0.3	0.5	0.5
1H-inden-1-one
Cedryl Methyl Ether	19870-74-7	6.0	10.0	4.0
Trans-4-Decenal	65405-70-1	0.005	0.002	0.002
Decyl Aldehyde	112-31-2	3.74	2.0	2.0
3-methyl cyclopentadecenone	63314-79-4	0.4	1.0	1.0
Diphenyl Oxide	101-84-8	0.5	1.0	1.0
3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-indenyl acetate	54830-99-8	5.0	8.0	8.0
3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-1-yl propanoate	68912-13-0	6.0	8.0	8.0
2-(5-methyl-2-propan-2-yl-8-bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane	68901-32-6	10.0	15.0	15.0
(E)-3,7-dimethyl-2,6-octadienylhexadecanoate	3681-73-0	10.0	10.0	16.0
Iso Nonyl Acetate	58430-94-7	6.65	8.0	3.0
2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undecan-5-one	23787-90-8	10.0	8.0	8.0
(1-Methyl-2-(1,2,2-trimethylbicyclo[3.1.0]-hex-3-	198404-98-7	0.1	0.3	0.3
ylmethyl)cyclopropyl)methanol
Lauric Aldehyde	112-54-9	0.625	1.0	0.7
Methyl Iso Eugenol	93-16-3	18.000	10.0	13.0
Methyl hexadecanoate	112-39-0	3.000	10.0	12.0
2,3-dihydro-1,1-1H-dimethyl-indene-ar-propanal	300371-33-9	0.400	0.0	0.3
4-tert-butylcyclohexanol	98-52-2	0.400	0.1	0.1
2-isobutyl-4-hydroxy-4-methyltetrahydropyran	63500-71-0	1.600	2.0	2.0
Undecyl Aldehyde	112-44-7	1.725	2.888	1.888
Undecylenic Aldehyde	112-45-8	0.550	0.2	1.2
Total		100	100.0	100.0

EXAMPLE 4

84 wt % Core/16 wt % Wall Melamine Formaldehyde (MF) Capsule

25 grams of butyl acrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pKa 4.5-4.7, (Kemira Chemicals, Inc. Kennesaw, Ga. U.S.A.) is dissolved and mixed in 200 grams deionized water. The pH of the solution is adjusted to pH of 4.0 with sodium hydroxide solution. 8 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, (Cytec Industries West Paterson, N.J., U.S.A.)) is added to the emulsifier solution. 200 grams of perfume oil according to Table 1 or Table 2 is added to the previous mixture under mechanical agitation and the temperature is raised to 50° C. After mixing at higher speed until a stable emulsion is obtained, the second solution and 4 grams of sodium sulfate salt are added to the emulsion. This second solution contains 10 grams of butyl acrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pKa 4.5-4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to adjust pH to 4.8, 25 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 70° C. and maintained overnight with continuous stirring to complete the encapsulation process. 23 grams of acetoacetamide (Sigma-Aldrich, Saint Louis, Mo., U.S.A.) is added to the suspension. An average capsule size of 30 um is obtained as analyzed by a Model 780 Accusizer.

EXAMPLE 5

To demonstrate the benefit of the present invention, Applicants prepared liquid detergent matrix A, below.

	Active Material in weight %	A

	C14-C15 alkyl poly ethoxylate 7	3.39
	C12-C14 alkyl poly ethoxylate 7	1.13
	C12-C14 alkyl poly ethoxylate 3 sulfate	7.66
	Na salt
	Alkylbenzene sulfonic acid	1.17
	Citric Acid	2.73
	C12-18 fatty acid	5.06
	Enzymes	0.2
	Boric Acid	1.40
	Trans-sulphated ethoxylated	0.81
	hexamethylene diamine quat
	Diethylene triamine penta methylene	0.12
	phosphonic acid
	Hydrogenated Castor Oil structurant	0.300
	Ethanol	1.59
	1, 2 propanediol	0.07
	Sodium hydroxide	3.48
	Silicone PDMS emulsion	0.0025
	Blue Dye	0.0006
	Preservative Acticide MBS 2550	0.0135
	(ex Thor)
	Perfume (Neat)	0.3
	Malodor reducing composition (Neat)	0.02
	Perfume/Malodor reducing	0
	composition in delivery system
	Malodor reducing composition in	0.04
	Delivery System
	Merquat 5300 polymer (1)	0.19
	Water	Balance
		to 100%
	(1) Merquat 5300: terpolymer with mole ratio: 90% PAM/5% AA/5% MAPTAC produced by Nalco.

EXAMPLES 6-13

Laundry Detergent Compositions Comprising the Perfume Composition are Included Below

	% w/w of laundry detergent compositions

Material	6	7	8	9	10	11	12	13

Linear alkyl benzene	7.1	6.7	11.0	10.6	6.9	4.5	10.1	8.9
sulphonate
Sodium C12-15 alkyl ethoxy	3.5	0.0	1.5	0.0	0.0	0.0	0.0	1.9
sulphate having a molar
average degree of
ethoxylation of 3
Acrylic Acid/Maleic Acid	3.6	1.8	4.9	2.0	1.0	1.6	3.9	2.3
Copolymer
Sodium Alumino Silicate	4.0	0.5	0.8	1.4	16.3	0.0	17.9	2.4
(Zeolite 4A)
Sodium Tripolyphosphate	0.0	17.5	0.0	15.8	0.0	23.3	0.0	0.0
Sodium Carbonate	23.2	16.8	30.2	17.3	18.4	9.0	20.8	30.0
Sodium Sulphate	31.4	29.4	35.5	7.2	26.3	42.8	33.2	28.3
Sodium Silicate	0.0	4.4	0.0	4.5	0.0	6.1	0.0	4.6
C14-15 alkyl ethoxylated	0.4	2.6	0.8	2.5	3.1	0.3	3.8	0.4
alcohol having a molar
average degree of
ethoxylation of 7
Sodium Percarbonate	16.0	0.0	8.4	20.4	13.1	3.6	0.0	7.0
Sodium Perborate	0.0	9.9	0.0	0.0	0.0	0.0	0.0	0.0
Tetraacetylethylenediamine	2.2	1.7	0.0	4.7	3.6	0.0	0.0	0.8
(TAED)
Calcium Bentonite	0.0	0.0	0.0	1.8	0.0	0.0	0.0	5.6
Citric acid	2.0	1.5	2.0	2.0	2.5	1.0	2.5	1.0
Protease (84 mg active/g)	0.14	0.12	0.0	0.12	0.09	0.08	0.10	0.08
Amylase (22 mg active/g)	0.10	0.11	0.0	0.10	0.10	0.0	0.14	0.08
Lipase (11 mg active/g)	0.70	0.50	0.0	0.70	0.50	0.0	0.0	0.0
Cellulase (2.3 mg active/g)	0.0	0.0	0.0	0.0	0.0	0.0	0.18	0.0
Free (Neat) Perfume	0.36	0.16	0.15	0.2	0.3	0.1	0.34	0.34
Free (Neat) malodor	0.04	0	0.03	.02	0	0	0.03	0.015
reducing composition
Perfume/malodor reducing	0.14	0.5	0	0.25	0	0.2	0.25	0.5
composition encapsulated5
Malodor reducing	0	0	0.2	0	0.02	0	0	0
composition encapsulated5

Water & Miscellaneous	Balance to 100%

EXAMPLES 14-21

Granular Laundry Detergent Compositions Comprising the Perfume Composition are Included Below

	% w/w of laundry detergent compositions

Material	14	15	16	17	18	19	20	21

Linear alkyl benzene	7.1	6.7	11.0	10.6	6.9	4.5	10.1	8.9
sulphonate
Sodium C12-15 alkyl ethoxy	3.5	0.0	1.5	0.0	0.0	0.0	0.0	1.9
sulphate having a molar
average degree of
ethoxylation of 3
Acrylic Acid/Maleic Acid	3.6	1.8	4.9	2.0	1.0	1.6	3.9	2.3
Copolymer
Sodium Alumino Silicate	4.0	0.5	0.8	1.4	16.3	0.0	17.9	2.4
(Zeolite 4A)
Sodium Tripolyphosphate	0.0	17.5	0.0	15.8	0.0	23.3	0.0	0.0
Sodium Carbonate	23.2	16.8	30.2	17.3	18.4	9.0	20.8	30.0
Sodium Sulphate	31.4	29.4	35.5	7.2	26.3	42.8	33.2	28.3
Sodium Silicate	0.0	4.4	0.0	4.5	0.0	6.1	0.0	4.6
C14-15 alkyl ethoxylated	0.4	2.6	0.8	2.5	3.1	0.3	3.8	0.4
alcohol having a molar
average degree of
ethoxylation of 7
Sodium Percarbonate	16.0	0.0	8.4	20.4	13.1	3.6	0.0	7.0
Sodium Perborate	0.0	9.9	0.0	0.0	0.0	0.0	0.0	0.0
Tetraacetylethylenediamine	2.2	1.7	0.0	4.7	3.6	0.0	0.0	0.8
(TAED)
Calcium Bentonite	0.0	0.0	0.0	1.8	0.0	0.0	0.0	5.6
Citric acid	2.0	1.5	2.0	2.0	2.5	1.0	2.5	1.0
Protease (84 mg active/g)	0.14	0.12	0.0	0.12	0.09	0.08	0.10	0.08
Amylase (22 mg active/g)	0.10	0.11	0.0	0.10	0.10	0.0	0.14	0.08
Lipase (11 mg active/g)	0.70	0.50	0.0	0.70	0.50	0.0	0.0	0.0
Cellulase (2.3 mg active/g)	0.0	0.0	0.0	0.0	0.0	0.0	0.18	0.0
Free (Neat) Perfume	0.36	0.16	0.15	0.2	0.3	0.1	0.34	0.34
Free (Neat) malodor	0.04	0	0.03	.02	0	0	0.03	0.015
reducing composition
Perfume/malodor reducing	0.14	0.5	0	0.25	0	0.2	0.25	0.5
composition encapsulated5
Malodor reducing	0	0	0.2	0	0.02	0	0	0
composition encapsulated5

Water & Miscellaneous	Balance to 100%

The equipment and materials described in Examples 4 through to 21 can be obtained from the following: IKA Werke GmbH & Co. KG, Staufen, Germany; CP Kelco, Atlanta, United States; Forberg International AS, Larvik, Norway; Degussa GmbH, Dusseldorf, Germany; Niro A/S, Soeberg, Denmark; Baker Perkins Ltd, Peterborough, United Kingdom; Nippon Shokubai, Tokyo, Japan; BASF, Ludwigshafen, Germany; Braun, Kronberg, Germany; Industrial Chemicals Limited, Thurrock, United Kingdom; Primex ehf, Siglufjordur, Iceland; ISP World Headquarters; Polysciences, Inc. of Warrington, Pa., United States; Cytec Industries Inc., New Jersey, United States; International Specialty Products, Wayne, N.J., United States; P&G Chemicals Americas, Cincinnati, Ohio, United States; Sigma-Aldrich Corp., St. Louis, Mo., United States, Dow Chemical Company of Midland, Mich., USA

EXAMPLES 22-31

Fabric Conditioner

Non-limiting examples of fabric conditioners containing the polymer coated perfume microcapsules disclosed in the present specification are summarized in the following table.

	EXAMPLES

(% wt)	22	23	24	25	26	27	28	29	30	31

FSA a	14	16.47	14	12	12	16.47	—	—	5	10
FSA b					—		3.00	—	—	—
FSA c					—		—	6.5	—	—
Ethanol	2.18	2.57	2.18	1.95	1.95	2.57	—	—	0.81
Isopropyl Alcohol	—	—	—	—	—	—	0.33	1.22	—	1.0—
Starch d	1.25	1.47	2.00	1.25	—	2.30	0.5	0.70	0.71	0.42
Phase Stabilizing	0.21	0.25	0.21	0.21	0.14	0.18	0.15	0.14	0.2	0.1
Polymer f
Suds Suppressor g	—	—	—	—	—	—	—	0.1	—	—
Calcium Chloride	0.15	0.176	0.15	0.15	0.30	0.176	—	0.1-0.15	—	0025.
DTPA h	0.017	0.017	0.017	0.017	0.007	0.007	0.20	—	0.002	0.002
Preservative (ppm) i, j	5	5	5	5	5	5	—	250 j	5	5
Antifoamk	0.015	0.018	0.015	0.015	0.015	0.015	—	—	0.015	0.015
Dye (ppm)	40	40	40	40	40	40	11	30-300	30	30
Ammonium Chloride	0.100	0.118	0.100	0.100	0.115	0.115	—	—	—	—
HCl	0.012	0.014	0.012	0.012	0.028	0.028	0.016	0.025	0.011	0.011
Perfume microcapsules	0.2	0.02	0.1	0.15	0.12	0.13	0.3	0.4	0.24	0.1
as disclosed in Example 1
Malodor reducing	0	0	0.2	0	0.02	0	0	0	0.5	0.02
composition
encapsulated5
Perfume/malodor reducing	0.14	0.5	0	0.25	0	0.2	0.25	0.5	0	0
composition
encapsulated5
Additional Neat Perfume	0.8	0.7	0.9	0.5	1.2	0.5	1.1	0.6	1.0	0.9
Free (Neat) malodor	0.04	0	0.03	0.02	0	0	0.03	0.015	0.03	0.02
reducing composition
Deionized Water	†	†	†	†	†	†	†	†	†	†
a N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
b Methyl bis(tallow amidoethyl)2-hydroxyethyl ammonium methyl sulfate.
c Reaction product of Fatty acid with Methyldiethanolamine in a molar ratio 1.5:1, quaternized with Methylchloride, resulting in a 1:1 molar mixture of N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride and N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl ammonium chloride.
d Cationic high amylose maize starch available from National Starch under the trade name CATO ®.
f Rheovis DCE ex BASF.
g SE39 from Wacker
h Diethylenetriaminepentaacetic acid.
i KATHON ® CG available from Rohm and Haas Co. “PPM” is “parts per million.”
j Gluteraldehyde
kSilicone antifoam agent available from Dow Corning Corp. under the trade name DC2310.
† balance

EXAMPLES 32-37

Liquid Laundry Formulations (HDLs)

Ingredient	32	33	34	35	36	37

Alkyl Ether Sulphate	0.00	0.50	12.0	12.0	6.0	7.0
Dodecyl Benzene	8.0	8.0	1.0	1.0	2.0	3.0
Sulphonic Acid
Ethoxylated Alcohol	8.0	6.0	5.0	7.0	5.0	3.0
Citric Acid	5.0	3.0	3.0	5.0	2.0	3.0
Fatty Acid	3.0	5.0	5.0	3.0	6.0	5.0
Ethoxysulfated	1.9	1.2	1.5	2.0	1.0	1.0
hexamethylene diamine
quaternized
Diethylene triamine penta	0.3	0.2	0.2	0.3	0.1	0.2
methylene phosphonic acid
Enzymes	1.20	0.80	0	1.2	0	0.8
Brightener (disulphonated	0.14	0.09	0	0.14	0.01	0.09
diamino stilbene based
FWA)
Cationic hydroxyethyl	0	0	0.10	0	0.200	0.30
cellulose
Poly(acrylamide-co-	0	0	0	0.50	0.10	0
diallyldimethylammonium
chloride)
Hydrogenated Castor Oil	0.50	0.44	0.2	0.2	0.3	0.3
Structurant
Boric acid	2.4	1.5	1.0	2.4	1.0	1.5
Ethanol	0.50	1.0	2.0	2.0	1.0	1.0
1,2 propanediol	2.0	3.0	1.0	1.0	0.01	0.01
Glutaraldehyde	0	0	19 ppm	0	13 ppm	0
Diethyleneglycol (DEG)	1.6	0	0	0	0	0
2,3-Methyl-1,3-	1.0	1.0	0	0	0	0
propanediol (M pdiol)
Mono Ethanol Amine	1.0	0.5	0	0	0	0
NaOH Sufficient To	pH 8	pH 8	pH 8	pH 8	pH 8	pH 8
Provide Formulation pH of:
Sodium Cumene	2.00	0	0	0	0	0
Sulphonate (NaCS)
Silicone (PDMS) emulsion	0.003	0.003	0.003	0.003	0.003	0.003
Perfume (neat)	0.2	0.15	0	0.2	0.2	0.1
Malodor reducing	0.01	0.002	0.08	0	0	0.001
composition (neat)
Malodor reducing	0.1	0.1	0	0.2	0	0
composition in delivery
system
Perfume/Malodor reducing	0	0	0.22	0	0.3	0.2
composition in delivery
system
Water	Balance	Balance	Balance	Balance	Balance	Balance

EXAMPLES 38-45

Liquid Unit Dose

The following are examples of unit dose executions wherein the liquid composition is enclosed within a PVA film. The preferred film used in the present examples is Monosol M8630 76 μm thickness.

	D	E	F
	3 compartments	2 compartments	3 compartments

Compartment #	38	39	40	41	42	43	44	45
Dosage (g)	34.0	3.5	3.5	30.0	5.0	25.0	1.5	4.0

Ingredients	Weight %

Alkylbenzene sulfonic	20.0	20.0	20.0	10.0	20.0	20.0	25	30
acid
Alkyl sulfate				2.0
C12-14 alkyl 7-	17.0	17.0	17.0		17.0	17.0	15	10
ethoxylate
C12-14 alkyl ethoxy 3	7.5	7.5	7.5			7.5	7.5
sulfate
Citric acid	0.5		2.0	1.0				2.0
Zeolite A				10.0
C12-18 Fatty acid	13.0	13.0	13.0		18.0	18.0	10	15
Sodium citrate				4.0	2.5
enzymes	0-3	0-3	0-3	0-3		0-3	0-3	0-3
Sodium Percarbonate				11.0
TAED				4.0
Polycarboxylate				1.0
Ethoxylated	2.2	2.2	2.2
Polyethylenimine1
Hydroxyethane	0.6	0.6	0.6	0.5			2.2
diphosphonic acid
Ethylene diamine						0.4
tetra(methylene
phosphonic) acid
Brightener	0.2	0.2	0.2	0.3		0.3
Perfume/Malodor	0.4	0	1.5	1.3	0	0	0.12	0
reducing composition
in delivery system
Malodor reducing	0	0.25	0	0	0.10	0.25	0	0.12
composition in
delivery system
Water	9	8.5	10	5	11	10	10	9
CaCl2							0.01
Perfume (neat)	1.7	1.7		0.6	0.2	1.5	0.5	0.1
Malodor reducing	0.015	0.002	0.02	0.06	0	0	0.002	0
composition (neat)
Minors (antioxidant,	2.0	2.0	2.0	4.0	1.5	2.2	2.2	2.0
sulfite, aesthetics, . . .)

Buffers (sodium	To pH 8.0 for liquids
carbonate,	To RA > 5.0 for powders
monoethanolamine) 3
Solvents (1,2	To 100 p
propanediol, ethanol),
Sulfate
Polyethylenimine (MW = 600) with 20 ethoxylate groups per —NH.
3 RA = Reserve Alkalinity (g NaOH/dose)

EXAMPLE 46-47

Shampoo Formulation

	Ingredient	46	47

	Ammonium Laureth Sulfate (AE3S)	6.00	6.00
	Ammonium Lauryl Sulfate (ALS)	10.00	10.00
	Laureth-4 Alcohol	0.90	0.90
	Trihydroxystearin	0.10	0.10
	Perfume (neat)	0.15	0.15
	Malodor reducing	0	0
	composition (neat)
	Perfume/malodor delivery	0.4	0.2
	in delivery system
	Malodor reducing composition	0	0.05
	in delivery system
	Sodium Chloride	0.40	0.40
	Citric Acid	0.04	0.04
	Sodium Citrate	0.40	0.40
	Sodium Benzoate	0.25	0.25
	Ethylene Diamine Tetra Acetic Acid	0.10	0.10
	Dimethicone	1.00	1.00
	Water and Minors (QS to 100%)	Balance	Balance

Example 48-55

Free Flowing Particles Products

Free flowing particles products that comprise perfume and/or microcapsules comprising such perfume are provided below. The table below also exemplifies combinations which comprise also perfume free and in microcapsules or combinations of these with aforementioned combinations with malodor reduction materials and/or compositions. The table also exemplifies compositions having only malodor reduction materials and/or compositions free, in microcapsules and combinations thereof that have little to no fragrance to provide a product that is essentially ‘fragrance free’

COMPOSITION	48	49	50	51
Component	% Wt Active	% Wt Active	% Wt Active	% Wt Active
Polyethylene glycol	70-99	0-20	0-29	0-40
Clay	0-29	0-20	0-20	0-10
NaCl	0-29	50-99	0-29	0-40
Na2SO4	0-10	0-10	0-10	0-5
Urea	0-29	0-29	0-99	0-40
Polysaccharide	0-29	0-29	0-29	0-5
Zeolite	0-29	0-29	0-29	0-5
Plasticizers/Solvents
Starch/Zeolite	0-29	0-29	0-29	0-5
Silica	0-5	0-5	0-5	0-5
Metal oxide	0-29	0-29	0-29	0-29
Metal catalyst	0.001-0.5	0.001-0.5	0.001-0.5	0.001-0.5
Opacifier	0-5	0-5	0-1	0-1
Water	0-2	0-2	0-5	0-5
Perfume	0-5	0-5	0-5	0-5
Delivery System	0.001-10	0.001-4.5	0.001-3	0.001-7.5
comprising malodor
reduction composition
COMPOSITION	52	53	54	55
Component	% Wt Active	% Wt Active	% Wt Active	% Wt Active
Polyethylene glycol	70-99	0-20	0-29	0-40
Clay	0-29	0-20	0-20	0-10
NaCl	0-29	50-99	0-29	0-40
Na2SO4	0-10	0-10	0-10	0-5
Urea	0-29	0-29	0-99	0-40
Polysaccharide	0-29	0-29	0-29	0-5
Zeolite	0-29	0-29	0-29	0-5
Plasticizers/Solvents
Starch/Zeolite	0-29	0-29	0-29	0-5
Silica	0-5	0-5	0-5	0-5
Metal oxide	0-29	0-29	0-29	0-29
Metal catalyst	0.001-0.5	0.001-0.5	0.001-0.5	0.001-0.5
Opacifier	0-5	0-5	0-1	0-1
Water	0-2	0-2	0-5	0-5
Delivery System	0.001-10	0.001-4.5	0.001-3	0.001-7.5
comprising perfume/
malodor reducing
composition
(1) PEG
(2) Clay
(3) Urea
(4) Polysaccharide, mostly starches, unmodified starches, starch derivatives, acid-modified starch and kappa carrageenan
(5) Zeolite
(6) Starch/Zeolite-SEA
(7) Metal oxides-non-limiting examples-TiO2, ZnO, MnO
(8) Metal catalysts
(9) Opacifier

Example 56-60

Aqueous Composition/Fabric Refresher or Air Freshening Composition

The resulting fabric refreshing spray product when used to treat fabric surfaces is effective at reducing malodor on the treated fabric.

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm. ”

Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.